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通过对吸附率(有效吸附系数)Ks和饱和吸附量msat的测量,描述了粘度为0.001 Pa·s~0.850 Pa·s的各种油类在膨胀石墨柱中的吸附动力学,发现吸附率Ks对油类粘度有很强的相关性.吸入膨胀石墨柱中的饱和吸附量msat几乎恒定在50kg/kg,该值略低于由膨胀石墨块直接浸渍在油中测得的吸附容量,这是由于所吸附的油沿膨胀石墨柱高度存在重力梯度.

The sorption kinetics of various oils with viscosities from 0. 001 to 0. 850 Pa· s onto an exfoliated graphite column was characterized by measuring sorptivity ( effective sorption coefficient) Ks and saturated amount of sorption msat. A strong dependence of Ks on oil viscosity was observed. msat was almost constant at 50 kg/kg, which was a little smaller than that measured by direct soaking of a lump of exfoliated graphite in oil. This was because of a gradient of sorbed oil along the height of the exfoliated graphite column.

参考文献

[1] Shen W;Wen S;Cao N et al.Expanded graphite-a new kind of biomedical material[J].Carbon,1999,37:356-358.
[2] 康飞宇,郑永平,兆恒,王海宁,王鲁宁,沈万慈,稻垣道夫.膨胀石墨对重油和生物体液的吸附-来自中国的研究[J].新型炭材料,2003(03):161-173.
[3] Toyoda M;Aizawa J;Inagaki M et al.Sorption and recovery of heavy oil by using exfoliated graphite[J].Desalination,1998,115:199-201.
[4] Toyoda M.;Inagaki M. .Heavy oil sorption using exfoliated graphite - New application of exfoliated graphite to protect heavy oil pollution[J].Carbon: An International Journal Sponsored by the American Carbon Society,2000(2):199-210.
[5] Inagaki M;Toyoda M;Iwashita N et al.Exfoliated graphite for spilled heavy oil recovery[J].Carbon Sci(Korea),2001,2(01):1-8.
[6] Toyoda M;Moriya K;Aizawa J et al.Sorption and recovery of heavy oil by using exfoliated graphite Part Ⅰ:Maximum sorption capacity[J].Desalination,2000,128(03):205-211.
[7] Michio Inagaki;Masahiro Toyoda;Kouji Moriya;Tsutomu Kihara .Sorption and recovery of heavy oils by using exfoliated graphite Part II:Recovery of heavy oil and recycling of exfoliated graphite[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2000(3):213-218.
[8] Nishi Y;Dai N;Iwashita N et al.Evaluation of sorption behavior of heavy oil into exfoliated graphite by wicking method[J].Material Scientific Research International,2002,8(04):243-248.
[9] Nishi Y;Iwashita N;Sawada Y et al.Sorption kinetics of heavy oil into porous carbons[J].Water Research,2002,36:5029-5036.
[10] Inagaki M;Nishi Y;Iwashita N et al.Mechanism of heavy oil sorption into porous carbons[J].Fresenius Environmental Bulletin,2004,13:183-189.
[11] Michio Inagaki;Akihiro Kawahra;Hidetaka Konno .Recovery of heavy oil from contaminated sand by using exfoliated graphite[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2004(1):77-82.
[12] Michio Inagaki;Masahiro Toyoda;Norio Iwashita .Sorption, Recovery and Recycle of Spilled Heavy Oils Using Carbon Materials[J].炭素,2002(201):16-25.
[13] Toyoda M;Iwashita N;Inagaki M.Sorption of heavy oils into carbon materials[J].Chemistry and Physics of Carbon
[14] Inagaki M;Iwashita N;Toyoda M;Carbons,J M D.Sorption of Viscous Organics by Macroporous Carbons[M].Elsevier
[15] Inagaki M;Toyoda M;Kang F .Exfoliation of graphite via intercalation compounds[J].Chemistry and Physics of Carbon,2004,29:1-69.
[16] Michio Inagaki;Taisuke Suwa .Pore structure analysis of exfoliated graphite using image processing of scanning electron micrographs[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(6):915-920.
[17] 稻垣道夫,丰田义雄,康飞宇,郑永平,沈万慈.膨胀石墨的孔隙结构-中国国家自然科学基金和日本学术振兴会联合研究项目报道[J].新型炭材料,2003(04):241-249.
[18] Zheng YP;Wang HN;Kang FY;Wang LN;Inagaki M .Sorption capacity of exfoliated graphite for oils-sorption in and among worm-like particles[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(12/12):2603-2607.
[19] Washburn E W .The dynamics of capillary flow[J].Physical Review,1921,17:273-283.
[20] Beltran V;Escardino A;Feliu C et al.Liquid suction by porous ceramics materials[J].British Ceramic Transactions,1988,87:64-69.
[21] Beltran V;Barba A;Rodrigo M D et al.Liquid suction by porous ceramics materials 2-Influence of pressing conditions[J].British Ceramic Transactions,1989,88:219-222.
[22] Beltran V;Barba A;Jaque J C et al.Liquid suction by porous ceramics materials 3-Influence of the nature of composition and the preparation method of the pressing powder[J].British Ceramic Transactions,1991,90:77-80.
[23] Escardino A;Beltran V;Barba A et al.Liquid suction by porous ceramicsmaterials 4-Influence of firing conditions[J].Br Ceram Tran Journal,1999,98:225-229.
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