本文采用固相反应法合成了一系列掺Nd3+的Na3La2(BO3)3(Na3La2(BO3)3:Nd3+)多晶粉末,X-ray粉末衍射分析表明,它们属于正交晶系,Amm2空间群.测试了Na3La2(BO3)3:Nd3+的红外光谱、反射光谱和荧光光谱,观察到试样在590 nm、740 nm和800 nm附近存在显著吸收,以及在878 nm、1067 nm、1326 nm三个发射带.研究了发光强度与Nd3+离子浓度之间的关系,确定了Nd3+离子在Na3La2(BO3)3基质中发光的适宜浓度为10 %摩尔分数.
参考文献
[1] | Webjorn J.;Waarts RG. .Frequency doubling offers advantages for blue lasers[J].Laser Focus World: The Magazine for the Photonics & Optoelectronics Industry,1998(5):135-144. |
[2] | Roux R. .Solid-state lasers - Frequency-doubling crystal source found[J].Laser Focus World: The Magazine for the Photonics & Optoelectronics Industry,1998(5):30-32. |
[3] | Yvonne A C .Diode Lasers,Nonlinear Optics,and Solid-state Lasers[J].Laser Focus World,1993,29(04):113-130. |
[4] | Leonyuk N I;Leonyuk L I .Growth and Characterization of RM3(BO3)4 Crystals[J].Prog Cryst Growth and Charact,1995,31(3-4):179-278. |
[5] | Iwai M;Kobayashi T;Furuya H et al.Crystal Growth and Optical Characterization of Rare-Earth(Re)Calcium Oxyborate ReCa4O(BO3)3(Re=Y or Gd)as New Nonlinear Optical Material[J].Japanese Journal of Applied Physics Part 2:Letters,1997,36(3A):L276-L279. |
[6] | Yicheng Wu;Jianguo Liu;Peizhen Fu;Junxing Wang;Huyun Zhou;Guofu Wang;Chuangtian Chen .A new lanthanum and calcium borate La_2CaB_(10)O_(19)[J].Chemistry of Materials,2001(3):753-755. |
[7] | Pierre Gravereau;Jean-Pierre Chaminade;Stanislav Pechev;Velin Nikolov;Diana Ivanova;Pavel Peshev .Na_3La_9O_3(BO_3)_8, a new oxyborate in the ternary system Na_2O-La_2O_3-B_2O_3: preparation and crystal structure[J].Solid state sciences,2002(7):993-998. |
[8] | Guochun Zhang;Yicheng Wu;Peizhen Fu;Guofu Wang;Shilie Pan;Chuangtian Chen .A New Nonlinear Optical Borate Crystal Na_3La_2 (BO_3)_3[J].Chemistry Letters,2001(5):456-457. |
[9] | 张国春,傅佩珍,王国富,郭范,官向国.Na3La2(BO3)3∶Tm3+的合成及其光谱特性[J].中国科学技术大学学报,2001(01):112-116,84. |
[10] | 张国春,傅佩珍,王国富,郭范,官向国.Na3La2(BO3)3:Sm3+的合成及其光谱特性[J].发光学报,2001(03):237-242. |
[11] | Lemanceau S;Bertrand-Chadeyron G;Mahiou R et al.Synthesis and Characterization of H-LnBO3 Orthoborates(Ln=La,Nd,Sm,and Eu)[J].Journal of Solid State Chemistry,1999,148(02):229-235. |
[12] | Sankar R.;Rao GVS. .Luminescence studies on doped borates, A(6)MM '(BO3)(6)[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(2):126-136. |
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