染料敏化太阳能电池以其成本低廉、原材料丰富、制作工艺简单、理论转换效率高、对环境无污染等优势而备受人们关注,并在工业化生产中逐渐得到推广和应用.虽然人们在物理和化学方面对其进行了大量的研究,但其转换效率并没有得到明显的提高.对电极作为染料敏化太阳能电池的重要组成部分,其材料的性能直接影响着染料敏化太阳能电池的转换效率.为此,不少科研工作者提出了一个通过优化对电极材料自身结构来提高整个染料敏化太阳能电池光电性能的议题.着重综述了近几年对电极材料自身结构优化方面具有代表性的研究成果.
参考文献
[1] | O'Regan B;Grǎtzel M .A low-cost high-efficiency solar cell based on dye sensitized colloidal TiO2 films[J].NATURE,1991,353:737. |
[2] | Snaith H J;Schmidt-Mende L .Advances in liquid-electrolyte and solid-state dye-sensitized solar cells[J].Advanced Materials,2007,19:3187. |
[3] | Papageorgiou N.;Gratzel M.;Maier WF. .AN IODINE/TRIIODIDE REDUCTION ELECTROCATALYST FOR AQUEOUS AND ORGANIC MEDIA[J].Journal of the Electrochemical Society,1997(3):876-884. |
[4] | Grǎtzel M .Photovoltaic performance and long-term stability of dye-sensitized meosocopic solar cells[J].Comptes Rendus Chim,2006,9(5-6):578. |
[5] | Yella A;Lee H W;Grǎtzel M et al.Porphyrirrsensitized solar cells with cobalt (Ⅱ / Ⅲ)-based redox electrolyte exceed 12 percent efficiency[J].SCIENCE,2011,334:629. |
[6] | Murakami TN;Ito S;Wang Q;Nazeeruddin MK;Bessho T;Cesar I;Liska P;Humphry-Baker R;Comte P;Pechy P .Highly efficient dye-sensitized solar cells based on carbon black counter electrodes[J].Journal of the Electrochemical Society,2006(12):A2255-A2261. |
[7] | Murakami TN;Gratzel M .Counter electrodes for DSC: Application of functional materials as catalysts[J].Inorganica Chimica Acta,2008(3):572-580. |
[8] | 孔凡太,戴松元.染料敏化太阳电池研究进展[J].化学进展,2006(11):1409-1424. |
[9] | 盛显良,赵勇,翟锦,朱道本.基于ZnO光阳极的染料敏化太阳电池[J].化学进展,2007(01):59-65. |
[10] | 李国,胡志强,高岩,刘敬肖,刘贵山.染料敏化太阳能电池对电极的研究进展[J].材料导报,2007(12):16-19,40. |
[11] | 奚小网,胡林华,方霞琴,戴松元.TiO2薄膜优化对染料敏化太阳电池性能的影响[J].无机化学学报,2011(07):1353-1357. |
[12] | 吴迪,沈珍,薛兆历,游效曾.卟啉类光敏剂在染料敏化太阳能电池中的应用[J].无机化学学报,2007(01):1-14. |
[13] | 周煜华,许祖勋,胡泉源,王世敏.染料敏化太阳能电池的染料敏化剂的最新研究进展[J].广州化工,2012(07):11-15. |
[14] | 尹艳红,许泽辉,冯磊硕,杨书廷,李承斌.染料敏化太阳能电池对电极的研究进展[J].材料导报,2009(09):109-112. |
[15] | 张盼盼,朱枫,艾希成,付立民,徐东升,张建平.锌掺杂对TiO2染料敏化电池光阳极中电荷俘获态分布及电子复合过程的影响[J].高等学校化学学报,2013(02):418-422. |
[16] | 孙振范,李玉光.二氧化钛纳米晶薄膜的吸收光谱和激发发射光谱[J].无机化学学报,2006(12):2173-2178. |
[17] | 赵义平,陶汝华,董伟伟,邵景珍,邓赞红,方晓东.二氧化钛有序纳米阵列染料敏化太阳能电池光阳极的研究进展[J].材料导报,2012(23):1-7. |
[18] | 肖尧明,吴季怀,李清华,谢桂香,岳根田,叶海峰,兰章,黄妙良,林建明.柔性染料敏化太阳能电池光阳极的制备及其应用[J].科学通报,2009(16):2425-2430. |
[19] | 赵勇,盛显良,翟锦.染料敏化太阳电池中TiO2光阳极研究进展[J].化学进展,2006(11):1452-1459. |
[20] | 金晓艳,刘志勇,王艳芳,蔡传兵,鲁玉明,胡林华,戴松元.碳纳米管在染料敏化太阳电池光阳极中的应用[J].功能材料与器件学报,2011(01):13-21. |
[21] | Li P J;Wu J H;Lin J M et al.Improvement of performance of dye-sensitized solar cells based on electrodeposited-platinum counter electrode[J].Electrochimica Acta,2008,53:4161. |
[22] | Gao F;Wang Y;Shi D;Zhang J;Wang MK;Jing XY;Humphry-Baker R;Wang P;Zakeeruddin SM;Gratzel M .Enhance the optical absorptivity of nanocrystalline TiO2 film with high molar extinction coefficient ruthenium sensitizers for high performance dye-sensitized solar cells[J].Journal of the American Chemical Society,2008(32):10720-10728. |
[23] | Guai G H;Song Q L;Guo C X et al.Graphene-Pt/ITO counter electrode to significantly reduce Pt loading and enhance charge transfer for high performance dye-sensitized solar cell[J].SOLAR ENERGY,2012,86:2041. |
[24] | Chen H Y;Liao J Y;Lei B X et al.Highly catalytic carbon nanotube/Pt nanohybrid-based transparent counter electrode for efficient dye-sensitized solar cells[J].Chem Asian J,2012,7:1795. |
