近些年,人们越来越关注太阳辐射的光伏利用.光伏发电技术在迅猛发展,薄膜太阳电池从占有主导地位的硅晶片技术中抢占了一定的市场份额.其中铜锌锡硫薄膜太阳电池因具有低成本、高的光电转化效率和吸收系数、合适的禁带宽度和环境友好等优点成为近年来薄膜太阳电池研究的热点.本文阐述了铜锌锡硫薄膜太阳电池的器件结构和性能特点,介绍了铜锌锡硫薄膜太阳电池的制备方法和研究进展,并对今后主要的发展方向进行了展望.
参考文献
| [1] | 殷志强,等.中国可再生能源发展战略研究丛书--太阳能卷[M].北京:中国电力出版社出版,2010,38~41.,2010. |
| [2] | 王文静,等.中国光伏产业发展研究报告[R].中国光伏产业发展研究报告项目研究组,2004,2~12.,2004. |
| [3] | A.WeberH,Krauth,S.Perlt,B.Schubert,et al .Multistage evaporation of Cu2ZnSnS4 thin film[J].Thin Solid Films,2009,517 |
| [4] | B.-A.Schubert,B.Marsen,S.Cinque,et al .Cu2ZnSnS4 thin film solar cells by fast coevaporation[J].Prog.Photovolt,2011,29(1):93~96.,2011. |
| [5] | T .Tanaka,A.Yoshida,D.Saiki,K.Saito,Q.Guo,M.Nishio,T.Yamaguchi.Influence of composition ratio on properties of Cu2ZnSnS4 thin films fabricated by co-evaporation[J].Thin Solid Films,2010,518 |
| [6] | T .Tanaka,A.Yoshida,M.Nishio,Q.Guo,H.Ogawa.Fabrication of Cu2ZnSnS4 thin films by co-evaporation[J].Phy.Status Solid,2006,3(8):2844~2847.,2006. |
| [7] | A .Weber,R.Mainz,H.W.Schock.On the Sn loss from thin films of the material system Cu-Zn-Sn-S in high vacuum[J].Journal of Applied Physics,2010,107(1):013516~013516.,2010. |
| [8] | A .Redinger,D.M.Berg,P.J.Dale,S.Siebentritt.The consequences of kesterite equilibria for efficient solar cells[J].Journal of the American Chemical Society,2011,133(10):3320~3323.,2011. |
| [9] | K.Wang,O.Gunawan,T.TODOROV,et al .Thermally evaporated Cu2ZnSnS4 solar cell[J].Applied Physics Letters,2010,97 |
| [10] | B.Shin,O.Gunawan,et al .Thin film solar cell with 8.4% power conversion efficiency using an earth-abundant Cu2ZnSnS4 absorber[J].Progress in Photovoltaics:Research and Applications,2013,21(1):72~76.,2013. |
| [11] | H.Katagiri,N.Sasaguchi,S.Hando,et al .Preparation and evaluation of Cu2ZnSnS4 thin films by sulfurization of E-B evaporated precursors[J].Sol.Energy Mater.Sol.Cell,1997,407 |
| [12] | H.katagiri,K.jimbo,K.Monya,et al.Solar cell without environmental pollution by using CZTS thin film[C].Photovoltaic Energy Conversion,2003.Proceedings of 3rd World Conference on IEEE,2003,3:2874~2879.,2003. |
| [13] | J.Zhang,L.Shao,et al .Cu2ZnSnS4 thin films prepared by sulfurization of ion beam sputtered precursors and their electrical and optical properties[J].Rare Met:2006,2006,25 |
| [14] | J.-S.Seol,S.-Y.Lee,J.-C.Lee,et al .Electrical and optical properties of Cu2ZnSnS4 thin films prepared by rf magnetron sputtering process[J].Sol.Energy Mater.Sol.Cells,2003,75(1):155~162.,2003. |
| [15] | K.Jimbo,R.Kimura,T.Kamimura,S.Yamada,et al .Cu2ZnSnS4 type thin film solar cells using abundant materials[J].Thin Solid Films,2007,515 |
| [16] | Hironori Katagiri,Kazuo Jimbo,Satoru Yamada,et al.Enhanced conversion efficiencies of Cu2ZnSnS4 based thin film solar cells by using preferential etching technique[J].Appl.phys.Express,2008,(1) 041201:1~4.,2008. |
| [17] | F.Y.Liu,K.Zhang,et al .Growth and characterization of Cu2ZnSnS4 thin films by dc reactive magnetron sputtering for photovoltaic applications[J].Electrochemical and Solid-State Letters,2010,13(11):H379~H381.,2010. |
| [18] | N .Nakayama,K.Ito.Sprayed films of stannite Cu2ZnSnS4[J].Appl.Surf.Sci,1996,92 |
| [19] | J .Madarasz,P.Bombicz,M.Okuya,S.Kaneko.Thermal decomposition of thiourea complexes of Cu (Ⅰ),Zn (Ⅱ) and Sn (Ⅱ) chlorides as precursors for the spray pyrolysis deposition of sulfide thin films[J].Solid State lonics,2001,439 |
