综述了硬硅钙石材料制备的研究现状,重点对纳米硬硅钙石的制备方法、合成过程中的影响因素及应用进展进行了分析:合成纳米硬硅钙石的方法主要有水热法、微乳液法、微波辅助法、化学沉淀法；适量的Mg、Na离子及化学外加剂CaCl2、Sr(NO3)2、ZrOCl2·8H2O、C2S等有助于纳米硬硅钙石的生成；Al离子会阻碍产物硬硅钙石的生成.最后对纳米硬硅钙石制备及应用中存在的问题和今后的研究提出了建议.
参考文献
| [1] | Shaw S.;Henderson CMB.;Clark SM. .Hydrothermal formation of the calcium silicate hydrates, tobermorite (Ca5Si6O16(OH)(2)center dot 4H(2)O) and xonotlite (Ca6Si6O17(OH)(2)): an in situ synchrotron study[J].Chemical geology,2000(1/2):129-140. |
| [2] | L Black;K. Garbev;A. Stumm .Structure, bonding and morphology of hydrothermally synthesised xonotlite[J].Advances in Applied Ceramics,2009(3):137-144. |
| [3] | 郑远林;张吉元;蒋智.动态水热合成硬硅钙石的反应历程研究[J].中国建筑材料科学研究院学报,1991(04):20. |
| [4] | Yanagisawa K et al.Hydrothermal synthesis of xonotlite whiskers by ion diffusion[J].Journal of Materials Science Letters,1997,16:889. |
| [5] | L.Z. Pei;L.J. Yang;Y. Yang;C.G. Fan;W.Y. Yin;J. Chen;Q.F. Zhang .A green and facile route to synthesize calcium silicate nanowires[J].Materials Characterization,2010(11):1281-1285. |
| [6] | Fei L;Lingke Z;Cao J et al.Preparation of ultra-light xonotlite thermal insulation material using carbide slag[J].J Wuhan University Techn:Mater Sci Ed,2010,25(02):295. |
| [7] | Li XK;Chang J .A novel hydrothermal route to the synthesis of xonotlite nanofibers and investigation on their bioactivity[J].Journal of Materials Science,2006(15):4944-4947. |
| [8] | Microwave-assisted preparation of Ca_6Si_6O_(17)(0H)2 and β-CaSiO_3 nanobelts[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2010(4):509. |
| [9] | Lin KL;Chang J;Chen GF;Ruan ML;Ning CQ .A simple method to synthesize single-crystalline beta-wollastonite nanowires[J].Journal of Crystal Growth,2007(2):267-271. |
| [10] | 林开利 .纳米磷酸钙、硅酸钙及其复合生物与环境材料的制备和性能研究[D].华东师范大学,2008. |
| [11] | Qian G;Xu G;Li H et al.Mg-xonotlite and its coexisting phases[J].Cement and Concrete Research,1997,27(03):315. |
| [12] | 徐光亮;赖振宇;钱光人.CaO-SiO2-MgO-H2O体系的热力学研究[J].西南工学院学报,1999(03):1. |
| [13] | 范付忠,钱光人,赖振宇,徐光亮.CaO-MgO-SiO2-H2O体系的热力学基础研究[J].硅酸盐通报,2001(01):18-23,17. |
| [14] | 范付忠;钱光人;赖振宇.水热条件下CaO-MgO-SiO2-H2O体系中反应物的竞争与产物的转化机制[J].西南工学院学报,2000(04):1. |
| [15] | Nocun-Wczelik W .Effect of some inorganic admixtures on the formation and properties of calcium silicate hydrates produced in hydrothermal conditions[J].Cement and Concrete Research,1997,27(01):83. |
| [16] | Liu F;Cao J;Zhu B.Effect of anion impurity on preparing xonotlite whiskers via hydrothermal synthesis[A].Shenzhen:Trans Techn Publications,2011 |
| [17] | Nocuò-Wczelik W .Effect of Na and Al on the phase composition and morphology of autoclaved calcium silicate hydrates[J].Cement and Concrete Research,1999,29(11):1759. |
| [18] | Nelson E B;Kalousek G L .Effects of Na2O on calcium silicate hydrates at elevated temperatures[J].Cement and Concrete Research,1977,7(06):687. |
