随着石墨烯低成本宏量制备技术的突破,石墨烯的工业化应用进程已引起人们广泛关注。本文介绍了石墨烯在聚合物基复合材料领域的研究进展,侧重阐述石墨烯/聚合物复合材料在力学增强、导电/导热网络构建、防腐阻燃等方面的代表性研究成果,同时对商业化石墨烯产品及其复合材料应用进行了简单评述,探讨了石墨烯/聚合物复合材料领域目前存在的主要问题及未来发展趋势。
With the rapid development and technological breakthroughs in the synthesis of graphene on a large scale at low cost, the commercial application of graphene materials has been arousing great interest from both academic and industrial fields. We re-view the latest research progress on graphene/polymer composites, focusing on their mechanical reinforcement, improvement of electrical and thermal conductivity, corrosion resistance, and flame-retardance. The current situation regarding commercial graphene products is summarized, and the main problems and future development of graphene/polymer composites are discussed.
参考文献
[1] | Alberto Bianco;Hui-Ming Cheng;Toshiaki Enoki.All in the graphene family - A recommended nomenclature for two-dimensional carbon materials[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:1-6. |
[2] | Balandin AA;Ghosh S;Bao WZ;Calizo I;Teweldebrhan D;Miao F;Lau CN.Superior thermal conductivity of single-layer graphene[J].Nano letters,20083(3):902-907. |
[3] | Tapas Kuilla;Sambhu Bhadra;Dahu Yao.Recent advances in graphene based polymer composites[J].Progress in Polymer Science,201011(11):1350-1375. |
[4] | Hua Bai;Chun Li;Gaoquan Shi.Functional Composite Materials Based on Chemically Converted Graphene[J].Advanced Materials,20119(9):1089-1115. |
[5] | Xiao Huang;Xiaoying Qi;Freddy Boey.Graphene-based composites[J].Chemical Society Reviews,20122(2):666-686. |
[6] | Stankovich S;Dikin DA;Dommett GHB;Kohlhaas KM;Zimney EJ;Stach EA;Piner RD;Nguyen ST;Ruoff RS.Graphene-based composite materials[J].Nature,20067100(7100):282-286. |
[7] | Raquel Verdejo;M. Mar Bernal;Laura J. Romasanta.Graphene filled polymer nanocomposites[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201110(10):3301-3310. |
[8] | Mittal, Garima;Dhand, Vivek;Rhee, Kyong Yop;Park, Soo-Jin;Lee, Wi Ro.A review on carbon nanotubes and graphene as fillers in reinforced polymer nanocomposites[J].Journal of industrial and engineering chemistry,20151 Pt.1(1 Pt.1):11-25. |
[9] | Du, J.;Cheng, H.-M..The fabrication, properties, and uses of graphene/polymer composites[J].Macromolecular chemistry and physics,201210/11(10/11):1060-1077. |
[10] | 王旭珍;刘宁;胡涵;王新平;邱介山.3D二硫化钼/石墨烯组装体的制备及其催化脱硫性能[J].新型炭材料,2014(2):81-88. |
[11] | Diana Berman;Ali Erdemir;Anirudha V. Sumant.Graphene: a new emerging lubricant[J].Materials Today,20141(1):31-42. |
[12] | Xuemei Sun;Hao Sun;Houpu Li;Huisheng Peng.Developing Polymer Composite Materials: Carbon Nanotubes or Graphene?[J].Advanced Materials,201337(37):5153-5176. |
[13] | Hernandez Y;Nicolosi V;Lotya M;Blighe FM;Sun ZY;De S;McGovern IT;Holland B;Byrne M;Gun'ko YK.High-yield production of graphene by liquid-phase exfoliation of graphite[J].Nature nanotechnology,20089(9):563-568. |
[14] | DUSTIN K. JAMES;JAMES M. TOUR.Graphene: Powder, Flakes, Ribbons, and Sheets[J].Accounts of Chemical Research,201310(10):2307-2318. |
[15] | Weifeng Zhao;Ming Fang;Furong Wu.Preparation of graphene by exfoliation of graphite using wet ball milling[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201028(28):5817-5819. |
[16] | Yanwu Zhu;Shanthi Murali;Weiwei Cai;Xuesong Li;Ji Won Suk;Jeffrey R. Potts;Rodney S. Ruoff.Graphene and Graphene Oxide: Synthesis, Properties, and Applications[J].Advanced Materials,201035(35):3906-3924. |
[17] | 中国石墨烯产业技术创新战略联盟[J].中国科技产业,2014(8):27-27. |
