研究了粒化高炉矿渣(GGBFS)作为粉煤灰基地聚合物外加剂的可行性.GGBFS的掺量为4%,将其抗压强度结果和增进机理与氟硅酸钠作为外加剂的结果进行了对比.测试结果表明,外加剂GGBFS和Na2SiF6的掺入都可以提高粉煤灰基地聚合物的抗压强度,其中4%GGBFS掺入后粉煤灰基地聚合物在30℃下养护14天的抗压强度可以提高19MPa以上,而10%Na2SiF6掺入仅提高10MPa以上.采用X射线衍射分析(XRD)、傅立叶变换红外光谱(FTIR)和压汞测孔技术(MIP)研究了两种外加剂对粉煤灰基地聚合物抗压强度的增进机理.研究结果表明,GG-BFS的掺入可以产生更多的无定形产物,增加胶凝材料的数量,并且能细化其孔隙,减少孔隙率,从而提高粉煤灰基地聚合物的强度.
参考文献
[1] | Davidovits J .Geopolymers and geopolymeric new materials[J].Journal of Thermal Analysis,1989,35:429. |
[2] | Davidovits J;Douglas C;Comrie et al.Geopolyrnerie concretes for environmental protection[J].Concrete International:Design Construction,1990,12(07):30. |
[3] | Davidovits J.Technical data sheet for geopolymeric cement type(Potassium,calcium)-Poly(sialate-siloxo)[A].Saint-Quentin,France:The Geopolymer Institue,1999:83. |
[4] | Ross A Fletcher;Kenneth J D MacKenzie;Catherine L Nicholson et al.The composition range of aluminosilicate geopolymers[J].Journal of the European Ceramic Society,2004,25(09):1471. |
[5] | Swanepoel JC.;Strydom CA. .Utilisation of fly ash in a geopolymeric material[J].Applied Geochemistry: Journal of the International Association of Geochemistry and Cosmochemistry,2002(8):1143-1148. |
[6] | Bankowski P;Zou L;Hodges R .Reduction of metal leaching in brown coal fly ash using geopolymers[J].Journal of Hazardous Materials,2004,114(1-3):59. |
[7] | Bakharev T .Geopolymeric materials prepared using glass fly ash and elevated temperature curing[J].Cement and Concrete Research,2005,35(06):1224. |
[8] | Van Jaarsveld J G S;Van Deventer J S J;Lukey G C .The effect of composition and temperature on the properties of fly ash and kaolinite-based geopolymers[J].Chemical Engineering Journal,2002,89(1-3):63. |
[9] | A.Palomo;M.W.Grutzeck .Alkali-activated fly ashes A cement for the future[J].Cement and Concrete Research,1999(8):1323-1329. |
[10] | Glukhovsky V D;Rostovskaja G S;Rnmyna G V.High strength slag-alkaline cements[A].France:Paris,1980:164. |
[11] | Yip C K;Lukey G C;Van Deventer J S J .Effect of blast furnace slag addition on microstructure and properties of metakaolinite geopolymeric materials[J].British Ceramic Transactions,2004,153:187. |
[12] | C.K. Yip;G.C. Lukey;J.S.J. van Deventer .The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation[J].Cement and Concrete Research,2005(9):1688-1697. |
[13] | Mackenzie Kenneth J D.What are these things called geopolymers?A physico-chemical perspective[A].,2004:175. |
[14] | 冶金工业部建筑研究总院.水玻璃耐酸混凝土[M].北京,1985 |
[15] | A. Fernandez-Jimenez;A. Palomo .Characterisation of fly ashes. Potential reactivity as alkaline cements[J].Fuel,2003(18):2259-2265. |
[16] | Lee WKW.;van Deventer JSJ. .Structural reorganisation of class F fly ash in alkaline silicate solutions[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2002(1):49-66. |
[17] | Shigemoto N;Sugiyama S;Hayashi H et al.Characterization of Na-X,Na-A and Coal fly ash zeolites and their amorphous precursors by IR,MAS,NMR,and XPS[J].Journal of Materials Science,1995,30(22):5777. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%