对经过前期提纯的冶金级硅料进行一次性定向凝固生长多晶硅铸锭,研究了长晶阶段降温速率对多晶硅少子寿命的影响。结果显示降温速率越低,获得多晶硅少子寿命越高,但降温速率低到一定程度时,少子寿命反而会降低。通过测试生长多晶硅硅锭曲率半径、晶体结构等数据,分析了该现象的产生原因。这将有助于升级冶金硅一次性定向凝固生长多晶硅铸锭的生产应用。
According to multicrystalline silicon ( mc-Si ) ingots cast by one-step directional solidification growth with the pre-purification metallurgical grade silicon feedback, the effect of cooling rate on the minority carrier lifetime of mc-Si ingots can be known. In the study, using a lower cooling rate during growth process of mc-Si ingots, a higher lifetime on the mc-Si ingots can be obtained. But when the cooling rate is low to a certain degree, the minority carrier lifetime of mc-Si ingots reduces. The cause of the phenomenon is analyzed by measuring the curvature radius and the crystal structure of the grown mc-Si ingot. This phenomenon can be used to guide the production applications of metallurgical route with one-step directional solidification growth of mc-Si ingots.
参考文献
[1] | Tao Luo;Guoqiang Lv;Wenhui Ma;Kuixian Wei;Xi Yang;Shaoyuan Li.Numerical and experimental study of vacuum directional solidification purification process for SoG-Si in metallurgical route[J].Journal of Crystal Growth,2013Dec.1(Dec.1):122-128. |
[2] | 苏海军;张军;刘林;傅恒志.冶金硅定向凝固法制备太阳能级多晶硅及其微观组织与位错[J].中国有色金属学报(英文版),2012(10):2548-2553. |
[3] | A. A. Istratov;T. Buonassisi;R. J. McDonald;A. R. Smith;R. Schindler;J. A. Rand;J. P. Kalejs;E. R. Weber.Metal content of multicrystalline silicon for solar cells and its impact on minority carrier diffusion length[J].Journal of Applied Physics,200310(10):6552-6559. |
[4] | Franke D.;Rettelbach T.;Hassler C.;Koch W.;Muller A..Silicon ingot casting: process development by numerical simulations[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,20021/4(1/4):83-92. |
[5] | Y.T. Wong;C. Hsu;C.W. Lan.Development of grain structures of multi-crystalline silicon from randomly orientated seeds in directional solidification[J].Journal of Crystal Growth,2014Feb.1(Feb.1):10-15. |
[6] | Wei, Jiuan;Zhang, Hui;Zheng, Lili;Wang, Chenlei;Zhao, Bo.Modeling and improvement of silicon ingot directional solidification for industrial production systems[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,20099(9):1531-1539. |
[7] | 谭毅;孙世海;董伟;邢其智;冀明.多晶硅定向凝固过程中固-液界面特性研究[J].材料工程,2012(8):33-38. |
[8] | Kozo Fujiwara;Keiji Nakajima;Toru Ujihara.In situ observations of crystal growth behavior of silicon melt[J].Journal of Crystal Growth,20022(2):275-282. |
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