以对硝基苯胺、环氧氯丙烷等为主要原料,经过重氮化、偶合等反应合成了对硝基偶氮苯酚(Ⅰ)和对硝基偶氮苯缩水甘油醚(Ⅱ);以丁二酸酐和环氧丙醇为原料合成了全羧基超支化聚酯(Ⅲ);利用(Ⅲ)的羧基与(Ⅱ)的环氧基团的开环反应制备了对硝基偶氮苯功能化的超支化聚酯(Ⅳ),并用FT-IR、UV/Vis、1H-NMR、DSC、GPC等表征了化学结构,研究了(Ⅱ)和(Ⅳ)在紫外光作用下的顺-反异构化.
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