以环保特性优良的植酸为基本成分（150 mg/L）,通过添加少量生物缓蚀剂、稀土缓蚀剂等成分作为工序间零件的防锈溶液,对机加工零件经过工序间防锈处理的试样进行湿（相对湿度90%）热（50℃）环境下的加速腐蚀、中性盐雾腐蚀试验,考察机加工钢铁零件经过工序间防锈处理后的防锈性能和电化学行为。试验结果表明：工序间防锈液处理的零件在高温高湿环境下的防锈性能优良。工序间防锈液中的植酸与生物缓蚀剂、稀土缓蚀剂在钢铁零件工序间防锈处理中具有协同效应。经工序间防锈液处理的试样其阻抗谱出现两个容抗弧,且腐蚀电位正移400 mV。
An interprocess antirust solution consisting of phytic acid with biological corrosion inhibitor and rare earth inhibitor was prepared and its performance for interprocess rust-proofing of steel parts was evaluated.Corrosion experiments of steel Q235 treated with the antirust solution were conducted in hygrothermal environment（relative humidity 90%,50 ℃） and neutral salt spray envorionment,and antirust property and behaviour of electrochemistry of the treated steel were examined.The results show that the antirust property of the steel treated with interprocess antirust solution is excellent under the enviroments of high temperature and high humidity.The phytic acid,biological inhibitor and rare earth inhibitor,present a synergy effect in the process of rust-proofing treatment.The EIS diagram of the treated steel has two capacitive loops,and the corrosion potential positively shifts about 400 mV.
参考文献
| [1] | 李志林,韩立兴,陈泽民.水基防锈剂的研究进展[J].表面技术,2006(05):51-53. |
| [2] | 董晓静 .乙醇胺化合物缓蚀性能的研究[D].哈尔滨工业大学,2007. |
| [3] | 陈旭俊;徐越;马仁川 等.乙醇胺钼酸盐的缓蚀作用与机理[J].中国腐蚀与防护学报,1995,15(05):279-284. |
| [4] | 李玉明,刘静敏,马志超,匡云飞.钼酸盐与磷酸盐、硅酸盐复配缓蚀剂的研究[J].腐蚀与防护,2004(06):248-251. |
| [5] | 刘宝玉,刘峥,王国瑞.海水缓蚀剂的研究现状与展望[J].材料保护,2010(08):51-56,59. |
| [6] | 倪铁军,王文西,蔡兰坤.水溶液中硅酸盐缓蚀剂与碳钢表面氧化物相互作用的研究[J].腐蚀与防护,2001(11):479-482. |
| [7] | 穆振军,杜敏.天然海水中高效缓蚀剂对碳钢缓蚀作用的研究[J].中国腐蚀与防护学报,2005(04):205-208. |
| [8] | 沈大娲,马清林.硅酸盐缓蚀剂的研究及其在铁质文物保护中的应用[J].腐蚀科学与防护技术,2009(06):568-570. |
| [9] | W. J. van Ooij,D. Zhu,M. Stacy,A. Seth,T. Mugada,J. Gandhi,P. Puomi.Corrosion Protection Properties of Organofunctional Silanes-An Overview[J].清华大学学报（英文版）,2005(06):639-664. |
| [10] | Palanivel Vignesh;HuangY;Ooij Wire J van.Effect s ofaddition of corrosion inhibitors to silane films on the performance of AA2024-T3 in a 0 5 M N Aci solution[J].Progress in Organic Coatings,2005(53):153-168. |
| [11] | 郭侃,刘慧丛,王培鹏,李卫平.一种用于工序间防锈的含有稀土成分的硅烷水溶液[J].表面技术,2010(06):101-103. |
| [12] | Danqing Zhu;Wim J. van Ooij .Enhanced corrosion resistance of AA 2024-T3 and hot-dip galvanized steel using a mixture of bis-[triethoxysilylpropyl]tetrasulfide and bis-[trimethoxysilylpropyl]amine[J].Electrochimica Acta,2004(7):1113-1125. |
| [13] | 张洪生.植酸在金属表面处理中的应用[J].腐蚀与防护,2000(09):413-414. |
| [14] | 刘泓,沈月敏.植酸在金属防腐中的应用研究[J].应用化工,2009(11):1701-1702. |
| [15] | 赵地顺,刘会茹,徐智策,庞登甲,王春芳.植酸盐缓蚀剂及其机理研究[J].高等学校化学学报,2005(02):334-336. |
| [16] | 曹楚南;张鉴清.电化学阻抗谱导论[M].北京:科学出版社,2002 |
- 下载量()
- 访问量()
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%