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介绍了一种新型的锂离子电池正极材料LiNi1/3Co1/3Mn1/3O2的最新研究状况,描述了材料的晶体及电子结构,以及电化学性能;重点总结了现今国内外制备此材料的几种主要合成方法及研究进展:同时,介绍了不同掺杂元素(Fe、B、A1、Ti)对材料的改性作用.

参考文献

[1] Kim MG;Shin HJ;Kim JH;Park SH;Sun YK .XAS investigation of inhomogeneous metal-oxygen bond covalency in bulk and surface for charge compensation in li-ion battery cathode Li[Ni1/3Co1/3Mn1/3]O-2 material[J].Journal of the Electrochemical Society,2005(7):A1320-A1328.
[2] 应皆荣;姜长印 .锂离子电池正极材料高密度球形镍钴锰酸锂的制备方法[P].中国专利.CN 1622371A,2004-12-30.
[3] Liao P Y;Duh J G;Sheen S R .Microstructure and electrochemical performance of LiNi0.6 Co0.4-xMnxO2 cathode materials[J].Power Sources,2005,143:212.
[4] Alcantara R;Jaraba M;Lavela P .New LiNiyCo1-2yMnl+yO4 spinel oxide solid solutions as 5V electrode material for Li-ion batteries[J].Journal of the Electrochemical Society,2004,151(01):A53.
[5] Hideki Kitao;Toyokl Fujihara;Kazuhisa Takeda .High-Temperature Storage Performance of Li-Ion Batteries Using a Mixture of Li-Mn Spinel and Li-Ni-Co-Mn Oxide as a Positive Electrode Material[J].Electrochemical and solid-state letters,2005(2):A87-A90.
[6] Zhaoxiang Wang;Yucheng Sun;Liquan Chen .Electrochemical Characterization of Positive Electrode Material LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2 and Compatibility with Electrolyte for Lithium-Ion Batteries[J].Journal of the Electrochemical Society,2004(6):A914-A921.
[7] Kim J M;Chung H T .The first cycle characteristics of LiNi1/3 Co1/3Mnl/3 O2 charged up to 4.7V[J].Electrochemica Acts,2004,49(06):937.
[8] 谭显艳,胡国荣,高旭光,禹筱元.正极材料LiNi1/3Co1/3Mn1/3O2的研究进展[J].电池,2005(04):315-316.
[9] Naoaki Yabuuchi;Tsutomu Ohzuku .Novel lithium insertion material of for advanced lithium-ion batteries[J].Journal of Power Sources,2003(119/121):171-174.
[10] Kim JH.;Park CW.;Sun YK. .Synthesis and electrochemical behavior of Li[Li0.1Ni0.35-x/2CoxMn0.55-x/2]O-2 cathode materials[J].Solid state ionics,2003(1/2):43-49.
[11] Park S H;Yoon C S et al.Synthesis and structural characterization of layered LiNi1/3 Co1/3 Mn1/3 O2 cathode materials by ultrasonic spray pyrolysis method[J].Electrochimica Acta,2004,49:557.
[12] Naoaki Yabuuchi;Yukinori Koyama .Solid-state chemistry and electrochemistry of LiNi1/3Co1/3 Mn1/3 O2 for advanced lithiumion batteriesⅡ[J].Journal of the Electrochemical Society,2005,152(07):A1434.
[13] Koyama Y;Yabuuchi N;Tanaka I;Adachi H;Ohzuku T .Solid-state chemistry, and electrochemistry of LiCo1/3Ni1/3Mn1/3O2 for advanced lithium-ion batteries - I. First-principles calculation on the crystal and electronic structures[J].Journal of the Electrochemical Society,2004(10):A1545-A1551.
[14] Choi J;Manthiram A .Comparison of the electrochemical behaviors of stoichiometric LiNi1/3 Co1/3 Mnw3 O2 and lithium excess Li1.03(Ni1/3Co1/3Mn1/3)0.7gO2[J].Electrochemocal and Solid State Letters,2004,7(10):A365.