| [19] | 王坤英,李建平,肖晋宜,史珂,倪文.添加剂对制备纳米直径硬硅钙石纤维的影响[J].新型建筑材料,2007(02):43-45. |
| [20] | 陈淑祥,倪文,江翰,董文辉.几种锆类化合物添加剂对硬硅钙石形貌的影响[J].矿产综合利用,2005(01):24-28. |
| [21] | Tashiro C;Kawaguchi K .Effects of the CaO/SiO2 ratio and Cr2O3 on the hydrothermal synthesis of xonotlite[J].Cement and Concrete Research,1977,7(01):69. |
| [22] | 倪文;曹贞源;舒先林.C2S对硬硅钙石型硅酸钙保温材料质量影响[J].北京科技大学学报,1996(06):495. |
| [23] | Baltakys K .Influence of gypsum additive on the formation of calcium silicate hydrates in mixtures with C/S =0.83 or 1.0[J].Mater Sci Poland,2009,27(04):1091. |
| [24] | 段雪;王作新;詹洪.反应条件与硅酸钙水合晶体的生长规律[J].北京化工学院学报(自然科学版),1992(01):65. |
| [25] | 孙国匡;赵宇平.CaO-SiO2-Al2O3-H2O系统中和压蒸制品有关的水化产物的研究[J].硅酸盐学报,1983(02):149. |
| [26] | Nicola Meller;Christopher Hall;Jonathan S. Phipps .A new phase diagram for the CaO-Al_2O_3-SiO_2-H_2O hydroceramic system at 200℃[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2005(5):715-723. |
| [27] | Sergey V. Churakov;Peter Mandaliev .Structure of the hydrogen bonds and silica defects in the tetrahedral double chain of xonotlite[J].Cement and Concrete Research,2008(3):300-311. |
| [28] | Udawatte C.P.;Yanagisawa K. .Solidification of xonotlite fibers with chitosan by hydrothermal hot pressing[J].Materials Letters,2000(6):298-301. |
| [29] | Komarneni S;Breval E;Roy D M et al.Reactions of some calcium silicates with metal cations[J].Cement and Concrete Research,1988,18(02):204. |
| [30] | 韩剑宏,倪文,于衍真.硬硅钙石二次粒子对含铅废水处理效果的影响研究[J].环境污染治理技术与设备,2006(01):22-25. |
| [31] | Mandaliev, P.;D?hn, R.;Tits, J.;Wehrli, B.;Wieland, E. .EXAFS study of Nd(III) uptake by amorphous calcium silicate hydrates (C-S-H)[J].Journal of Colloid and Interface Science,2010(1):1-7. |
| [32] | Mandaliev, P.;Wieland, E.;D?hn, R.;Tits, J.;Churakov, S.V.;Zaharko, O. .Mechanisms of Nd(III) uptake by 11? tobermorite and xonotlite[J].Applied Geochemistry: Journal of the International Association of Geochemistry and Cosmochemistry,2010(6):763-777. |
| [33] | Shrivastava O P;Komarment S;Breval E .Mg2+ uptake by synthetic tobermorite and xonotlite[J].Cement and Concrete Research,1991,21(01):83. |
| [34] | Takahashi K;Yamasaki N;Mishima K et al.Coating of pulp fiber with xonotlite under hydrothermal conditions[J].Journal of Materials Science Letters,2002,21(19):1521. |
| [35] | Souma I;Wakano H .Studies on the combustion of the PVC-xonotlite composite system[J].JOURNAL OF FIRE & FLAMMABILITY,1979,10:129. |
| [36] | JIANG Jinguo,CUI Chong,LIU Jinqiang,LIAO Wenli.Hydrothermal Synthesis of Xonotlite-type Calcium Silicate Insulation Material Using Industrial Zirconium Waste Residue[J].武汉理工大学学报（材料科学版）（英文版）,2011(03):519-522. |
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