[25] | Syrrokostas, G.;Siokou, A.;Leftheriotis, G.;Yianoulis, P..Degradation mechanisms of Pt counter electrodes for dye sensitized solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2012:119-127. |
[26] | Im J S;Lee S K;Yun J et al.CNT-Pt counter electrode prepared using a polyol process to achieve high performance in dye-sensitised solar cells[J].Journal of Industrial and Engineering Chemistry,2012,18:1023. |
[27] | Kay A.;Gratzel M. .LOW COST PHOTOVOLTAIC MODULES BASED ON DYE SENSITIZED NANOCRYSTALLINE TITANIUM DIOXIDE AND CARBON POWDER[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1996(1):99-117. |
[28] | Kazuharu Suzuki;Makoto Yamaguchi;Mikio Kumagai;Shozo Yanagida .Application of Carbon Nanotubes to Counter Electrodes of Dye-sensitized Solar Cells[J].Chemistry Letters,2003(1):28-29. |
[29] | Anwar H;George A E;Hill I G .Vertically-aligned carbon nanotube counter electrodes for dye-sensitized solar cells[J].SOLAR ENERGY,2013,88:129. |
[30] | Munkhbayar B;Nine M J;Jeoun J et al.Synthesis of a grapheneetungsten composite with improved dispersibility of graphene in an ethanol solution and its use as a counter electrode for dye-sensitised solar cells[J].Journal of Power Sources,2013,230:207. |
[31] | Choi, H.J.;Gong, H.H.;Park, J.-Y.;Hong, S.C. .Characteristics of dye-sensitized solar cells with surface-modified multi-walled carbon nanotubes as counter electrodes[J].Journal of Materials Science,2013(2):906-912. |
[32] | 范乐庆,吴季怀,黄昀昉,林建明.阴极修饰对染料敏化TiO2太阳能电池性能的改进[J].电子元件与材料,2003(05):1-3. |
[33] | Xia J B;Yuan C C;Yanagida S .Novel counter electrode V2O5/Al for solid dye-sensitized solar cells[J].ACS Appl Mater Interf,2010,2:2136. |
[34] | Yun, S.;Wang, L.;Guo, W.;Ma, T..Non-Pt counter electrode catalysts using tantalum oxide for low-cost dye-sensitized solar cells[J].Electrochemistry communications,2012:69-73. |
[35] | Mingxing Wu;Yudi Wang;Xiao Lin .Economical and effective sulfide catalysts for dye-sensitized solar cells as counter electrodes[J].Physical chemistry chemical physics: PCCP,2011(43):19298-19301. |
[36] | Park S H;Shin K H;Kim J Y et al.The application of camphorsulfonic acid doped polyaniline films prepared on TCOfree glass for counter electrode of bifacial dye-sensitized solar cells[J].Journal of Photochemistry and Photobiology A:Chemistry,2012,245:1. |
[37] | Effects of mesoscopic poly(3,4-ethylenedioxythiophene) films as counter electrodes for dye-sensitized solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2010(6):1716. |
[38] | Yum J H;Baranoff E;Grǎtzel M et al.A cobalt complex redox shuttle for dye-sensitized solar cells with high open-circuit potentials[J].Nat Commun,2012,3:631. |
[39] | Wu M X;Ma T L;Wang L et al.In situ synthesized economical tungsten dioxide imbedded in mesoporous carbon for dye-sensitized solar cells as counter electrode catalyst[J].J Phys Chem C,2011,115:22598. |
[40] | Lin, X.;Wu, M.;Wang, Y.;Hagfeldt, A.;Ma, T. .Novel counter electrode catalysts of niobium oxides supersede Pt for dye-sensitized solar cells[J].Chemical communications,2011(41):11489-11491. |
[41] | Yue G T;Lin J Y;Wu J H et al.A catalytic composite film of MoS2/graphene flake as a counter electrode for Pt-free dye-sensitized solar cells[J].Electrochimica Acta,2012,85:162. |
[42] | Gong, F.;Wang, H.;Xu, X.;Zhou, G.;Wang, Z.-S. .In situ growth of Co _(0.85)Se and Ni _(0.85)Se on conductive substrates as high-performance counter electrodes for dye-sensitized solar cells[J].Journal of the American Chemical Society,2012(26):10953-10958. |
