合成V2O5-V2O3-Li2O体系的3种化合物LiV3O8、γ-LiV2O5和VO2,并以其作为热电池正极活性物质、锂硼合金为负极、LiCl-KCl为电解质进行500 ℃、100 mA/cm2的放电实验,研究该正极活性物质在放电中的物相转变过程,同时对V2O5、β-Li0.3V2O5、VnO2n+1和VnO2n-1的放电反应进行分析.结果表明,LiV3O8、γ-LiV2O5和VO2均进行分解式放电反应,生成LiV2O5、Li3VO4、V2O3和LiVO2等物相.分析认为V2O5和β-Li0.3V2O5可能出现嵌入反应直至转变为γ-LiV2O5,再由γ-LiV2O5进行放电,VnO2n+1和VnO2n-1放电最终也将生成Li3VO4和V2O3.γ-LiV2O5和VO2放电过程中V4+歧化反应产生Li3VO4相和V2O3相,Li3VO4相较差的电子导电性使正极材料失去快速放电能力.
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