采用真空蒸发的方法交替沉积Ag和TCNQ分子制备了Ag-TCNQ金属有机双层膜.研究了在大气,真空室,干燥器,饱和蒸汽室,水浸没5种不同环境下Ag-TCNQ络合物形成过程中双层膜中的传质情况.结果显示氧气对传质过程基本无影响;而随着环境湿度的增加,传质速度显著加快,并采用一种电化学反应机制对这种加速现象做出了解释.
参考文献
| [1] | Potember R S;Poehler T O;Cowan D O .[J].Applied Physics Letters,1979,34:405. |
| [2] | Potember R S;Poehler T O;Benson R C .[J].Applied Physics Letters,1982,41:548. |
| [3] | Potember R S;Poehler T O;Rappa A et al.[J].Synthetic Metals,1982,4:371. |
| [4] | Sato C;Wakamatsu S;Tadokoro K et al.[J].Journal of Applied Physics,1990,68:6536. |
| [5] | Yamaguchi S;Viands C A;Potember R S .[J].Journal of Vacuum Science and Technology B:Microelectronics and Nanometer Structures,1991,9:1129. |
| [6] | Hua Z Y;Chen G R .[J].VACUUM,1992,43:1019. |
| [7] | Sun SQ.;Zhu DB.;Wu PJ. .THE PREPARATION, CHARACTERIZATION OF AMORPHOUS CU-TCNQ FILM WITH A LOW DEGREE OF CHARGE-TRANSFER (DCT) AND ITS ELECTRIC SWITCHING PROPERTIES[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1997(1/2):192-196. |
| [8] | Hoagland J J;Wang X D;Hipps K W .[J].Chemistry of Materials,1993,5:54. |
| [9] | 叶钢锋;严学俭;潘钢 等.[J].真空科学与技术,2001,21:91. |
| [10] | Xu W;Chen G R;Hua Z Y .[J].Applied Physics Letters,1995,67:2241. |
| [11] | Tromp R M;LeGoues F K;Ho P S.[J].Journal of Vacuum Science and Technology A-Vacuum Surfaces and Films,1985(03):782. |
| [12] | Faupel F;Willecke R;Thran A .[J].Materials Science and Engineering,1998,R22:1. |
| [13] | Thran A;Strunskus T;Zaporojtchenko V et al.[J].Applied Physics Letters,2002,81:244. |
| [14] | Nordman O;Nordman N .[J].Optics Communications,2001,193:147. |
| [15] | Hopkins J .[J].Applied Physics Letters,1986,7:129. |
| [16] | 魏宝明.金属腐蚀理论及应用[M].北京:化学工业出版社,2001 |
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