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采用射频磁控溅射方法在Al2O3陶瓷基底上淀积厚度为500 nm的Cu膜,并将其于真空热处理炉中采用30℃/min和5℃/min两个升温速率升温至400℃退火处理2h,研究了退火升温速度对铜膜表面形貌、电阻率及附着力的影响.结果表明:退火热处理使Cu薄膜表面粗糙度增加,铜膜电阻率降低,膜-基结合力增强.且30℃/min快速升温较5℃/min缓慢升温退火热处理,Cu薄膜表面粗糙度低,Cu薄膜表面电阻率低,膜-基结合力差.利用自由电子气理论和扩散理论对退火热处理过程引起的性能变化进行了分析解释.

参考文献

[1] Qiu H.;Wang FP.;Wu P.;Pan LQ.;Tian Y. .Structural and electrical properties of Cu films deposited on glass by DC magnetron sputtering[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2002(3/4):447-452.
[2] Jha H;Kikuchi T;Sakairi M;Takahashi H .Area-selective microscale metallization on porous anodic oxide film of aluminium[J].Electrochemistry communications,2007(7):1596-1601.
[3] Kang S H;Obeng Y S;Decker M A et al.Effect of annealing on the surface microstructural evolution and the electromigration reliability of electroplated Cu films[J].Journal of Electronic Materials,2001,30(02):1506-1512.
[4] Chi Fo Tsang;Jasmine Woo .Effect of nitrogen and oxygen annealing on the morphology and hardness behavior of copper thin films[J].Materials Characterization,2000(3):187-194.
[5] L. H. Qian;Q. H. Lu;W. J. Kong;K. Lu .Electrical resistivity of fully-relaxed grain boundaries in nanocrystalline Cu[J].Scripta materialia,2004(11):1407-1411.
[6] Okolo B;Lamparter P;Welzel U;Wagner T;Mittemeijer EJ .The effect of deposition parameters and substrate surface condition on texture, morphology and stress in magnetron-sputter-deposited Cu thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2005(1/2):50-63.
[7] 雒向东,罗崇泰.退火态Cu膜表面形貌的分形特征[J].电子显微学报,2009(03):209-213.
[8] George Palasantzas .Influence of anomalous roughness growth on the electrical conductivity of thin films[J].Physical review, B. Condensed matter and materials physics,2005(20):205320.1-205320.5.
[9] 王新建 .溅射铜和铜合金薄膜的微观结构与性能[D].上海:上海交通大学,2009.
[10] 张树人,陈国良,郭太良.高性能导电薄膜的制备[J].真空,2007(03):24-27.
[11] 雒向东,吴学勇,赵海阔.磁控溅射300 nm铜膜的电学性能研究[J].微电子学,2007(06):826-829.
[12] 王晓平,赵特秀,季航,梁齐,董翊.晶粒尺寸对薄膜电阻率温度系数的影响[J].物理学报,1994(02):297-302.
[13] 郑伟涛.薄膜材料与薄膜技术[M].北京:化学工业出版社,2007:79.
[14] Zhang J;Tanaka H;Kanki T .Strain effect and the phase diagram of La{ 1-x} MnO thin films[J].Physical Review,2001,64(18):184404-1884407.
[15] Koo T Y;Park S H;Lee K B et al.Anisotropic strains and megnetoresistance of LaCaMnO[J].Applied Physics Letters,1997,71:977-980.
[16] 程丙勋,吴卫东,何智兵,许华,唐永建,卢铁城.退火温度对溅射铝膜结构与电性能的影响[J].强激光与粒子束,2008(01):155-158.
[17] Vinci RP.;Bravman JC.;Zielinski EM. .THERMAL STRAIN AND STRESS IN COPPER THIN FILMS[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1995(1/2):142-153.
[18] M. Shariati;M. Ghoranneviss;H. Hosseini;M.R. Hantehzadeh .Effect of annealing temperature on properties of Al–Cu–N thin films deposited by DC magnetron sputtering[J].Surface & Coatings Technology,2007(9/11):5570-5573.
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