[15] Shaju KM;Rao GVS;Chowdari BVR .Influence of Li-ion kinetics in the cathodic performance of layered Li(Ni1/3Co1/3Mn1/3)O-2[J].Journal of the Electrochemical Society,2004(9):A1324-A1332.
[16] 韦旎妮,赖琼钰,高媛,陈元端,卢集政.层状LiCo1/3Ni1/3Mn1/3O2正极材料的合成及电化学性能研究[J].无机化学学报,2005(07):999-1003.
[17] 郭炳锟;徐徽.锂离子电池[M].长沙:中南大学出版社,2002:7.
[18] Chen Yao;Wang G X et al.Synthesis and characterization of LiCoxMnyNi1-x-yO2 as a cathode material for secondary lithium batteries[J].Power Sources,2003,121:184.
[19] Sun Yucheng;Ouyang Chuying;Wang Zhaoxiang .Effect of Co content on rate performance of LiMn0.5-xCo2 Ni0.5-x02 cathode materials for lithium-ion batteries[J].Electrochemical Soeiety,2004,151(04):A504.
[20] Cho T H;Park S M;Yoshio M .Effect of synthesis condition on the structural and electrochemical properties of LiNi1/3 Co1/3 Mn1/3 O2 prepared by carbonate co-precipitation method[J].Power Sources,2005,142:306.
[21] 禹筱元,胡国荣,彭忠东,肖劲,刘业翔.层状LiNi1/3Co1/3Mn1/3O2正极材料合成及电化学性能[J].电源技术,2005(10):641-643,697.
[22] 刘会权;王传福 .由碳酸盐前驱体制备锂过渡金属复合氧化物的方法[P].中国专利,CN 1500732A,2002-11-19.
[23] Yanko Marinov Todorov;Koichi Numata .Effects of the Li:(Mn + Co + Ni) molar ratio on the electrochemical properties of LiMn{sub}(1/3)Co{sub}(1/3)Ni{sub}(1/3)O{sub}2 cathode material[J].Electrochimica Acta,2004(2/3):495-499.
[24] Ebeman K;Evin W .Solid state synthesis of lithum-nickel-cobah-manganese mxed metal oxides for use in lithium ion battery cathode material[P].us Patent,WO 2005/056480 Al,2005-06-23.
[25] Li De-Cheng;Muta Takahisa et al.Effect of synthesis method on the electrochemical performance of LiNi1/3 Co1/3 Mn1/3 O2[J].Power Soueees,2004,132:150-155.
[26] Sebastien Patoux;Marca M. Doeff .Direct synthesis of LiNi_(1/3)Co)(1/3)Mn_(1/3)O_2 from nitrate precursors[J].Electrochemistry communications,2004(8):767-772.
[27] Kim JH.;Park CW.;Sun YK. .Synthesis and electrochemical behavior of Li[Li0.1Ni0.35-x/2CoxMn0.55-x/2]O-2 cathode materials[J].Solid state ionics,2003(1/2):43-49.
[28] Park S H;Yoon C S et al.Synthesis and structural characterization of layered LiNi1/3 Co1/3 Mn1/3 O2 cathode materials by ultrasonic spray pyrolysis method[J].Electrochimica Acta,2004,49:557-563.
[29] Y. S. Meng;Y. Wei Wu;B. Joe Hwang .Combining Ab Initio Computation with Experiments for Designing New Electrode Materials for Advanced Lithium Batteries: LiNi_(1/3)Fe_(1/6)Co_(1/6)Mn_(1/3)O_2[J].Journal of the Electrochemical Society,2004(8):A1134-A1140.
[30] 檀柏杉,韩恩山,李鹏.LiNi1/3Co1/4Mn1/3M1/12O2(M=Al,Ti)的性能研究[J].电池,2005(04):259-260.
[31] S. Jouanneau;W. Bahmet;K. W. Sherman .Effect of the Sintering Agent, B_2O_3, on Li[Ni_xCo_(1-2x)Mn_x]O_2 Materials[J].Journal of the Electrochemical Society,2004(11):A1789-A1796.
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