本文采用数据协同方法,研究了由于模型参数和实验测量不确定度传递导致的H2/CO详细化学动力学模型预测的不确定性.研究发现在数据集中增加一组H2/O2/CO2混合物在1.5 MPa时层流火焰传播速度实验测量值,数据集出现不一致,并分析了两种有可能导致数据集不一致的原因.研究结果还表明,选择性的增加实验目标,能有效地约束模型参数不确定性空间,提高模型预测性能,并为实验研究提供引导.
参考文献
[1] | JUAN LI;ZHENWEI ZHAO;ANDREI KAZAKOV .A Comprehensive Kinetic Mechanism for CO,CH2O,and CH3OH Combustion[J].International Journal of Chemical Kinetics,2007(3):109-136. |
[2] | A. Frassoldati;T. Faravelli;E. Ranzi .The ignition, combustion and flame structure of carbon monoxide/hydrogen mixtures. Note 1: Detailed kinetic modeling of syngas combustion also in presence of nitrogen compounds[J].International journal of hydrogen energy,2007(15):3471-3485. |
[3] | Negative pressure dependence of mass burning rates of H_2/CO/O_2/diluent flames at low flame temperatures[J].Combustion and Flame,2010(4):618. |
[4] | Ryan Feeley;Pete Seiler;Andrew Packard;Michael Frenklach .Consistency of a Reaction Dataset[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2004(44):9573-9583. |
[5] | Michael Frenklach .Collaborative data processing in developing predictive models of complex reaction systems[J].International Journal of Chemical Kinetics,2004(1):57-66. |
[6] | Feeley R;Frenklach M;Onsum M;Russi T;Arkin A;Packard A .Model discrimination using data collaboration[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2006(21):6803-6813. |
[7] | XIAOQING YOU;ANDREW PACKARD;MICHAEL FRENKLACH .Process Informatics Tools for Predictive Modeling: Hydrogen Combustion[J].International Journal of Chemical Kinetics,2012(2):101-116. |
[8] | Russi T;Packard A;Feeley R;Frenklach M .Sensitivity analysis of uncertainty in model prediction[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2008(12):2579-2588. |
[9] | You XQ;Wang H;Goos E;Sung CJ;Klippenstein SJ .Reaction kinetics of CO+HO2 -> products: Ab initio transition state theory study with master equation modeling[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2007(19):4031-4042. |
[10] | AMEYA V.JOSHI;HAI WANG .Master Equation Modeling of Wide Range Temperature and Pressure Dependence of CO + OH ->Products[J].International Journal of Chemical Kinetics,2006(1):57-73. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%