开发掺杂改性的碳材料用作燃料电池的非贵金属氧还原催化剂已成为燃料电池领域的重要研究课题，相关研究对于降低燃料电池成本、促进燃料电池的商业化具有十分重要的意义。大量研究工作表明，对碳材料进行掺杂改性可以实现其形貌、微观结构、组成及其他表面物理化学性质的优化，从而得到具有较高催化活性、选择性和稳定性的氧还原催化剂。人们在这类催化剂的制备方法、性能优化和催化机理等方面进行了大量研究工作。综述了对碳纳米管、石墨烯、介孔碳、大孔碳、碳微球等碳材料进行掺杂改性的最新进展。并基于目前的研究结果，展望了掺杂碳材料作为燃料电池非贵金属氧还原催化剂的应用前景和未来的发展趋势。
ABSTRACT:It is becoming one of the most important topics in the fuel cell field to develop doped/modified carbon materials as non-precious-metal catalysts for oxygen reduction, which will effectively reduce the cost of fuel cell and promote the commercializa-tion of the fuel cells. It has been demonstrated by a lot of researches that the microstructures, compositions and other superficial physicochemical properties can be improved and optimized through the doping modification of carbon materials, thus resulting in ox-ygen reduction catalysts with excellent catalytic activity, selectivity and stability. A considerable amount of researches have been done in the preparation methods, performance optimization and catalytic mechanism of this type of catalysts. In this paper, the lat-est research progresses in the doping modification of carbon materials, such as carbon nanotube, graphene, mesoporous carbons, macroporous carbons and carbon microspheres, were reviewed. Based on the results achieved, we proposed their application pros-pects as catalysts in fuel cell, as well as the developing trend of the doped carbon catalyst in the future.
参考文献
| [1] | Mark K. Debe .Electrocatalyst approaches and challenges for automotive fuel cells[J].Nature,2012(Jun.7 TN.7401):43-51. |
| [2] | Zhongwei Chen;Drew Higgins;Aiping Yu;Lei Zhang;Jiujun Zhang .A review on non-precious metal electrocatalysts for PEM fuel cells[J].Energy & environmental science: EES,2011(9):3167-3192. |
| [3] | UDAY N;WON J;JU M et al.Chemically Modified/Doped Carbon Nanotubes & Graphene for Optimized Nanostruc-tures & Nanodevices[J].Advanced Materials,2014,26:40-67. |
| [4] | Nitrogen-doped Carbon Nanotube Arrays With High Electrocatalytic Activity For Oxygen Reduction[J].Science,2009(Feb.6 TN.5915):760. |
| [5] | Yu, D.;Zhang, Q.;Dai, L. .Highly efficient metal-free growth of nitrogen-doped single-walled carbon nanotubes on plasma-etched substrates for oxygen reduction[J].Journal of the American Chemical Society,2010(43):15127-15129. |
| [6] | Shuangyin Wang;Eswaramoorthi Iyyamperumal;Ajit Roy .Vertically Aligned BCN Nanotubes as Efficient Metal-Free Electrocatalysts for the Oxygen Reduction Reaction: A Synergetic Effect by Co-Doping with Boron and Nitrogen[J].Angewandte Chemie,2011(49):11756-11760. |
| [7] | Lijun Yang;Shujuan Jiang;Yu Zhao .Boron-Doped Carbon Nanotubes as Metal-Free Electrocatalysts for the Oxygen Reduction Reaction[J].Angewandte Chemie,2011(31):7132-7135. |
| [8] | ZHU J;JIANG S;WANG R et al.One-pot Synthesis of a Nitrogen and Phosphorusdual-doped Carbon Nanotube Array as a Highly Effective Electrocatalyst for the Oxygen Reduc-tion Reaction[J].Journal of Materials Chemistry A,2014,2:15448-15453. |
| [9] | Xingbang Hu;Youting Wu;Haoran Li .Adsorption and Activation of O2 on Nitrogen-Doped Carbon Nanotubes[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(21):9603-9607. |
