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Se量是影响CIGS薄膜生长的重要因素之一.本实验利用三步共蒸法在不同Se量常温下沉积CIGS薄膜,而后对衬底分三步在不同温度下真空退火,采用扫描电子显微镜(SEM)和能量散射谱(EDS)观察和分析了薄膜的表面形貌和元素成分,采用X射线衍射仪(XRD)表征了薄膜的组织结构,采用紫外可见分光光度计(UV)研究了薄膜的光学性质,结果表明真空退火下Se量应严格控制在Culn0.7 Ga0.3 Se2化学计量比范围内,这样有利于制备出较高吸收率的CIGS薄膜.

参考文献

[1] Ahn S;Kim C;Yun J;Lee J;Yoon K .Effects of heat treatments on the properties of Cu(In,Ga)Se-2 nanoparticles[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2007(19):1836-1841.
[2] Sung-Ho Han;Falah S. Hasoon;Allen M. Hermann;Dean H. Levi .Spectroscopic evidence for a surface layer in CuInSe_(2):Cu deficiency[J].Applied physics letters,2007(2):021904-1-021904-3-0.
[3] Philip Jackson;Roland Wurz;Uwe Rau .High Quality Baseline for High Efficiency, Cu(In_(1-x), Ga_x)Se_2 Solar Cells[J].Progress in photovoltaics,2007(6):507-519.
[4] M. Venkatachalam;M.D. Kannan;S. Jayakumar;R. Balasundaraprabhu;N. Muthukumarasamy .Effect of annealing on the structural properties of electron beam deposited CIGS thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2008(20):6848-6852.
[5] C. Lei;C. M. Li;A. Rockett;I. M. Robertson .Grain boundary compositions in Cu(InGa)Se_(2)[J].Journal of Applied Physics,2007(2):024909-1-024909-7-0.
[6] Miguel A. Contreras;Manuel J. Romero;R. Noufi .Characterization of Cu(In,Ga)Se_2 materials used in record performance solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(7):51-54.
[7] A. Rockett .The electronic effects of point defects in Cu(In{sub}xGa{sub}(1-x))Se{sub}2[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2000(0):330-337.
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