电子转移生成催化剂原子转移自由聚合(AGET ATRP)和电子转移再生催化荆原子转移自由基聚合(ARGET ATRP)是两种新型的原子转移自由基聚合体系,它们不仅克服了传统原子转移自由基聚合体系(NormalATRP)中低价态过渡金属催化剂容易氧化、用量大、后处理困难等问题,而且在制备嵌段共聚物的过程中不会生成均聚物,可以进行本体、溶液、细乳液聚合,尤其是使电子转移再生催化剂原子转移自由基聚合体系中催化剂浓度降到10×10<'-6>,对原子转移自由基聚合的工业化应用产生了深远影响.综述了这两种原子转移自由基聚合的最新研究进展,包括目前适用于该引发体系的单体、引发剂、过渡金属络合物、配体和还原剂,展望了原子转移自由基聚合的发展.
参考文献
| [1] | Krzysztof Matyjaszewski;Jianhui Xia .Atom Transfer Radical Polymerization[J].Chemical Reviews,2001(9):2921-2990. |
| [2] | Sang Beom Lee;Alan J.Russell;Krzysztof Matyjaszewski .ATRP synthesis of amphiphilic random,gradient,and block copolymers of 2-(dimethylamino)ethyl methacrylate and n-butyl methacrylate in aqueous media[J].Biomacromolecules,2003(5):1386-1393. |
| [3] | Moschogianni P;Pispas S;Hadjichristidis N .Multifunctional ATRP initiators:Synthesis of four-arm star homopolymers of methyl methacrylate and craft copolymers of polystyrene and poly(t-butyl methacrylate)[J].Journal of Polymer Science Part A: Polymer Chemistry,2001,39(05):650. |
| [4] | Lutz JF.;Neugebauer D.;Matyjaszewski K. .Stereoblock copolymers and tacticity control in controlled/living radical polymerization[J].Journal of the American Chemical Society,2003(23):6986-6993. |
| [5] | Hosei Shinoda;Krzysztof Matyjaszewski .Structural Control of Poly(Methyl Methacrylate)-g-poly(Lactic Acid) Graft Copolymers by Atom Transfer Radical Polymerization (ATRP)[J].Macromolecules,2001(18):6243-6248. |
| [6] | Braunecker WA;Matyjaszewski K .Recent mechanistic developments in atom transfer radical polymerization[J].Journal of molecular catalysis, A. Chemical,2006(1/2):155-164. |
| [7] | Jin-Shan Wang;Krzysztof Matyjaszewski .Controlled/'Living' Radical Polymerization. Atom Transfer Radical Polymerization in the Presence of Transition-Metal Complexes[J].Journal of the American Chemical Society,1995(20):5614-5615. |
| [8] | Kato M;Kamigaito M;Sawarnoto M et al.Polymerization of methyl methacrylate with the carbon tetrachloride/dichlorotris-(triphenylphosphine) ruthenium(Ⅱ) / Methytaluminum Bis(2,6-ditertbutylphenox ide) initiating system:Possibility of living radical polymerization[J].Macromolecules,1995,28(05):1721. |
| [9] | Ke Min;Haifeng Gao;Krzysztof Matyjaszewski .Preparation of Homopolymers and Block Copolymers in Miniemulsion by ATRP Using Activators Generated by Electron Transfer (AGET)[J].Journal of the American Chemical Society,2005(11):3825-3830. |
| [10] | Jakubowski W;Min K;Matyjaszewski K .Activators regenerated by electron transfer for atom transfer radical polymerization of styrene[J].Macromolecules,2006(1):39-45. |
| [11] | Min K;Jakubowski W;Matyjaszewski K .AGET ATRP in the presence of air in miniemulsion and in bulk[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2006(8):594-598. |
| [12] | Matyjaszewski Krzysztof .Lifetimes of polystyrene chains in atom transfer radical polymerization[J].Macromolecules,1999(26):9051-9053. |
| [13] | Nicolay V.Tsarevsky;Krzysztof Matyjaszewski ."Green" Atom Transfer Radical Polymerization:From Process Design to Preparation of Well-Defined Environmentally Friendly Polymeric Materials[J].Chemical Reviews,2007(6):2270-2299. |
| [14] | Jakubowski W;Matyjaszewski K .Activator generated by electron transfer for atom transfer radical polymerization[J].Macromolecules,2005(10):4139-4146. |
| [15] | 程晓奕 .ARGET ATRP法制备苯乙烯聚合物及其表征[D].武汉理工大学,2009. |
| [16] | Bai, LJ;Zhang, LF;Zhu, J;Cheng, ZP;Zhu, XL .Iron(III)-Mediated AGET ATRP of Styrene Using Tris(3,6-Dioxaheptyl)amine as a Ligand[J].Journal of Polymer Science, Part A. Polymer Chemistry,2009(8):2002-2008. |
| [17] | Taniguchi, T;Kasuya, M;Kunisada, Y;Miyai, T;Nagasawa, H;Nakahira, T .Surface modification of polymer latex particles by AGET ATRP of a styrene derivative bearing a lactose residue[J].Colloids and Surfaces, B. Biointerfaces,2009(2):194-199. |
| [18] | Matyjaszewski K;Dong HC;Jakubowski W;Pietrasik J;Kusumo A .Grafting from surfaces for "Everyone": ARGET ATRP in the presence of air[J].Langmuir: The ACS Journal of Surfaces and Colloids,2007(8):4528-4531. |
| [19] | Oueffelec J;Gaynor S G;Matyjaszewski K .Optimization of atom transfer radical polymerization using Cu(Ⅰ)/tris(2-(dimethylamino)ethyl) amine as a catalyst[J].Macromolecules,2000,33(23):8629. |
| [20] | Ke Min;Haifeng Gao;Krzysztof Matyjaszewski .Use of Ascorbic Acid as Reducing Agent for Synthesis of Well-Defined Polymers by ARGET ATRP[J].Macromolecules,2007(6):1789-1791. |