| [10] | Liang, Y.;Wang, H.;Diao, P.;Chang, W.;Hong, G.;Li, Y.;Gong, M.;Xie, L.;Zhou, J.;Wang, J.;Regier, T.Z.;Wei, F.;Dai, H. .Oxygen reduction electrocatalyst based on strongly coupled cobalt oxide nanocrystals and carbon nanotubes[J].Journal of the American Chemical Society,2012(38):15849-15857. |
| [11] | Dehui Deng;Liang Yu;Xiaoqi Chen .Iron Encapsulated within Pod-like Carbon Nanotubes for Oxygen Reduction Reaction[J].Angewandte Chemie,2013(1):371-375. |
| [12] | CHUNG H T;WON J H;ZELENAY P .Active and Stable Carbon Nanotube/Nanoparticle Composite Electrocatalyst for Oxygen Reduction[J].Nature Communications,2013,4(1922):1-5. |
| [13] | Ismail Hijazi;Tiphaine Bourgeteau;Renaud Cornut;Adina Morozan;Arianna Filoramo;Jocelyne Leroy;Vincent Derycke;Bruno Jousselme;Stéphane Campidelli .Carbon Nanotube-Templated Synthesis of Covalent Porphyrin Network for Oxygen Reduction Reaction[J].Journal of the American Chemical Society,2014(17):6348-6354. |
| [14] | Ping-Jie Wei;Guo-Qiang Yu;Yoshinori Naruta .Covalent Grafting of Carbon Nanotubes with a Biomimetic Heme Model Compound To Enhance Oxygen Reduction Reactions[J].Angewandte Chemie,2014(26):6659-6663. |
| [15] | WANG X;SUN G;PARIMAL R et al.Heteroatom-doped Graphene Materials:Syntheses,Properties and Applications[J].Chemical Society Reviews,2014,43:7067-7098. |
| [16] | Qu, L.;Liu, Y.;Baek, J.-B.;Dai, L. .Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells[J].ACS nano,2010(3):1321-1326. |
| [17] | Wei Ding;Zidong Wei;Siguo Chen .Space-Confinement-Induced Synthesis of Pyridinic- and Pyrrolic-Nitrogen-Doped Graphene for the Catalysis of Oxygen Reduction[J].Angewandte Chemie,2013(45):11755-11759. |
| [18] | Yuanjian Zhang;Keisuke Fugane;Toshiyuki Mori .Wet chemical synthesis of nitrogen-doped graphene towards oxygen reduction electrocatalysts without high-temperature pyrolysis[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(14):6575-6580. |
| [19] | Sheng, Z.-H.;Shao, L.;Chen, J.-J.;Bao, W.-J.;Wang, F.-B.;Xia, X.-H. .Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis[J].ACS nano,2011(6):4350-4358. |
| [20] | YANG S;ZHI L;TANG K et al.Efficient Synthesis of He-teroatom(N or S)-doped Graphene Based on Ultrathin Gra-phene Oxide-porous Silica Sheets for Oxygen Reduction Re-actions[J].Advanced Functional Material,2012,22(17):3634-3640. |
| [21] | Yan Jiao;Yao Zheng;Mietek Jaroniec;Shi Zhang Qiao .Origin of the Electrocatalytic Oxygen Reduction Activity of Graphene-Based Catalysts: A Roadmap to Achieve the Best Performance[J].Journal of the American Chemical Society,2014(11):4394-4403. |
| [22] | Yang, Z.;Yao, Z.;Li, G.;Fang, G.;Nie, H.;Liu, Z.;Zhou, X.;Chen, X.;Huang, S. .Sulfur-doped graphene as an efficient metal-free cathode catalyst for oxygen reduction[J].ACS nano,2012(1):205-211. |
| [23] | JEON I;CHOI H;CHOI M et al.Facile,Scalable Synthesis of Edge-halogenated Grapheme Nanoplatelets as Efficient Metal-free Eletrocatalysts for Oxygen Reduction Reaction[J].Scientific Report,2013,3(1810):1-7. |
| [24] | Yongye Liang;Yanguang Li;Hailiang Wang .Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction[J].Nature materials,2011(10):780-786. |
| [25] | WU Z;YANG S;SUN Y et al.3D Nitrogen-doped Graphene Aerogel-supported Fe3 O4 Nanoparticles as Efficient Electro-catalysts for the Oxygen Reduction Reaction[J].Journal of the American Chemical Society,2012,134(22):9082-9085. |
