选取两种不同微观结构的蝴蝶翅膀作为模板,制备了具备蝶翅结构的TiO2膜,以它作为光阳极,组装成染料敏化太阳能电池.比较了两种电池的电流电压曲线,结果表明,采用准蜂窝状蝶翅膀光阳极的电池其光电性能优于准光子晶体蝶翅膀结构.对两种结构光阳极的微观形貌和反射光谱进行了表征,解释了电池性能的差异.
参考文献
[1] | Gr(o)tzel M .Photoelectrochemical cells[J].Nature,2001,414(6861):338. |
[2] | M.Gratzel .Perspectives for Dye-sensitized Nanocrystalline Solar Cells[J].Progress in photovoltaics,2000(1):171-185. |
[3] | Satoshi UCHIDA;Ryoji CHIBA;Miho TOMIHA .Application of Titania Nanotubes to a Dye-sensitized Solar Cell[J].電気化学および工業物理化学,2002(6):418-420. |
[4] | 马玉涛,林原,肖绪瑞,李学萍,周晓文.TiO2纳米管薄膜的制备及其光散射性能[J].科学通报,2005(17):1824-1828. |
[5] | Mor GK;Varghese OK;Paulose M;Shankar K;Grimes CA .A review on highly ordered, vertically oriented TiO2 nanotube arrays: Fabrication, material properties, and solar energy applications[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2006(14):2011-2075. |
[6] | Ismael F C;Nei J L;Claudia L et al.Dye-sensitized solar cells based on TiO2 nanotubes and a solid-state electrolyte[J].J Photochem Photob A:Chem,2007,189(2-3):153. |
[7] | Three-dimensional photonic-crystal emitter for thermal photovoltaic power generation[J].Applied physics letters,2003(2):380-382. |
[8] | Halaoui L I;Abrams N M;Mallouk T E .Increasing the conversion efficiency of dye-sensitized TiO2 photoelectrochemical cells by coupling to photonic crystals[J].Journal of Physical Chemistry B,2005,109(13):6334. |
[9] | Huisman CL;Schoonman J;Goossens A .The application of inverse titania opals in nanostructured solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2005(1):115-124. |
[10] | Huang S Y;Schlichthorl G;Nozik A J et al.Charge recombination in dye-sensitized nanocrystalline TiO2 solar cells[J].Journal of Physical Chemistry B,1997,101(14):2576. |
[11] | 任露泉,邱兆美,韩志武,关会英,邬立岩.绿带翠凤蝶翅面结构光变色机理的试验研究[J].中国科学E辑,2007(07):952-957. |
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