[43] | Al-Mamun, M.;Kim, J.-Y.;Sung, Y.-E.;Lee, J.-J.;Kim, S.-R..Pt and TCO free hybrid bilayer silver nanowire-graphene counter electrode for dye-sensitized solar cells[J].Chemical Physics Letters,2013:115-119. |
[44] | Xu S J;Liu G W;Li J et al.Incorporating conductor paste in a low-temperature fabrication process for large mesoporous carbon counter electrode in dye-sensitized solar cells[J].Electrochimica Acta,2012,76:504. |
[45] | Feng Gong;Zhuoqun Li;Hong Wang .Enhanced electrocatalytic performance of graphene via incorporation of SiO2 nanoparticles for dye-sensitized solar cells[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(33):17321-17327. |
[46] | 叶报喜,李作鹏,马祥元,张世国,胡晓东,张庆华,张晓萍,邓友全.电聚合PANI作为低成本离子液体型DSSC对电极[J].太阳能学报,2011(06):826-830. |
[47] | Kaniyoor A;Ramaprabhu S .Enhanced efficiency in dye sensitized solar cells with nanostructured Pt decorated multiwalled carbon nanotube based counter electrode[J].Electrochimica Acta,2012,72:199. |
[48] | Bu C H;Tai Q D;Liu Y M et al.A transparent and stable polypyrrole counter electrode for dye-sensitized solar cell[J].Journal of Power Sources,2013,221:78. |
[49] | 徐顺建,罗玉峰,李水根,钟炜,黄明道.低温制备介孔碳对电极构建的染料敏化太阳电池优化研究[J].无机材料学报,2012(01):83-88. |
[50] | 储玲玲,高玉荣,武明星,王琳琳,马廷丽.附着性能优异的碳对电极的制备及其在染料敏化太阳能电池中的应用[J].物理化学学报,2012(07):1739-1744. |
[51] | 巩翠翠,胡志强,苏岩,李璞,周红茹,康姣.染料敏化太阳能电池改性PEDOT:PSS对电极的制备[J].微细加工技术,2008(06):58-60. |
[52] | Paul G S;Kim J H;Kim M S et al.Different hierarchical nanostructured carbons as counter electrodes for CdS quantum dot solar cells[J].ACS Appl Mater Interf,2012,4:375. |
[53] | Yang Y Y;Zhang Q X;Wang T Z et al.Novel tandem structure employing mesh-structured Cu2S counter electrode for enhanced performance of quantum dot-sensitized solar cells[J].Electrochimica Acta,2013,88:44. |
[54] | Fan B H;Mei X G;Sun K et al.Conducting polymer/carbon nanotube composite as counter electrode of dye-sensitized solar cells[J].Applied Physics Letters,2008,93:143103. |
[55] | Lu-Yin Lin;Po-Chin Nien;Chuan-Pei Lee .Low-Temperature Flexible Photoanode and Net-Like Pt Counter Electrode for Improving the Performance of Dye-Sensitized Solar Cells[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(49):21808-21815. |
[56] | Han, J.;Kim, H.;Kim, D.Y.;Jo, S.M.;Jang, S.-Y. .Water-soluble polyelectrolyte-grafted multiwalled carbon nanotube thin films for efficient counter electrode of dye-sensitized solar cells[J].ACS nano,2010(6):3503-3509. |
[57] | 陈小焱,王璟,丁雨田.直流磁控溅射制备ZAO透明导电薄膜及性能研究[J].功能材料,2013(01):139-142. |
[58] | Kang, JH;Oh, YJ;Paek, SM;Hwang, SJ;Choy, JH .Electrochromic device of PEDOT-PANI hybrid system for fast response and high optical contrast[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2009(12):2040-2044. |
[59] | Kim S H;Choi H S;Dao V D et al.Efficiency enhancement of dye-sensitized solar cell using Pt hollow sphere counter electrode[J].J Phys Chem C,2011,115:25529. |
[60] | Lee, Y.-L.;Chen, C.-L.;Chong, L.-W.;Chen, C.-H.;Liu, Y.-F.;Chi, C.-F. .A platinum counter electrode with high electrochemical activity and high transparency for dye-sensitized solar cells[J].Electrochemistry communications,2010(11):1662-1665. |
[61] | Yang, C.-C.;Zhang, H.Q.;Zheng, Y.R. .DSSC with a novel Pt counter electrodes using pulsed electroplating techniques[J].Current applied physics: the official journal of the Korean Physical Society,2011(Suppl.1):S147-S153. |
