以邻氨基苯硫酚、苯甲酰氯为起始原料,通过与三氯化铱配合反应,合成了一种新型金属铱的(2-苯基苯并噻唑)配合物(bt)2Ir(acac),产率为45.47%,熔点为303～304℃.通过质谱、元素分析及红外光谱对其结构进行了表征,并对其光致发光性质进行了研究.研究表明,配合物在350～450nm存在单线态和三线态金属铱到配体的电荷跃迁,在566.0 nm处有强的金属配合物三线态磷光发射,配合物(bt)2Ir(acac)是一种新型的磷光材料.
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