[18] | Gurunathan, T.;Rao, C.R.K.;Narayan, R.;Raju, K.V.S.N..Polyurethane conductive blends and composites: Synthesis and applications perspective[J].Journal of Materials Science,20131(1):67-80. |
[19] | 唐征海;郭宝春;张立群;贾德民.石墨烯/橡胶纳米复合材料[J].高分子学报,2014(7):865-877. |
[20] | Wang, Han;Xie, Guiyuan;Fang, Minghe;Ying, Zhe;Tong, Yu;Zeng, You.Electrical and mechanical properties of antistatic PVC films containing multi-layer graphene[J].Composites, Part B. Engineering,2015Sep.(Sep.):444-450. |
[21] | 游峰;王东瑞.高介电性能石墨烯/聚合物纳米复合材料研究进展[J].高分子学报,2014(7):878-884. |
[22] | 于小雯;石高全.石墨烯/高分子复合薄膜的制备及应用[J].高分子学报,2014(7):885-895. |
[23] | 匡达;胡文彬.石墨烯复合材料的研究进展[J].无机材料学报,2013(03):235-246. |
[24] | Layek, R.K.;Nandi, A.K..A review on synthesis and properties of polymer functionalized graphene[J].Polymer: The International Journal for the Science and Technology of Polymers,201319(19):5087-5103. |
[25] | N Saravanan;R Rajasekar;S Mahalakshmi.Graphene and modified graphene-based polymer nanocomposites - A review[J].Journal of Reinforced Plastics and Composites,201412(12):1158-1170. |
[26] | Rajatendu Sengupta;Mithun Bhattacharya;S. Bandyopadhyay.A review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites[J].Progress in Polymer Science,20115(5):638-670. |
[27] | Sie Chin Tjong.Polymer Composites with Graphene Nanofillers: Electrical Properties and Applications[J].Journal of nanoscience and nanotechnology,20142(2):1154-1168. |
[28] | 张力;吴俊涛;江雷.石墨烯及其聚合物纳米复合材料[J].化学进展,2014(4):560-571. |
[29] | 赵冬梅;李振伟;刘领弟;张艳红;任德财;李坚.石墨烯/碳纳米管复合材料的制备及应用进展[J].化学学报,2014(2):185-200. |
[30] | 黄桂荣;刘洪波;杨丽;何月德;夏笑虹;陈惠.石墨烯/酚醛树脂纳米复合材料的热解行为[J].新型炭材料,2015(5):412-418,380. |
[31] | 张志毅;张焕;寿金泉;孙友谊;刘亚青.原位制备还原氧化石墨烯增强环氧树脂基复合材料及其形状记忆性能[J].新型炭材料,2015(5):404-411,379. |
[32] | Rohini, Rani;Katti, Prajakta;Bose, Suryasarathi.Tailoring the interface in graphene/thermoset polymer composites: A critical review[J].Polymer: The International Journal for the Science and Technology of Polymers,2015:A17-A34. |
[33] | John Texter.Graphene dispersions[J].Current opinion in colloid & interface science,20142(2):163-174. |
[34] | Evgeniy E. Tkalya;Marcos Ghislandi;Gijsbertus de With.The use of surfactants for dispersing carbon nanotubes and graphene to make conductive nanocomposites[J].Current opinion in colloid & interface science,20124(4):225-232. |
[35] | Xiaoqing Zhang;Chun Yan;Xinyu Fan.Interfacial Microstructure and Properties of Carbon Fiber Composites Modified with Graphene Oxide[J].ACS applied materials & interfaces,20123(3):1543-1552. |
[36] | JONATHAN N COLEMAN.Liquid Exfoliation of Defect-Free Graphene[J].Accounts of Chemical Research,20131(1):14-22. |
[37] | Bin Shen;Wentao Zhai;Mimi Tao;Dingding Lu;Wenge Zheng.Chemical functionalization of graphene oxide toward the tailoring of the interface in polymer composites[J].Composites science and technology,2013Mar.(Mar.):87-94. |
[38] | Li, Fei;Liu, Yu;Qu, Cheng-Bing;Xiao, Hong-Mei;Hua, Yang;Sui, Guo-Xin;Fu, Shao-Yun.Enhanced mechanical properties of short carbon fiber reinforced polyethersulfone composites by graphene oxide coating[J].Polymer: The International Journal for the Science and Technology of Polymers,2015:155-165. |
[39] | Kian Ping Loh;Qiaoliang Bao;Priscilla Kailian Ang.The chemistry of graphene[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,201012(12):2277-2289. |
[40] | 潘龙;刘一涛;谢续明.高性能石墨烯/聚合物纳米复合材料的研究进展--界面作用力的设计及其影响[J].高分子学报,2014(6):724-736. |
[41] | Sung Ho Song;Kwang Hyun Park;Bo Hyun Kim;Yong Won Choi;Gwang Hoon Jun;Dong Ju Lee;Byung-Seon Kong;Kyung-Wook Paik;Seokwoo Jeon.Enhanced Thermal Conductivity of Epoxy-Graphene Composites by Using Non-Oxidized Graphene Flakes with Non-Covalent Functionalization[J].Advanced Materials,20135(5):732-737. |