[62] | 马换梅,田建华,廖文明,单忠强.染料敏化太阳能电池Pt/NiP/ITO对电极的制备和性能[J].硅酸盐学报,2012(10):1519-1523. |
[63] | Won Jae Lee;Easwaramoorthi Ramasamy;Dong Yoon Lee .Efficient Dye-Sensitized Solar Cells with Catalytic Multiwall Carbon Nanotube Counter Electrodes[J].ACS applied materials & interfaces,2009(6):1145-1149. |
[64] | Zhu G;Pan L K;Lu T et al.Electrophoretic deposition of carbon nanotubes films as counter electrodes of dye-sensitized solar cells[J].Electrochimica Acta,2011,56:10288. |
[65] | 李晓雪;张君;图布新 等.纳米结构聚苯胺和聚吡咯电活性的对比研究[J].显微与测量,2011,8(03):66. |
[66] | Lin, W.-J.;Hsu, C.-T.;Tsai, Y.-C. .Dye-sensitized solar cells based on multiwalled carbon nanotube-titania/titania bilayer structure photoelectrode[J].Journal of Colloid and Interface Science,2011(2):562-566. |
[67] | Chou C S;Huang C L;Yang R Y et al.The effect of SWCNT with the functional group deposited on the counter electrode on the dye-sensitized solar cell[J].Adv Powder Techn,2010,21:542. |
[68] | Jiang W;Yin L;Liu H Z et al.Nanograss-structured counter electrode for dye-sensitized solar cells[J].Journal of Power Sources,2012,218:405. |
[69] | 王永祯,李智辉,蔡晓岚.MWCNT/Fe-Co/PANI复合材料的制备及其电催化性能[J].炭素,2012(02):32-37,12. |
[70] | 张莉,李琛.氧等离子体改性的聚苯胺/碳纳米管电化学性能[J].无机化学学报,2012(04):698-702. |
[71] | Wu, M.;Lin, X.;Hagfeldt, A.;Ma, T. .A novel catalyst of WO_2 nanorod for the counter electrode of dye-sensitized solar cells[J].Chemical communications,2011(15):4535-4537. |
[72] | Yun D J;Ra H;Rhee S W .Concentration effect of multiwalled carbon nanotube and poly (3,4-ethylenedioxythiophene) polymerized with poly(4-styrenesulfonate) conjugated film on the catalytic activity for counter electrode in dye sensitized solar cells[J].RENEWABLE ENERGY,2013,50:692. |
[73] | Kung, C.-W.;Chen, H.-W.;Lin, C.-Y.;Huang, K.-C.;Vittal, R.;Ho, K.-C. .CoS acicular nanorod arrays for the counter electrode of an efficient dye-sensitized solar cell[J].ACS nano,2012(8):7016-7025. |
[74] | Chen J K;Meng F Q;Gui X C et al.The application of a three dimensional CNT-sponge as the counter electrode for dye-sensitized solar cells[J].CARBON,2012,50:5618. |
[75] | Durr M;Schmid A;Obermaier M;Rosselli S;Yasuda A;Nelles G .Low-temperature fabrication of dye-sensitized solar cells by transfer of composite porous layers[J].Nature materials,2005(8):607-611. |
[76] | Jeon S S;Kim C;Ko J et al.Pt nanoparticles supported on polypyrrole nanospheres as a catalytic counter electrode for dye-sensitized solar cells[J].J Phys Chem C,2011,115:22O35. |
[77] | Sun B;Hao Y Z;Guo F et al.Fabrication of poly(3-hexylthiophene)/CdS/ZnO core-shell nanotube array for semiconductor-sensitized solar cell[J].J Phys Chem C,2012,116:1395. |
[78] | Development of a TiO_2 modified optical fiber electrode and its incorporation into a photoelectrochemical reactor for wastewater treatment[J].Water research: A journal of the international water association,2009(14):3593-3603. |
[79] | Minna Toivola;Marju Ferenets;Peter Lund;Ali Harlin .Photovoltaic Fiber[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2009(8):2799-2802. |
[80] | Zou D C;Wang D;Chu Z Z et al.Fiber-shaped flexible solar cells[J].Coordination Chemistry Review,2010,254(9-10):1169. |
[81] | Bajpai R;Roy S;Koratkar N et al.NiO nanoparticles deposited on graphene platelets as a cost-effective counter electrode in a dye sensitized solar cell[J].CARBON,2013,56:56. |
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