随着固体氧化物燃料电池（SOFC）的工作温度从1000℃降低到600-800℃，铁素体不锈钢成为SOFC连接体材料的最佳选择，但在高温氧化气氛下，氧化层快速生长以及cr的毒化问题使得电池堆性能大大降低。目前，主要的解决方式是在基体材料表面涂镀保护膜层和材料改性。前者由于生产简单、成本低成为当前研究热点。本文主要介绍金属连接体保护膜的分类和研究现状，并探讨各膜层材料的优缺点及发展前景。
With the solid oxide fuel cells (SOFC) operation temperature reduced from 1000℃ to 600-800℃, Fe-based ferritic stainless steels was the best candidate for SOFC interconnect applications. However, rapid scale growth and the volatility of Cr led to significant SOFC performance degradation. Two solutions were suggested to solve the problem, i.e. applying surface protective coating and bulk material modification, and the former one was considered as potential remedy due to its low cost and easy fabrication. The focus of this paper was to categorize the current coatings for interconnects, as well as the characteristics and prospects of coatings.
参考文献
| [1] | Fergus JW .Metallic interconnects for solid oxide fuel cells[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2005(1/2):271-283. |
| [2] | W.Z.Zhu;S.C.Deevi .Opportunity of metallic interconnects for solid oxide fuel cells: a status on contact resistance[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2003(6):957-972. |
| [3] | Fergus JW .Lanthanum chromite-based materials for solid oxide fuel cell interconnects[J].Solid state ionics,2004(1/2):1-15. |
| [4] | B.C. Church;T.H. Sanders;R.F. Speyer .Thermal expansion matching and oxidation resistance of Fe-Ni-Cr interconnect alloys[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2007(0):334-340. |
| [5] | Zhenguo Yang .Recent advances in metallic interconnects for solid oxide fuel cells[J].International Materials Reviews,2008(1):39-54. |
| [6] | Junwei Wu,Xingbo Liu.Recent Development of SOFC Metallic Interconnect[J].材料科学技术学报（英文版）,2010(04):293-305. |
| [7] | Nima Shaigan .A review of recent progress in coatings, surface modifications and alloy developments for solid oxide fuel cell ferritic stainless steel interconnects[J].Journal of Power Sources,2010(6):1529. |
| [8] | Xuguang Li;Jong-Won Lee;Branko N. Popov .Performance Studies Of Solid Oxide Fuel Cell Cathodes In The Presence Of Bare And Cobalt Coated E-brite Alloy Interconnects[J].Journal of Power Sources,2009(2):356-362. |
| [9] | Chun-Lin Chu;Jye Lee;Tien-Hsi Lee;Yung-Neng Cheng .Oxidation Behavior Of Metallic Interconnect Coated With La-sr-mn Film By Screen Painting And Plasma Sputtering[J].International journal of hydrogen energy,2009(1):422-434. |
| [10] | Gannon PE;Tripp CT;Knospe AK;Ramana CV;Deibert M;Smith RJ;Gorokhovsky V;Shutthanandan V;Gelles D .High-temperature oxidation resistance and surface electrical conductivity of stainless steels with filtered arc Cr-Al-N multilayer and/or superlattice coatings[J].Surface & Coatings Technology,2004(0):55-61. |
| [11] | Kayani A;Smith RJ;Teintze S;Kopczyk M;Gannon PE;Deibert MC;Gorokhovsky VI;Shutthanandan V .Oxidation studies of CrAlON nanolayered coatings on steel plates[J].Surface & Coatings Technology,2006(3/4):1685-1694. |
| [12] | Xingbo Liu;Christopher Johnson;Chengming Li;Jing Xu;Caleb Cross .Developing TiAlN coatings for intermediate temperature solid oxide fuel cell interconnect applications[J].International journal of hydrogen energy,2008(1):189-196. |
| [13] | Junwei Wu;Chengming Li;Christopher Johnson;Xingbo Liu .Evaluation of SmCo and SmCoN magnetron sputtering coatings for SOFC interconnect applications[J].Journal of Power Sources,2008(2):833-840. |
| [14] | B. A. Pint .Experimental Observations in Support of the Dynamic-Segregation Theory to Explain the Reactive-Element Effect[J].Oxidation of Metals,1996(1/2):1-37. |
| [15] | Hou PY. .Sulfur segregation to growing Al2O3/alloy interfaces[J].Journal of Materials Science Letters,2000(7):577-578. |
| [16] | R. Cueff;H. Buscail;E. Caudron .OXIDATION BEHAVIOUR OF KANTHAL APM AND KANTHAL AF AT 1173 K: EFFECT OF YTTRIUM ALLOYING ADDITION[J].Surface Engineering,2003(1):58-64. |
