以锆和硅的醇盐为原料,合成了平面波导用紫外光敏性ZrO2-SiO2有机-无机杂化溶胶-凝胶光学材料,用旋涂法在单晶硅片上制备了其光学薄膜.用棱镜耦合仪、FTIR红外光谱仪和原子力显微镜(AFM)等测试了薄膜的厚度和折射率、结构基团和薄膜表面粗糙度,并用棱镜耦合法测试了其平板型光波导的光传输损耗.结果表明:该杂化材料可用于制备厚达约20 μm、折射率在1.45~1.50间可调、表面粗糙度小(约0.2 nm)的均匀光学薄膜;以这些杂化薄膜为导光层和衬底层的平板型光波导的光传输损耗小于1dB/cm.
参考文献
[1] | Sorek Y.;Weiss AM.;Reisfeld R. .EFFECT OF COMPOSITION AND MORPHOLOGY ON THE SPECTRAL PROPERTIES AND STABILITY OF DYES DOPED IN A SOL-GEL GLASS WAVEGUIDE[J].Chemical Physics Letters,1995(5-6):371-378. |
[2] | Segawa H;Omura K;Arai Y et al.[J].Journal of Photopolymer Science and Technology,2002,15(01):13. |
[3] | 钱国栋,王民权.若干无机/有机复合光功能材料及相关器件研究进展[J].硅酸盐学报,2001(06):596-601. |
[4] | Hayakawa T;Imaizumi D;Nogami M .[J].Journal of Materials Research,2000,15(02):530. |
[5] | Daniele Blanc;Pascal Peyrot;Clement Sanchez;Cedric Gonnet .Nonlinear hybrid materials: a potential for integrated light sources[J].Optical engineering,1998(4):1203-1207. |
[6] | Mennig M;Fries K;Lindenstruth M et al.[J].Thin Solid Films,1999,351(1-2):230. |
[7] | Bae B-S;Park O-H;Charters R et al.[J].Journal of Materials Research,2001,16(11):3184. |
[8] | Rantala JT.;Kivimaki L.;Descour MR.;Levy R. .Direct UV patterning of thick hybrid glass films for micro-opto-mechanical structures[J].Electronics Letters,2000(6):530-531. |
[9] | Wisian Neilson P.Inorganic and Organometallic Polymers II-Advanced Materials and Intermediates[M].Washington,DC:American Chemistry Society,1994:183. |
[10] | Brinker C J;Scherer G W.Sol-Gel Science:The Physics and Chemistry of Sol-Gel Processing[M].San Diego:academic Press,1990 |
[11] | Yeatman E M;Dawnay EJC .[J].Journal of Sol-Gel Science and Technology,1997,8:1007. |
[12] | Ballato J;Riman RE;Snitzer E .Sol-gel synthesis of fluoride optical materials for planar integrated photonic applications[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1997(0):126-136. |
[13] | Xu J;Almeida R M .[J].Journal of Sol-Gel Science and Technology,2000,19:243. |
[14] | Buestrich R;Kahlenberg F;Popall M et al.[J].Journal of Sol-Gel Science and Technology,2001,20:181. |
[15] | 曹冰,朱从善.采用有机改性硅醇盐甲基三乙氧基硅烷制备无支撑孤立膜[J].硅酸盐学报,1998(06):768-772. |
[16] | Ribeiro SJL;Messaddeq Y;Gonvalves R R et al.[J].Applied Physics Letters,2000,77(22):3502. |
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