磷酸铁锂(LiFePO_4)由于安全性能好、循环寿命长、原材料来源广泛、无环境污染等优点被公认为是最具发展潜力的锂离子动力与储能电池正极材料.经过10余年的深入研究,LiFePO_4已经进入实用化阶段,综述了磷酸铁锂材料近年来在基础和应用研究方面的最新进展.
Olivine lithium iron phosphate (LiFePO_4) is universally recognized as a promising cathode material for lithium rechargeable batteries for electric vehicles due to long lifespan, plentiful resources, environmental friendliness and high safety required to traction batteries. A brief review is presented on development and challenge of LiFePO_4 cathode material. Ongoing research strategies for electrochemical performance, tap density and low-temperature capability are discussed.
参考文献
[1] | Padhi AK.;Goodenough JB.;Nanjundaswamy KS. .PHOSPHO-OLIVINES AS POSITIVE-ELECTRODE MATERIALS FOR RECHARGEABLE LITHIUM BATTERIES[J].Journal of the Electrochemical Society,1997(4):1188-1194. |
[2] | Andersson A S;Thomas J O .[J].Journal of Power Sources,2001,97-98:498-502. |
[3] | Tarascon J M;Armand M .[J].Nature,2001,414:359-367. |
[4] | Prosini PP.;Lisi M.;Zane D.;Pasquali M. .Determination of the chemical diffusion coefficient of lithium in LiFePO4[J].Solid state ionics,2002(1/2):45-51. |
[5] | Goodenough J B;Mizuchima K .[P].US:4,302,518,1981. |
[6] | Islam M S;Driscoll D J;Fisher C A J et al.[J].Chemistry of Materials,2005,17:5085-5092. |
[7] | Ouyang C Y;Shi S Q;Wang Z X et al.[J].Physical Review B:Condensed Matter,2004,69:104303. |
[8] | Morgan D;Van der Ven A;Ceder G .[J].Electrochemical and Solid-State Letters,2004,7:A30-A32. |
[9] | Chung S Y;Bloking J T;Chiang Y M .[J].Nature Materials,2002,1:123-128. |
[10] | Yang S F;Song Y N;Ngala K et al.[J].Journal of Power Sources,2003,119:239-246. |
[11] | Imanishi N.;Takeda Y.;Yamamoto O.;Tabuchi M.;Fujiyoshi M. .Preparation and ~7Li-NMR study of chemically delithiated Li_(1-x)CoO_2 (0<x<0.5)[J].Solid state ionics,1999(1/2):121-128. |
[12] | Saadoune I;Menetrier M;Delmas C .[J].Journal of Materials Chemistry,1997,7:2505-2511. |
[13] | Ravet N;Abouimrane A;Armand M .[J].Nature Materials,2003,2:702. |
[14] | Delacourt C;Laffont L;Bouchet R et al.[J].Journal of the Electrochemical Society,2005,152:A913-A921. |
[15] | Huang Y H;Park K S;Goodenough J B .[J].Journal of the Electrochemical Society,2006,153:A2282-A2286. |
[16] | Huang Y H;Goodenough J B .[J].Chemistry of Materials,2008,20:7237-7241. |
[17] | Kang B;Ceder G .[J].Nature,2009,458:190-193. |
[18] | Zaghib K;Goodenough J B;Mauger A et al.[J].Journal of Power Sources,2009,194:1021-1023. |
[19] | Islam M S;Driscoll D J;Fisher C A J et al.[J].Chemistry of Materials,2005,17:5085-5092. |
[20] | Fisher C A J;Prieto V M H;Islam M S .[J].Chemistry of Materials,2008,20:5907-5915. |
[21] | Wang Y G;Wang Y R;Hosono E J et al.[J].Angewandte Chemie International Edition,2008,47:7461-7465. |
[22] | Ying J R;Lei M;Jiang C Y et al.[J].Journal of Power Sources,2006,158:543-549. |
[23] | Zou Z G;Li X M;Wu Y.Effect of Heating on the Structural and Electrochemical Properties of LiFePO4 by Molten Salt Method[A].,2007 |
[24] | Xie H M;Wang R S;Ying J R et al.[J].Advanced Materials,2006,18:2609-2613. |
[25] | Dominko R;Bele M;Goupil JM;Gaberseek M;Hanzel D;Arcon L;Jamnik J .Wired porous cathode materials: A novel concept for synthesis of LiFePO4[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(12):2960-2969. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%