采用化学共沉淀法制备尖晶石型ZnFe2O4纳米颗粒,将所得产物在450~900℃焙烧4h,使用FT-IR、XRD、TG-DTG、HRTEM及VSM研究烧结温度对化学成分、微结构及磁化性能的影响.研究结果表明:随着烧结温度升高,ZnFe2O4纳米颗粒尺寸从14 nm增大到了50 nm,而磁化强度从3.374 emu/g降低到了2.168 emu/g.
参考文献
[1] | 李荫远;李国栋.铁氧体物理学[M].北京:科学出版社,1974 |
[2] | Shah, SA;Hashmi, MU;Alam, S;Shamim, A .Magnetic and bioactivity evaluation of ferrimagnetic ZnFe2O4 containing glass ceramics for the hyperthermia treatment of cancer[J].Journal of Magnetism and Magnetic Materials,2010(3):375-381. |
[3] | Niu X S;Du W P;Du W M .Preparation and gas sensing properties of ZnM2O4 (M=Fe,Co,Cr)[J].Sensors and Actuators B:Chemical,2004,99(2-3):405. |
[4] | Toledo-Antonio J A;Nava N et al.Correlation between the magnetism of non-stoicometric zinc ferrites and their catalytic activity for oxidative dehydro-genation of 1-butene[J].Appl Cataly A:Gen,2002,234(1-2):137. |
[5] | Fan G L;Gu Z J;Yang L et al.Nanocrystalline zinc ferrite photocatalysts form using the colloid mill and hydrothermal technique[J].Chemical Engineering Journal,2009,155(1-2):534. |
[6] | Tomas-Alonso F;Palacios Latasa J M .Synthesis and surface properties of zinc ferrite species in supported sorbents for coal gas desulphurisation[J].Fuel Process Techn,2004,86(02):191. |
[7] | Meisheng Liang,Wenkai Kang,Keehang Xie.Comparison of reduction behavior of Fe2O3, ZnO and ZnFe2O4 by TPR technique[J].天然气化学(英文版),2009(01):110-113. |
[8] | Maletln M;Moshopoulou E G;Kontos A G et al.Synthesis and structural of In-doped ZnFe2O4 nanoporiticles[J].Journal of the European Ceramic Society,2007,27(13-15):4391. |
[9] | Mozaffari, M.;Eghbali Arani, M.;Amighian, J. .The effect of cation distribution on magnetization of ZnFe _2O_4 nanoparticles[J].Journal of Magnetism and Magnetic Materials,2010(21):3240-3244. |
[10] | Xinyong Li;Yang Hou;Qidong Zhao;Wei Teng;Xijun Hu;Guohua Chen .Capability of novel ZnFe_2O_4 nanotube arrays for visible-light induced degradation of 4-chlorophenol[J].Chemosphere: Environmental toxicology and risk assessment,2011(4):581-586. |
[11] | Rahman, M.M.;Khan, S.B.;Faisal, M.;Asiri, A.M.;Alamry, K.A. .Highly sensitive formaldehyde chemical sensor based on hydrothermally prepared spinel ZnFe _2O _4 nanorods[J].Sensors and Actuators, B. Chemical,2012(0):932-937. |
[12] | Mohai I.;Bertoti I.;Mohai M.;Gubicza J.;Ungar T.;Szepvolgyi J. .Thermal plasma synthesis of zinc ferrite nanopowders[J].Solid state ionics,2001(Special Issue SI):163-168. |
[13] | ZHAO Zhong-wei,OUYANG Kingsam,WANG Ming.Structural macrokinetics of synthesizing ZnFe2O4 by mechanical ball milling[J].中国有色金属学报(英文版),2010(06):1131-1135. |
[14] | J.M. Yang;F.S. Yen .Evolution of intermediate phases in the synthesis of zinc ferrite nanopowders prepared by the tartrate precursor method[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2008(1/2):387-394. |
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