[42] | Robert J. Young;Ian A. Kinloch;Lei Gong;Kostya S. Novoselov.The mechanics of graphene nanocomposites: A review[J].Composites science and technology,201212(12):1459-1476. |
[43] | Chih-Chun Teng;Chen-Chi M. Ma;Chu-Hua Lu.Thermal conductivity and structure of non-covalent functionalized graphene/epoxy composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,201115(15):5107-5116. |
[44] | Qunfeng Cheng;Lei Jiang;Zhiyong Tang.Bioinspired Layered Materials with Superior Mechanical Performance[J].Accounts of Chemical Research,20144(4):1256-1266. |
[45] | Ming Yang;Ying Hou;Nicholas A. Kotov.Graphene-based multilayers: Critical evaluation of materials assembly techniques[J].Nano Today,20125(5):430-447. |
[46] | Xu, Z.;Gao, C..In situ polymerization approach to graphene-reinforced nylon-6 composites[J].Macromolecules,201016(16):6716-6723. |
[47] | Han Wang;Guiyuan Xie;Zhenguo Zhu.Enhanced tribological performance of the multi-layer graphene filled poly(vinyl chloride) composites[J].Composites, Part A. Applied science and manufacturing,2014:268-273. |
[48] | Han Wang;Guiyuan Xie;Zhe Ying;Yu Tong;You Zeng.Enhanced Mechanical Properties of Multi-layer Graphene Filled Poly(vinyl chloride) Composite Films[J].材料科学技术(英文版),2015(4):340-344. |
[49] | Nantao Hu;Liangming Wei;Yanyan Wang;Rungang Gao;Jing Chai;Zhi Yang;Eric Siu-Wai Kong;Yafei Zhang.Graphene Oxide Reinforced Polyimide Nanocomposites via In Situ Polymerization[J].Journal of nanoscience and nanotechnology,20121(1):173-178. |
[50] | Zhen Xu;Chao Gao.Graphene in Macroscopic Order: Liquid Crystals and Wet-Spun Fibers[J].Accounts of Chemical Research,20144(4):1267-1276. |
[51] | Jianfeng Zang;Seunghwa Ryu;Nicola Pugno.Multif unctionality and control of the crumpling and unfolding of large-area graphene[J].Nature materials,20134(4):321-325. |
[52] | Shang, Jin;Chen, Yuli;Zhou, Yanguang;Liu, Luqi;Wang, Guorui;Li, Xianglong;Kuang, Jun;Liu, Qing;Dai, Zhaohe;Miao, Hong;Zhi, Linjie;Zhang, Zhong.Effect of folded and crumpled morphologies of graphene oxide platelets on the mechanical performances of polymer nanocomposites[J].Polymer: The International Journal for the Science and Technology of Polymers,2015:131-139. |
[53] | Cui Mao;Yutian Zhu;Wei Jiang.Design of Electrical Conductive Composites: Tuning the Morphology to Improve the Electrical Properties of Graphene Filled Immiscible Polymer Blends[J].ACS applied materials & interfaces,201210(10):5281-5286. |
[54] | Hua Deng;Lin Lin;Mizhi Ji.Progress on the morphological control of conductive network in conductive polymer composites and the use as electroactive multifunctional materials[J].Progress in Polymer Science,20144(4):627-655. |
[55] | Jinhong Du;Long Zhao;You Zeng.Comparison of electrical properties between multi-walled carbon nanotube and graphene nanosheet/high density polyethylene composites with a segregated network structure[J].Carbon: An International Journal Sponsored by the American Carbon Society,20114(4):1094-1100. |
[56] | Mengkai Li;Chunxiao Gao;Hongliang Hu.Electrical conductivity of thermally reduced graphene oxide/polymer composites with a segregated structure[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:371-373. |
[57] | Zongping Chen;Wencai Ren;Libo Gao.Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J].Nature materials,20116(6):424-428. |
[58] | Bin Shen;Wentao Zhai;Dingding Lu.Fabrication of microcellular polymer/graphene nanocomposite foams[J].Polymer international,201212(12):1693-1702. |
