为了研究硼化物(KBF4)和锶(Sr)对再生Al-Si合金中富铁相的影响,分别采用X射线荧光光谱分析仪(XRF)对试样进行成分分析,应用光学显微镜(OM)、扫描电镜(SEM)和能谱仪(EDS)对试样显微组织进行形貌观察和相成分分析.结果表明,KBF4不能起到降铁作用,但促使β-Fe相向初生α-Fe相转变,当B加入量达到0.75%时,初生α-Fe相周围出现了汉字状α-Fe相;Sr会促使β-Fe相向汉字状α-Fe相转变,当Sr加入量为0.3%时,β-Fe相几乎消失,同时,Sr对针状β-Fe相有溶解碎裂作用.
参考文献
[1] | Humberto Lopes de Moraes;Jose Roberto de Oliveira;Denise Crocce Romano Espinosa.Removal of Iron from Molten Recycled Aluminum through Intermediate Phase Filtration[J].Materials transactions,20067(7):1731-1736. |
[2] | 杨怀德;龙思远;吴明放;范超;吴星宇.硼化物、锰去除再生Al-Si合金中铁元素机理研究[J].稀有金属材料与工程,2015(3):621-627. |
[3] | 周敬恩;冉广.A356铸造铝合金的疲劳裂纹萌生及短裂纹扩展研究[J].金属热处理,2008(1):34-42. |
[4] | M. Mahta;M. Emamy;A. Daman;A. Keyvani;J. Campbell.Precipitation of Fe rich intermetallics in Cr- and Co-modified A413 alloy[J].International Journal Cast Metals Research,20052(2):73-79. |
[5] | 李海;史志欣;王芝秀;王秀丽;郑子樵.Mn和Cr对Al-Mg-Si-Cu合金组织及性能的影响[J].材料热处理学报,2011(10):100-105. |
[6] | S.G. Shabestari.The effect of iron and manganese on the formation of intermetallic compounds in aluminum-silicon alloys[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20042(2):289-298. |
[7] | J.W. Gao;D. Shu;J. Wang;B.D. Sun.Effects of Na2B4O7 on the elimination of iron from aluminum melt[J].Scripta materialia,20073(3):197-200. |
[8] | F.H.Samuel P.Ouellet.Effect of Mg and Sr Additions on the Formation of Intermetallics in Al-6 Wt Pct Si-3.5 Wt Pct Cu-(0.45) to (0.8) Wt Pct Fe 319-Type Alloys[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,199812(12):2871-2884. |
[9] | Samuel AM.;Doty HW.;Samuel FH..OBSERVATIONS ON THE FORMATION OF BETA-AL5FESI PHASE IN 319 TYPE AL-SI ALLOYS[J].Journal of Materials Science,199620(20):5529-5539. |
[10] | X. CAO;J. CAMPBELL.The Nucleation of Fe-Rich Phases on Oxide Films in Al-11.5Si-0.4Mg Cast Alloys[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,20037(7):1409-1420. |
[11] | 范超;龙思远;杨怀德;王向杰;张均成.Mn和Ce对再生Al-Si合金富铁相的影响[J].稀有金属材料与工程,2014(3):660-664. |
[12] | J. W. Gao;M. X. Xie;M. X. Xia.Effects of boron and lanthanum on the impurity iron in aluminium melts[J].Transactions of the Institutions of Mining and Metallurgy, Section C. Mineral Processing and Extractive Metallurgy,20113(3):172-176. |
[13] | Xinjin Cao;John Campbell.Morphology of β-Al{sub}5FeSi Phase in Al-Si Cast Alloys[J].Materials transactions,20065(5):1303-1312. |
[14] | Lifeng Zhang;Jianwei Gao;Lucas Nana Wiredu Damoah;David G. Robertson.REMOVAL OF IRON FROM ALUMINUM: A REVIEW[J].Mineral Processing and Extractive Metallurgy Review,20121/6(1/6):99-157. |
[15] | 于金;蒋建清;方峰;董岩;谈荣生;吴三械.真空铝热还原法制备金属Sr的热力学分析及实验研究[J].金属学报,2005(8):824-828. |
[16] | 葛学元;李建国;谭红艳;何迁.A356合金熔体中Al2O3夹杂对变质剂Sr的影响[J].铸造,2008(1):49-52. |
[17] | 范学义;董允;林晓娉;王铁宝;李丹;万志永;李娅珍.A356铝合金Al-5Ti-1B和Al-10Sr熔体处理遗传效应[J].材料热处理学报,2010(2):90-94. |
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