制备LiPON固体电解质薄膜,通过电沉积手段获得由LiPON膜保护的金属锂电极,测试该电极在有机电解液体系中的电化学性质.结果表明;LiPON膜的存在,抑制了锂电极和电解液之间的非法拉第反应,使锂电极具有更加稳定的电极/电解液界面.由于LiPON膜的保护作用,金属锂电极在充放电循环中也表现出优越的界面稳定性,从而获得更高的库伦循环效率和更好的电池循环寿命.
参考文献
[1] | Aurbach D.;Zinigrad E.;Cohen Y.;Teller H. .A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions[J].Solid state ionics,2002(3/4):405-416. |
[2] | 吴宇平,万春荣,姜长印,李建军,李阳兴.金属锂二次电池的研究进展[J].功能材料,2000(05):449-451. |
[3] | Wang X M et al.[J].Electrochimica Acta,2001,46:813. |
[4] | Morigaki K .[J].Journal of Power Sources,2002,104:13. |
[5] | Kanamura K.;Shiraishi S.;Takehara Z.;Takezawa H. .CHEMICAL REACTION OF LITHIUM SURFACE DURING IMMERSION IN LICLO4 OR LIPF6/DEC ELECTROLYTE[J].Journal of the Electrochemical Society,1997(6):1900-1906. |
[6] | Mogi R et al.[J].Journal of the Electrochemical Society,2002,149:A1578. |
[7] | Nagasubramanian G et al.[J].Journal of Power Sources,2004,136:395. |
[8] | Eftekhari A .[J].Journal of Power Sources,2004,132:240. |
[9] | Bates J B et al.[J].Solid State Ionics,1992,53-56:647. |
[10] | Zhao S L et al.[J].Journal of Power Sources,2003,122:174. |
[11] | 申万,杨志民,邢光健,毛昌辉,杜军.固态薄膜电解质LiSiPON和其性能研究[J].电源技术,2006(03):179-182. |
[12] | Byoungsoo K et al.[J].Journal of Power Sources,2002,109:214. |
[13] | Lee S J et al.[J].Journal of Power Sources,2003,123:61. |
[14] | Sakamoto JS.;Dunn B.;Wudl F. .Passivating lithium electrodes with trimethylsilylacetylene[J].Solid state ionics,2001(3/4):295-299. |
[15] | Ishikawaa M et al.[J].Journal of Power Sources,2005,146(1-2):199. |
[16] | Masson R N et al.[J].Solid State Ionics,1999,118(1-2):129. |
[17] | Yamaki J I et al.[J].Journal of Power Sources,1998,74:219. |
[18] | Aurbach D et al.[J].Journal of the Electrochemical Society,2000,147(04):1274. |
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