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采用中性盐雾试验比较了酸性氯化钾镀锌层经3种不同钝化剂钝化处理后所得钝化膜的耐蚀性,采用X射线光电子能谱研究了不同钝化膜的厚度及组成.结果表明,SpectraMATETM 25 彩色钝化所得钝化膜的耐蚀性最好,可以经受336 h以上的中性盐雾试验,TRI-V121钝化膜的耐蚀性次之,TRI-X120钝化膜最差.TRI-V120和TRI-V121蓝白钝化所得钝化膜的主要组成为Cr2O3,厚度均为200nm左右,但后者的Cr含量较高,因此具有较高的耐蚀性;经SpectraMATETM25彩色钝化所得钝化膜的组成为Cr(OH)3和Cr2O3,厚度约为800 nm,膜层厚是其具有高耐蚀性的主要原因.

参考文献

[1] 吴育忠,李伟善,马冲,梁碧敏,左正勋,吕东生.电镀锌钝化处理耐蚀效果的电化学评估[J].电镀与涂饰,2008(06):36-38.
[2] Almeida E.;Figueiredo MO.;Sa C.;Diamantino TC. .Oxidising alternative species to chromium VI in zinc galvanised steel surface treatment. Part 1 - A morphological and chemical study[J].Surface & Coatings Technology,1998(1):8-17.
[3] Bellezze T.;Roventi G.;Fratesi R. .Electrochemical study on the corrosion resistance of CrIII-based conversion layers on zinc coatings[J].Surface & Coatings Technology,2002(2/3):221-230.
[4] Bikulcius G;Rucinskiene A;Matulionis E;Sudavicius A .Influence of a static magnetic field on the protective ability of chromatic conversion coatings on zinc[J].Surface & Coatings Technology,2004(2/3):388-392.
[5] Kwon SC;Lee HJ;Kim JK;Byon E;Collins G;Short K .Plasma processing for surface modification of trivalent chromium as alternative to hexavalent chromium layer[J].Surface & Coatings Technology,2007(15):6601-6605.
[6] KeunWoo Cho;V. Shankar Rao;HyukSang Kwon .Microstructure and electrochemical characterization of trivalent chromium based conversion coating on zinc[J].Electrochimica Acta,2007(13):4449-4456.
[7] 任艳萍,陈锦虹.镀锌层三价铬钝化膜腐蚀行为的研究[J].材料保护,2007(02):7-10,41.
[8] 沈品华.镀锌三价铬钝化[J].电镀与环保,2007(03):27-30.
[9] WAGNER C D;NAUMKIN A V;KRAUT-VASS A et al.NIST X-rayPhotoelectron Spectroscopy Database[DB/OL].http://srdata.nist.gov/xps/Default.aspx,2007-08-27.
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