欢迎登录材料期刊网

材料期刊网

高级检索

利用高温高压反应釜进行腐蚀模拟试验。采用失重法、SEM 和 XRD 等手段研究了 CO2分压对 N80油管钢在100℃下 CO2腐蚀行为的影响。结果表明,N80钢的腐蚀速率随 CO2分压升高而上升。不同 CO2分压下腐蚀类型与腐蚀产物膜宏观形貌的变化相对应,在低 CO2分压下腐蚀产物膜完整覆盖。随着 CO2分压的进一步升高,腐蚀产物膜由局部覆盖转而重新完整覆盖。相应地,N80钢在低 CO2分压下发生全面腐蚀,然后随 CO2分压的进一步升高,腐蚀类型由局部腐蚀向全面腐蚀过渡。

The effects of CO2 partial pressure on CO2 corrosion behavior of N80 steel at 100 ℃ were studied by autoclave test,together with weight loss method,SEM,and XRD.The results showed that the corrosion rate of N80 steel rose with the increase of CO2 pressure corresponding to the change of corrosion product film macro-morphology. At the low partial pressure of CO2 ,the corrosion product film was complete,then with the further increase of CO2 partial pressure,corrosion product film turned from incomplete to complete.Accordingly,at low CO2 partial pressure,the corrosion of N80 steel was general corrosion,and then with the further increase of CO2 partial pressure, corrosion characteristics were transformed from localized corrosion to general corrosion.

参考文献

[1] 孙丽,徐庆磊,方炯,唐奕.CO2腐蚀与防护研究[J].焊管,2009(03):23-26.
[2] 张国安,陈长风,路民旭,吴荫顺.油气田中CO2腐蚀的预测模型[J].中国腐蚀与防护学报,2005(02):119-123.
[3] Electrochemical characterization and computational fluid dynamics simulation of flow-accelerated corrosion of X65 steel in a CO_2-saturated oilfield formation water[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2010(8):P.2716.
[4] 陈卓元.二氧化碳腐蚀防护对策及发展趋势[J].材料开发与应用,1998(06):40.
[5] 陈长风,路民旭,赵国仙,严密林,白真权,杨延清.N80油管钢CO2腐蚀点蚀行为[J].中国腐蚀与防护学报,2003(01):21-25.
[6] 李建平,赵国仙,郝士明.几种因素对油套管钢CO2腐蚀行为影响[J].中国腐蚀与防护学报,2005(04):241-244.
[7] 朱世东,林冠发,白真权,刘会,尹成先,尹志福.油田套管P110钢腐蚀的影响因素[J].材料保护,2009(01):48-51.
[8] 冯蓓,杨敏,李秉风,王栋.二氧化碳腐蚀机理及影响因素[J].辽宁化工,2010(09):976-979.
[9] 林冠发,白真权,赵新伟,郑茂盛,路民旭.CO2腐蚀产物膜形态结构与温度和压力的关系[J].石油机械,2005(02):1-4.
[10] 任呈强,刘道新,白真权,李铁虎.N80油管钢的CO2高温高压腐蚀电化学行为与机理研究[J].西安石油大学学报(自然科学版),2004(06):52-56.
[11] B. Kinsella;Y. J. Tan;S. Bailey .Electrochemical impedance spectroscopy and surface characterization techniques to study carbon dioxide corrosion product scales[J].Corrosion: The Journal of Science and Engineering,1998(10):835-842.
[12] 林冠发,白真权,赵新伟,郑茂盛,路民旭.CO2腐蚀产物膜形态结构与温度和压力的关系[J].石油机械,2005(02):1-4.
[13] 朱世东,林冠发,白真权,刘会,尹成先,尹志福.油田套管P110钢腐蚀的影响因素[J].材料保护,2009(01):48-51.
[14] 林冠发,郑茂盛,白真权,赵新伟.P110钢CO2腐蚀产物膜的XPS分析[J].光谱学与光谱分析,2005(11):1875-1879.
[15] 刘会,朱世东,赵国仙,吕祥鸿.动态和静态下CO2分压对P110钢腐蚀行为的影响[J].腐蚀与防护,2009(08):551-554.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%