[59] | Ngoc Hoang Vo;Trung Dung Dao;Jeong, Han Mo.Electrically Conductive Graphene/Poly(methyl methacrylate) Composites with Ultra-Low Percolation Threshold by Electrostatic Self-Assembly in Aqueous Medium[J].Macromolecular chemistry and physics,20157(7):770-782. |
[60] | Araby, Sherif;Meng, Qingshi;Zhang, Liqun;Zaman, Izzuddin;Majewski, Peter;Ma, Jun.Elastomeric composites based on carbon nanomaterials[J].Nanotechnology,201511(11) |
[61] | Ke Chu;Cheng-chang Jia;Wen-sheng Li.Effective thermal conductivity of graphene-based composites[J].Applied physics letters,201212(12):121916-1-121916-3. |
[62] | Chu, K.;Li, W.-S.;Dong, H..Role of graphene waviness on the thermal conductivity of graphene composites[J].Applied physics, A. Materials science & processing,20131(1):221-225. |
[63] | Noh, Ye Ji;Kim, Seong Yun.Synergistic improvement of thermal conductivity in polymer composites filled with pitch based carbon fiber and graphene nanoplatelets[J].Polymer Testing,2015:132-138. |
[64] | Wegrzyn, Marcin;Ortega, Amaya;Benedito, Adolfo;Gimenez, Enrique.Thermal and electrical conductivity of melt mixed polycarbonate hybrid composites co-filled with multi-walled carbon nanotubes and graphene nanoplatelets[J].Journal of Applied Polymer Science,201537/38(37/38) |
[65] | Kyhl, Line;Nielsen, Sune Fuglsang;Cabo, Antonija Grubisic;Cassidy, Andrew;Miwa, Jill A.;Hornekaer, Liv.Graphene as an anti-corrosion coating layer[J].Faraday discussions,2015:495-509. |
[66] | Hongping Li;Lin Chen;Yi Zhang;Xiaorui Ji;Shuai Chen;Haojie Song;Changsheng Li;Hua Tang.Synthesis of MoSe_2/Reduced graphene oxide composites with improved tribological properties for oil-based additives[J].Crystal Research and Technology: Journal of Experimental and Industrial Crystallography,20144(4):204-211. |
[67] | Dittrich, B.;Wartig, K.-A.;Hofmann, D.;Mülhaupt, R.;Schartel, B..Flame retardancy through carbon nanomaterials: Carbon black, multiwall nanotubes, expanded graphite, multi-layer graphene and graphene in polypropylene[J].Polymer Degradation and Stability,20138(8):1495-1505. |
[68] | Ping'an Song;Youming Yu;Tao Zhang.Permeability, Viscoelasticity, and Flammability Performances and Their Relationship to Polymer Nanocomposites[J].Industrial & Engineering Chemistry Research,201221(21):7255-7263. |
[69] | Deng, Chao;Jiang, Jianjun;Liu, Fa;Fang, Liangchao;Wang, Junbiao;Li, Dejia;Wu, Jianjun.Effects of electrophoretically deposited graphene oxide coatings on interfacial properties of carbon fiber composite[J].Journal of Materials Science,201517(17):5886-5892. |
[70] | Deng, Chao;Jiang, Jianjun;Liu, Fa;Fang, Liangchao;Wang, Junbiao;Li, Dejia;Wu, Jianjun.Influence of graphene oxide coatings on carbon fiber by ultrasonically assisted electrophoretic deposition on its composite interfacial property[J].Surface & Coatings Technology,2015:176-181. |
[71] | Juan Chen;Dan Zhao;Xin Jin;Cuicui Wang;Dongzhi Wang;Heyi Ge.Modifying glass fibers with graphene oxide: Towards high-performance polymer composites[J].Composites science and technology,2014Jun.16(Jun.16):41-45. |
[72] | Kamar, Nicholas T.;Hossain, Mohammad Mynul;Khomenko, Anton;Haq, Mahmood;Drzal, Lawrence T.;Loos, Alfred.Interlaminar reinforcement of glass fiber/epoxy composites with graphene nanoplatelets[J].Composites, Part A. Applied science and manufacturing,2015:82-92. |
[73] | 刘国强;石福志;李耀刚;张青红;王宏志.石墨烯包覆玻璃纤维复合材料的制备及其电学性能研究[J].无机材料学报,2015(07):763-768. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%