简要介绍了碳纳米管的结构及其分散性,说明碳纳米管具有一维结构及中空的内部结构,极高的化学稳定性,易于团聚.影响碳纳米管分散体系稳定性的关键是空间效应,所以末端亲水基团的结构和性能将明显影响碳纳米管的分散.碳纳米管在基体中的良好分散使复合材料力学性能大幅度提高,并且由于其优良的光电性能,加入碳纳米管也可显著提高复合材料的光电性能和导电性能.此外,碳纳米管石墨层的本质及独特的结构和尺寸,使碳纳米管在提高复合材料的热性能方面也有很大贡献.
The structure and the dispersion of carbon nanotubes are described, it is found that carbon nanotubes has one-dimensional structure and hollow internal structure, with a high chemical stability, easy to reunite. The key factors which affect the dispersion stability of the system is steric effect,so the dispersion of carbon nanotubes will be greatly affected by the structure and properties of the terminal hydrophilic group. The mechanical properties of composite materials are greatly improved by adding carbon nanotubes with good dispersion. And the optical properties and electrical conductivity properties of composite materials are also significantly improved because of carbon nanotubes' excellent optical properties. In addition, the graphite layer and the unique nature in the structure and size of carbon nanotubes,making it has a significant contribution to enhannce the thermal properties of composite materials.
参考文献
[1] | 鹿海军,梁国正,张宝艳,马晓燕,陈祥宝.纳米碳管在聚合物中的应用及其复合材料研究进展[J].材料导报,2003(07):57-60. |
[2] | 王垚,吴珺,魏飞,骞伟中,余皓.碳纳米管团聚结构的电镜研究[J].电子显微学报,2002(04):422-428. |
[3] | 孙宝云,韩晓晨.碳纳米管及新型一维碳纳米功能材料[J].现代物理知识,2007(04):25-27. |
[4] | Dresselhaus M S;Dresslhaus G;Eklund P C.Science of fullerenes & carbon nanotubes[M].San Diego:Academic Press,1996:785. |
[5] | 李莉香,李峰,英哲,杨全红,成会明.纳米碳管/聚合物功能复合材料[J].新型炭材料,2003(01):69-74. |
[6] | 张丽霞,齐鲁.多壁碳纳米管分散性研究[J].合成纤维,2008(06):32-35. |
[7] | Tzavalas S;Drakonakis V;Mouzakis DE;Fischer D;Gregoriou VG .Effect of carboxy-functionalized multiwall nanotubes (MWNT-COOH) on the crystallization and chain conformations of poly(ethylene terephthalate) PET in PET-MWNT nanocomposites[J].Macromolecules,2006(26):9150-9156. |
[8] | 唐玉生,顾军渭,孔杰.多壁碳纳米管(MW-CNTs)表面纯化改性研究[J].西安石油大学学报(自然科学版),2009(01):67-70. |
[9] | 沈剑锋,黄玮石,吴利平,胡轶喆,李俊,叶明新.多壁碳纳米管的纯化及修饰[J].材料导报,2006(z1):117-119. |
[10] | 姚承照,宋怀河,冯志海,李仲平,李嘉禄.碳纳米管表面硝酸氧化改性研究[J].宇航材料工艺,2008(02):34-38. |
[11] | Britto PJ.;Rubio A.;Alonso JA.;Ajayan PM.;Santhanam KSV. .Improved charge transfer at carbon nanotube electrodes[J].Advanced Materials,1999(2):154-157. |
[12] | 王川,邢哲,夏延致,隋坤艳,纪全,孔庆山.多壁碳纳米管的处理及其在芳纶1313中的分散[J].功能材料,2009(02):325-327. |
[13] | 郑成斐,杨胜林,李光,江建明.碳纳米管在聚丙烯腈中的分散状态[J].功能高分子学报,2004(01):25-29. |
[14] | Sreekumar T V et al.Polyacrylonitrile single-walled carbon nanotube composite fibers[J].Advanced Materials,2004,16(01):58. |
[15] | 董艳,张清华,李静,夏清明,陈大俊.聚丙烯腈/多壁碳纳米管共混纤维的研制[J].合成纤维,2008(04):1-4. |
[16] | Zhang Q;Rastogi S et al.Low percolation in single walled carbon nanotube/high density polyethylene composites prepared by melt processing technique[J].Carbon,2006,44(04):778. |
[17] | 王平华,杨莺,刘春华,唐龙祥,李凤妍.碳纳米管/PA6纳米复合材料的制备及力学性能[J].高分子材料科学与工程,2008(11):21-24. |
[18] | 贾志杰,王正元,徐才录,梁吉,魏秉庆,吴德海,张增民.原位法制取碳纳米管/尼龙6复合材料[J].清华大学学报(自然科学版),2000(04):14-16. |
[19] | 牛丽红,唐应武,张复实.卟啉修饰碳纳米管研究进展[J].化学通报(印刷版),2009(02):100-104. |
[20] | Curran SA.;Blau WJ.;Carroll DL.;Coleman JN.;Dalton AB. Davey AP.;Drury A.;McCarthy B.;Maier S.;Strevens A.;Ajayan PM. .A composite from poly(m-phenylenevinylene-co-2,5-dioctoxy-p-phenylenevinylene) and carbon nanotubes: A novel material for molecular optoelectronics[J].Advanced Materials,1998(14):1091-1093. |
[21] | McCarthy B;Coleman J N;Czerw R et al.Complex nano-assembiles of polymers and carbon nonotubes[J].Nanotech-nology,2001,12:187. |
[22] | 潘玮,张慧勤,陈燕.碳纳米管/聚丙烯腈导电纤维的结构与性能[J].合成纤维,2006(10):1-3,8. |
[23] | Sandler J;Shaffer M S P et al.Development of a dispersion process for carbon nanotubes in an epoxy matrix and the resulting electrical properties[J].Polymer,1999,40:5967. |
[24] | Jurewicz K.;Bertagna V.;Beguin F.;Frackowiak E.;Delpeux S. .Supercapacitors from nanotubes/polypyrrole composites[J].Chemical Physics Letters,2001(1/3):36-40. |
[25] | Gong X Y;Liu J;Baskaran S et al.Surfactant-assisted proceasing of carbon nanotube/polymer composites[J].Chemistry of Materials,2000,12(04):1049. |
[26] | 胡平;张天翔.聚合填料型超高分子量聚乙烯/碳纳米管复合材料的研究[A].北京:中国化学会,1999:171. |
[27] | 马雷,郑雪枫,李常清,童元建,徐樑华.碳纳米管/聚丙烯腈复合纤维的制备及结构研究[J].合成纤维工业,2008(05):1-3. |
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