| [26] | JIANG Y;LU Y;LV X et al.Enhanced Catalytic Perfor-mance of Pt-free Iron Phthalocyanine by Graphene Support for Efficient Oxygen Reduction Reaction[J].ACS Cataly-sis,2013,3:1263-1271. |
| [27] | Zheng, Y.;Jiao, Y.;Chen, J.;Liu, J.;Liang, J.;Du, A.;Zhang, W.;Zhu, Z.;Smith, S.C.;Jaroniec, M.;Lu, G.Q.;Qiao, S.Z. .Nanoporous graphitic-C _3N _4@carbon metal-free electrocatalysts for highly efficient oxygen reduction[J].Journal of the American Chemical Society,2011(50):20116-20119. |
| [28] | Ruili Liu;Dongqing Wu;Xinliang Feng .Nitrogen-Doped Ordered Mesoporous Graphitic Arrays with High Electrocatalytic Activity for Oxygen Reduction[J].Angewandte Chemie,2010(14):2565-2569. |
| [29] | JAE Y;TAEYOUNG K;YONGMAN C et al.Ordered Meso-porous Porphyrinic Carbons with Very High Electrocatalytic Activity for the Oxygen Reduction Reaction[J].Scientific Report,2013,3(2715):1-8. |
| [30] | Ji Liang;Yan Jiao;Mietek Jaroniec .Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance[J].Angewandte Chemie,2012(46):11496-11500. |
| [31] | Yang, D.-S.;Bhattacharjya, D.;Inamdar, S.;Park, J.;Yu, J.-S. .Phosphorus-doped ordered mesoporous carbons with different lengths as efficient metal-free electrocatalysts for oxygen reduction reaction in alkaline media[J].Journal of the American Chemical Society,2012(39):16127-16130. |
| [32] | Silva, R.;Voiry, D.;Chhowalla, M.;Asefa, T. .Efficient metal-free electrocatalysts for oxygen reduction: Polyaniline-derived N- and O-doped mesoporous carbons[J].Journal of the American Chemical Society,2013(21):7823-7826. |
| [33] | Yang, W.;Fellinger, T.-P.;Antonietti, M. .Efficient metal-free oxygen reduction in alkaline medium on high-surface-area mesoporous nitrogen-doped carbons made from ionic liquids and nucleobases[J].Journal of the American Chemical Society,2011(2):206-209. |
| [34] | Ji Liang;Yao Zheng;Jun Chen .Facile Oxygen Reduction on a Three-Dimensionally Ordered Macroporous Graphitic C3N4/Carbon Composite Electrocatalyst[J].Angewandte Chemie,2012(16):3892-3896. |
| [35] | Kelong Ai;Yanlan Liu;Changping Ruan;Lehui Lu;Caoqing (Max) Lu .Sp~2 C-Dominant N-Doped Carbon Sub-micrometer Spheres with a Tunable Size: A Versatile Platform for Highly Efficient Oxygen-Reduction Catalysts[J].Advanced Materials,2013(7):998-1003. |
| [36] | Chenghang You;Shijun Liao;Hualing Li.Uniform nitrogen and sulfur co-doped carbon nanospheres as catalysts for the oxygen reduction reaction[J].Carbon: An International Journal Sponsored by the American Carbon Society,2014:294-301. |
| [37] | Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells[J].Science,2009(Apr.3 TN.5923):71. |
| [38] | PROIETTI E;JAOUEN F;LEFèVRE M et al.Iron-based Cathode Catalyst with Enhanced Power Density in Polymer Electrolyte Membrane Fuel Cells[J].Nature Communica-tions,2011,2:416-424. |
| [39] | WU G;ARTYUSHKOVA K;FERRANDON M et al.Per-formance Durability of Polyaniline-derived Non-precious Cathode Catalysts[J].ECS Transactions,2009,25(01):1299-1311. |
| [40] | Gang Wu;Karren L. More;Christina M. Johnston;Piotr Zelenay .High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt[J].Science,2011(Apr.22 TN.6028):443-447. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%