欢迎登录材料期刊网

材料期刊网

高级检索

基于锂电池负极结构及其组成材料铜与碳粉的物料特性,采用锤振破碎、振动筛分与气流分选组合工艺对废锂电池负极组成材料进行分离与回收.实验采用ICP-AES分析实验样品与分离富集产品的金属品位.结果表明:该负极材料经破碎筛分后,粒径大于0.250 mm的破碎料中铜的品位为92.4%,而粒径小于0.125 mm的破碎料中碳粉的品位为96.6%,均可直接同收;粒度为0.125~0.250 mm的破碎料中,铜的品位较低,可通过气流分选实现铜与碳粉的有效分离回收;气流分选过程中,操作气流速度为1.00 m/s时,铜的回收率达92.3%,品位达84.4%.

参考文献

[1] 戴永年,杨斌,姚耀春,马文会,李伟宏.锂离子电池的发展状况[J].电池,2005(03):193-195.
[2] M. Armand;J.-M. Tarascon .Building better batteries[J].Nature,2008(7179):652-657.
[3] John B. Goodenough;Youngsik Kim .Challenges for Rechargeable Li Batteries[J].Chemistry of Materials: A Publication of the American Chemistry Society,2010(3):587-603.
[4] Jinqiu Xu;H.R. Thomas;Rob W. Francis;Ken R. Lum;Jingwei Wang;Bo Liang .A review of processes and technologies for the recycling of lithium-ion secondary batteries[J].Journal of Power Sources,2008(2):512-527.
[5] FERREIRA D A;PRADOS L M Z;MAJUSTE D;MANSUR M B .Hydrometallurgical separation of aluminum,cobalt,copper and lithium from spent Li-ion batteries[J].Journal of Power Sources,2009,187:238-246.
[6] B. Swain;J. Jeong;J.-c. Lee .Separation of cobalt and lithium from mixed sulphate solution using Na-Cyanex 272[J].Hydrometallurgy,2006(3/4):130-138.
[7] SWAIN B;JEONG J;LEE J C;LEE G H SOHN J S .Hydrometallutgical process for recovery of cobalt from waste cathodic active material generated during manufacturing of lithium ion batteries[J].Journal of Power Sources,2007,167:536-544.
[8] DORELLA G;MANSUR M B .A study of the separation of cobalt from spent Li-ion battery residues[J].Journal of Power Sources,2007,170:210-215.
[9] KIM D S;SOHN J S;LEE C K;LEE J H HAN K S LEE Y I .Simultaneous separation and renovation of lithium cobalt oxide from the cathode of spent lithium ion rechargeable batteries[J].Journal of Power Sources,2004,132:145-149.
[10] Jessica Frontino Paulino;Natalia Giovanini Busnardo;Julio Carlos Afonso .Recovery of valuable elements from spent Li-batteries[J].Journal of hazardous materials,2008(3):843-849.
[11] A combined recovery process of metals in spent lithium-ion batteries[J].Chemosphere: Environmental toxicology and risk assessment,2009(8):1132.
[12] Rong-Chi Wang;Yu-Chuan Lin;She-Huang Wu .A novel recovery process of metal values from the cathode active materials of the lithium-ion secondary batteries[J].Hydrometallurgy,2009(3/4):194-201.
[13] 胡传跃,郭军,易秋艳,汪形艳,易涛.从废旧锂离子电池中回收制备LiAlO2材料[J].湖南人文科技学院学报,2007(06):25-28.
[14] 刘云建,胡启阳,李新海,王志兴,郭华军,彭文杰.锂离子电池边角料中直接回收合成LiCoO2的性能[J].中国有色金属学报,2008(z1):398-402.
[15] O.A. Fouad;F.I. Farghaly;M. Bahgat .A novel approach for synthesis of nanocrystalline γ-LiAlO_2 from spent lithium-ion batteries[J].Journal of analytical & applied pyrolysis,2007(1):65-69.
[16] E. Sayilgan;T. Kukrer;G. Civelekoglu .A review of technologies for the recovery of metals from spent alkaline and zinc-carbon batteries[J].Hydrometallurgy,2009(3/4):158-166.
[17] KUI HUANG;JIA LI;ZHENMING XU .A Novel Process for Recovering Valuable Metals from Waste Nickel-Cadmium Batteries[J].Environmental Science & Technology: ES&T,2009(23):8974-8978.
[18] 王柏成 .对典型分选效率公式的分析和评价[J].西安冶金建筑学院学报,1994,26(02):202-207.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%