利用SEM和XRD研究了无磁场和2 T~10 T强磁场中电流密度和磁感应强度对铜电沉积层表面形貌及择优取向的影响.结果表明:无磁场下,表面晶粒随电流密度增加而增大,同时伴随氢气析出而导致气孔出现,施加10 T磁场后,表面晶粒随电流密度增加呈分裂细化趋势,同时氢气析出被抑制.强磁场施加使(220)晶面织构得到抑制,而(111),(200),(311)等晶面的织构得到增强,但无论是否施加磁场,在200A/m2~630A/m2的电流密度下,铜电沉积层仍保持(220)的优先生长方向.
参考文献
[1] | Fahidy T Z .[J].Journal of Applied Electrochemistry,1983,13:553. |
[2] | Chopart J P;Douglade J;Fricoteaux P et al.[J].Electrochimica Acta,1991,36:459. |
[3] | Noninski V C .[J].Electrochimica Acta,1997,42:251. |
[4] | Reilly C O;Hind G;Coey J M D .[J].Journal of the Electrochemical Society,2001,148:C674. |
[5] | Hinds G;Coey J M D;Lyons M E G .[J].Electrochemistry Communications,2001,3:215. |
[6] | Devos O;Omar A;Chopart J P et al.[J].Journal of Physical Chemistry A,2000,104:1544. |
[7] | Eugene J K .[J].Journal of the Electrochemical Society,1977,124:987. |
[8] | Hinds G;Coey J M D;Lyons M E G .[J].Electrochemistry Communications,2001,3:215. |
[9] | Aaboubi O;Chopart J P;Douglade J et al.[J].Journal of the Electrochemical Society,1990,137:1796. |
[10] | Devos O;Aaboubi O;Chopart J P et al.[J].Journal of the Electrochemical Society,1998,145:4135. |
[11] | Tronel-Peyroz E;Olivier A;Laforgue-Kantzer D .[J].Electrochimica Acta,1977,22:145. |
[12] | Chiba A;Hosokawa A;Ogawa T .[J].SURFACE AND COATINGS TECHNOLOGY,1986,27:131. |
[13] | Devos O;Olivier A;Chopart J P et al.[J].Journal of the Electrochemical Society,1998,145:401. |
[14] | Ismail M I;Fahidy T Z .[J].Journal of Applied Electrochemistry,1981,11:543. |
[15] | 周绍民.金属电沉积-原理与研究方法[M].上海:上海科学技术出版社,1987:242. |
[16] | 辜敏;杨防祖;黄令 et al.[J].物理学报,2002,18:973. |
[17] | Li D Y;Szpunar J A .[J].Electrochimica Acta,1997,42:37. |
[18] | Ye Xingpu;De Bonte M;Celis J P et al.[J].JOURNAL OF THE ELECTROCHEMICAL SOCIETY,1992,39:1592. |
[19] | 许书楷.电沉积条件对锌镀层织构的影响[J].电化学,1995(04):408. |
[20] | Dash J;King W W .[J].JOURNAL OF THE ELECTROCHEMICAL SOCIETY,1972,19:51. |
[21] | Devos;Aaboubi O;Chopart J P et al.[J].Journal of Physical Chemistry A,2000,104:1544. |
[22] | Mogi I.;Kamiko M. .STRIKING EFFECTS OF MAGNETIC FIELD ON THE GROWTH MORPHOLOGY OF ELECTROCHEMICAL DEPOSITS[J].Journal of Crystal Growth,1996(1/4):276-280. |
[23] | Oreper G M;Szekely J .[J].JOURNAL OF CRYSTAL GROWTH,1983,64:505. |
[24] | Chassaing E;Wiart R .[J].Electrochimica Acta,1984,29:649. |
[25] | 查全性.电极过程动力学导论[M].北京:中国科学技术出版社,2002 |
[26] | 钟云霄.热力学与统计物理[M].北京:中国科学技术出版社,1988:82. |
[27] | 王晖,任忠鸣,徐匡迪,黄晖,王秋良,严陆光.纯物质凝固的磁场热力学分析[J].中国有色金属学报,2004(06):945-948. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%