碳-碳键型活性自由基聚合引发体系的研究现状

高分子材料科学与工程, 2004, 20(2): 32-39.

碳-碳键型活性自由基聚合引发体系的研究现状

姚献东 ^1, , 祁茵 ^2, , 季根忠 ^3, , 孙旭东 ^4, , 王芸 ^5, , 郑小明 ^6, , 齐陈泽 ^7,

1.绍兴文理学院应用化学研究所,浙江,绍兴,312000

2.绍兴文理学院应用化学研究所,浙江,绍兴,312000

3.绍兴文理学院应用化学研究所,浙江,绍兴,312000

4.绍兴文理学院应用化学研究所,浙江,绍兴,312000

5.绍兴文理学院应用化学研究所,浙江,绍兴,312000

6.浙江大学西溪校区催化研究所,浙江,杭州,310028

7.绍兴文理学院应用化学研究所,浙江,绍兴,312000;浙江大学西溪校区催化研究所,浙江,杭州,310028

基金项目: 浙江省自然科学基金 (RC01050,501066)

关键词：碳-碳键引发剂 , 活性自由基聚合 , 引发体系

ADVANCE IN CARBON-CARBON BOND TYPE INITIATION SYSTEM FOR‘LIVING’RADICAL POLYMERIZATION

与其它引发剂相比,碳-碳键型引发剂由于其自身的优良性能,因而逐渐受到了研究者的重视.本文简要介绍碳-碳键型引发剂在热引发转移终止剂和反向ATRP引发体系中的引发机理,及这两种活性自由基的聚合方法.

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碳-碳键型活性自由基聚合引发体系的研究现状

ADVANCE IN CARBON-CARBON BOND TYPE INITIATION SYSTEM FOR‘LIVING’RADICAL POLYMERIZATION

参考文献