| [20] | Y.B.Kumar,P.U.Bhaskar,G.S.Babu,V.S.Raja.Effect of copper salt and thiourea concentrations on the formation of Cu2ZnSnS4 thin films by spray pyrolysis[J].Phys.Status.Solid,2010,A207:149~156.,2010. |
| [21] | T .Prabhakar,N.Jampana.Effect of sodium diffusion on the structural and electrical properties of Cu2ZnSnS4 thin films[J].Solar Energy Materials and Solar Cells,2011,95(3):1001~1004.,2011. |
| [22] | J.J.Scragg,P.J.Dale,L.M.Peter,G.Zoppi,I.Forbes.New routes to sustainable photovoltaic ' s evaporation of Cu2ZnSnS4 as an alternative absorber material[J].Phys.Status Solid,2008,B245:1772~1778.,2008. |
| [23] | J .J.Scragg,P.J.Dale,L.M.Peter.Synthesis and characterization of Cu2ZnSnS4 absorber layers by an eletrodeposition annealing route[J].Thin Solid Films,2009,517 |
| [24] | H.Araki,Y.Kubo,A.Mikaduki,et al .Preparation of Cu2 ZnSnS4 thin films by sulfurizing electroplated precursors[J].Sol.Energy Mater.Sol.Cells,2009,93 |
| [25] | J .J.Scragg,D.M.Berg,D.J.Dale.A 3.2% efficient kesterite device from electrodeposited stacked elemental layers[J].J.Electro and Chem,2010,646 |
| [26] | M.Kurihara,D.Berg,J.Fisher,S.Siebentritt,P.J.Dale.Kesterite absorber layer uniformity from electrodeposited precursors[J].Phys.Status Solid,2009,C6:1241~1244.,2009. |
| [27] | H.Araki,Y.Kubo,et al .Preparation of Cu2ZnSnS4 thin films by sulfurization of.co-electroplated Cu-Zn-Sn precursors[J].Phys.Status Solid,2009,6(5):1266~1268.,2009. |
| [28] | R.Schurr,A.Holzing,S.Jost,et al .The crystallization of Cu2ZnSnS4 thin film solar cell absorbers from co-electroplated Cu-Zn-Sn precursors[J].Thin Solid Films,2009,517 |
| [29] | A.Ennaoui,M.Lux-Steiner,A.Weber,etal .Cu2ZnSnS4 thin film solar cells from electroplated precursors Novel low-cost perspective[J].Thin Solid Films,2009,517 |
| [30] | A.Wangperawong,J.S.King,S.M.Herron,et al .Aqueous bath process for deposition of Cu2ZnSnS4 photovoltaic absorbers[J].Thin Solid Films,2011,519(8):2488~2492.,2011. |
| [31] | J.Y.Chane-Ching,A.Gillorin,O.Zaberca,et al .Highlycrystallized quaternary chalcopyrite nanocrystals via a hightemperature dissolution-reprecipition route[J].Chem.Commun,2011,47(18):5229~5231.,2011. |
| [32] | Z.H.Zhou,Y.Y.Wang,D.Xu,et al .Fabrication of Cu2ZnSnS4screen printed layers for solar cells[J].Sol.Energy Mater.Sol.Cells,2010,94(12):2042~2045.,2010. |
| [33] | N.M.Shinde,D.P.Dubal,et al .Room temperature novel chemical synthesis of Cu2ZnSnS4 (CZTS) absorbing layer for photovoltaic application[J].Materials Research Bulletin,2012,47(2):302~307.,2012. |
| [34] | S.S.Mali,P.S.Shinde,et al .Synthesis and characterization of Cu2ZnSnS4 thin films by SILAR method[J].Journal of Physics and Chemistry of Solids,2012,73(6):735~740.,2012. |
| [35] | S.S.Mali,B.M.Patil,et al .Novel synthesis of kesterite Cu2ZnSnS4 nanoflakes by successive ionic layer adsorption and reaction technique:Characterization and application[J].Electrochimica Acta,2012,66 |
| [36] | T.Washio,T.Shinji,et al .6% Efficiency Cu2ZnSnS4-based thin film solar cells using oxide precursors by open atmosphere type CVD[J].Journal of Materials Chemistry,2012,22(9):4021~4024.,2012. |
| [37] | T K Todorov,J Tang,S Bag,et al .Beyond 11% Efficiency:Characteristics of State-of-the-Art Cu2ZnSn(S,Se)4Solar Cells[J].Advanced Energy Materials,2013,3(1):34~38.,2013. |
| [38] | Wang W,Winkler M T,Gunawan O,et al.Device Characteristics of CZTSSe Thin-Film Solar Cells with 12.6%Efficiency[J].Advanced Energy Materials,2013.,2013. |
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