| [21] | 王新红;张春庆;李杨.通过新型ARGET ATRP合成两亲性嵌段共聚物PMMA-b-PDMAEMA[A].天津,2009 |
| [22] | Oh JK;Matyjaszewski K .Synthesis of poly(2-hydroxyethyl methacrylate) in protic media through atom transfer radical polymerization using activators generated by electron transfer[J].Journal of Polymer Science, Part A. Polymer Chemistry,2006(12):3787-3796. |
| [23] | Oh JK;Dong H;Zhang R;Matyjaszewski K;Schlaad H .Preparation of nanoparticles of double-hydrophilic PEO-PHEMA block copolymers by AGET ATRP in inverse miniemulsion[J].Journal of Polymer Science, Part A. Polymer Chemistry,2007(21):4764-4772. |
| [24] | Yafeng Wu;Songqin Liu;Lin He .Electrochemical Biosensing Using Amplification-by-Polymerization[J].Analytical chemistry,2009(16):7015-7021. |
| [25] | Jung Kwon Oh;Ke Min;Krzysztof Matyjaszewski .Preparation of Poly(oligo(ethylene glycol) monomethyl ether methacrylate) by Homogeneous Aqueous AGET ATRP[J].Macromolecules,2006(9):3161-3167. |
| [26] | Oh, JK;Perineau, F;Charleux, B;Matyjaszewski, K .AGET ATRP in Water and Inverse Miniemulsion: A Facile Route for Preparation of High-Molecular-Weight Biocompatible Brush-Like Polymers[J].Journal of Polymer Science, Part A. Polymer Chemistry,2009(7):1771-1781. |
| [27] | Dong H C;Matyjaszewski K .ARGET ATRP of 2-(dimethylamino) ethyl methacrylate as an intrinsic reducing agent[J].Macromolecules,2008,41(19):6868. |
| [28] | Hongchen Dong;Wei Tang;Krzysztof Matyjaszewski .Well-Defined High-Molecular-Weight Polyacrylonitrile via Activators Regenerated by Electron Transfer ATRP[J].Macromolecules,2007(9):2974-2977. |
| [29] | Pietrasik J;Dong HC;Matyjaszewski K .Synthesis of high molecular weight poly(styrene-co-acrylonitrile) copolymers with controlled architecture[J].Macromolecules,2006(19):6384-6390. |
| [30] | Aimi J;McCullough L A;Matyjaszewski K .Synthesis of poly(vinylacetylene) block copolymers by atom transfer radical polymerization[J].Macromolecules,2008,41(24):9522. |
| [31] | Tanaka K;Matyjaszewski K .Copolymerization of(meth)acrylates with olefins using activators regenerated by electron transfer for atom transfer radical polymerization(ARGET ATRP)[J].Macromolecular Symposia,2008,261(01):1. |
| [32] | Tan Y;Yang Q B;Sheng D K .AGET ATRP of aerylamide in aqueous media[J].E-POLYMERS,2008,25:1. |
| [33] | Ji H J;Hyun J J;Sung H A et al.Synthesis of high molecular weight 3-arm star PMMA by ARGET ATRP[J].Macromolecular Research,2009,17:240. |
| [34] | Kang Zhao;Zhenping Cheng;Zhengbiao Zhang .Synthesis of fluorescent poly(methyl methacrylate) via AGET ATRP[J].Polymer bulletin,2009(3):355-364. |
| [35] | Zhang, LF;Cheng, ZP;Shi, SP;Li, QH;Zhu, XL .AGET ATRP of methyl methacrylate catalyzed by FeCl3/iminodiacetic acid in the presence of air[J].Polymer,2008(13/14):3054-3059. |
| [36] | Zhang LF;Cheng ZP;Tang F;Li Q;Zhu XL .Iron(III)-Mediated ATRP of methyl methacrylate using activators generated by electron transfer[J].Macromolecular chemistry and physics,2008(16):1705-1713. |
| [37] | Chen, H;Yang, LX;Liang, Y;Hao, ZH;Lu, ZX .ARGET ATRP of Acrylonitrile Catalyzed by FeCl3/Isophthalic Acid in the Presence of Air[J].Journal of Polymer Science, Part A. Polymer Chemistry,2009(12):3202-3207. |
| [38] | Tang W;Kwak Y;Braunecker W;Tsarevsky NV;Coote ML;Matyjaszewski K .Understanding atom transfer radical polymerization: Effect of ligand and initiator structures on the equilibrium constants[J].Journal of the American Chemical Society,2008(32):10702-10713. |
| [39] | Wu DX;Yang YF;Cheng XH;Liu L;Tian J;Zhao HY .Mixed molecular brushes with PLLA and PS side chains prepared by AGET ATRP and ring-opening polymerization[J].Macromolecules,2006(22):7513-7519. |
| [40] | Tang HD;Radosz M;Shen YQ .CuBr2/N,N,N ',N '-tetra[(2-pyridal)methyl] ethylenediamine/tertiary amine as a highly active and versatile catalyst for atom-transfer radical polymerization via activator generated by electron transfer[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2006(14):1127-1131. |
| [41] | Tang W;Matyjaszewski K .Effect of ligand structure on activation rate constants in ATRP[J].Macromolecules,2006(15):4953-4959. |
| [42] | Matyjaszewski K;Jakubowski W;Min K;Tang W;Huang JY;Braunecker WA;Tsarevsky NV .Diminishing catalyst concentration in atom transfer radical polymerization with reducing agents[J].Proceedings of the National Academy of Sciences of the United States of America,2006(42):15309-15314. |
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