| [17] | Paolo Piccardo;Roberta Amendola;Sébastien Fontana;Sébastien Chevalier;Gilles Caboches;Paul Gannon .Interconnect materials for next-generation solid oxide fuel cells[J].Journal of Applied Electrochemistry,2009(4):545-551. |
| [18] | Sebastien Fontana;Sebastien Chevalier;Gilles Caboche .Metallic interconnects for solid oxide fuel cell: Effect of water vapour on oxidation resistance of differently coated alloys[J].Journal of Power Sources,2009(1):136-145. |
| [19] | Christopher Johnson;Randall Gemmen;Nina Orlovskaya .Nano-structured self-assembled LaCrO_3 thin film deposited by RF-magnetron sputtering on a stainless steel interconnect material[J].Composites, Part B. Engineering,2004(2):167-172. |
| [20] | Christopher Johnson;Nina Orlovskaya;Anthony Coratolo;Caleb Cross;Junwei Wu;Randall Gemmen;Xingbo Liu .The Effect Of Coating Crystallization And Substrate Impurities On Magnetron Sputtered Doped Lacro_3 Coatings For Metallic Solid Oxide Fuel Cell Interconnects[J].International Journal of Hydrogen Energy,2009(5):2408-2415. |
| [21] | Yang ZG;Xia GG;Maupin GD;Stevenson JW .Conductive protection layers on oxidation resistant alloys for SOFC interconnect applications[J].Surface & Coatings Technology,2006(7):4476-4483. |
| [22] | Yang ZG;Xia GG;Maupin GD;Stevenson JW .Evaluation of perovskite overlay coatings on ferritic stainless steels for SOFC interconnect applications[J].Journal of the Electrochemical Society,2006(10):A1852-A1858. |
| [23] | Changbo Lee;Joongmyeon Bae .Oxidation-resistant Thin Film Coating On Ferritic Stainless Steel By Sputteringfor Solid Oxide Fuel Cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2008(18):6432-6437. |
| [24] | Choi JJ;Lee JH;Park DS;Hahn BD;Yoon WH;Lin HT .Oxidation resistance coating of LSM and LSCF on SOFC metallic interconnects by the aerosol deposition process[J].Journal of the American Ceramic Society,2007(6):1926-1929. |
| [25] | Mikkelsen L;Chen M;Hendriksen PV;Persson A;Pryds N;Rodrigo K .Deposition of La0.8Sr0.2Cr0.97V0.03O3 and MnCr2O4 thin films on ferritic alloy for solid oxide fuel cell application[J].Surface & Coatings Technology,2007(4/7):1262-1266. |
| [26] | Anthony Petric;Hang Ling .Electrical Conductivity and Thermal Expansion of Spinels at Elevated Temperatures[J].Journal of the American Ceramic Society,2007(5):1515-1520. |
| [27] | Burriel M;Garcia G;Santiso J;Hansson AN;Linderoth S;Figueras A .CO3O4 protective coatings prepared by Pulsed Injection Metal Organic Chemical Vapour Deposition[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2005(1):98-103. |
| [28] | Yang ZG;Xia GG;Simner SP;Stevenson JW .Thermal growth and performance of manganese cobaltite spinel protection layers on ferritic stainless steel SOFC interconnects[J].Journal of the Electrochemical Society,2005(9):A1896-A1901. |
| [29] | Zhenguo Yang;Guan-Guang Xia;Xiao-Hong Li;Jeffry W. Stevenson .(Mn,Co)_3O_4 spinel coatings on ferritic stainless steels for SOFC interconnect applications[J].International journal of hydrogen energy,2007(16):3648-3654. |
| [30] | Junwei Wu;Christopher D. Johnson;Yinglu Jiang;Randall S. Gemmen;Xingbo Liu .Pulse plating of Mn-Co alloys for SOFC interconnect applications[J].Electrochimica Acta,2008(2):793-800. |
| [31] | Junwei Wu;Christopher D. Johnson;Randall S. Gemmen;Xingbo Liu .The Performance Of Solid Oxide Fuel Cells With Mn-co Electroplated Interconnect As Cathode Current Collector[J].Journal of Power Sources,2009(2):1106-1113. |
| [32] | Junwei Wu;Randall S. Gemmen;Ayyakkannu Manivannan;Xingbo Liu .Investigation of Mn/Co coated T441 alloy as SOFC interconnect by on-cell tests[J].International journal of hydrogen energy,2011(7):4525-4529. |
| [33] | Gorokhovsky VI;Gannon PE;Deibert MC;Smith RJ;Kayani A;Kopczyk M;VanVorous D;Yang ZG;Stevenson JW;Visco S .Deposition and evaluation of protective PVD coatings on ferritic stainless steel SOFC interconnects[J].Journal of the Electrochemical Society,2006(10):A1886-A1893. |
| [34] | X. Montero;F. Tietz;D. Sebold;H.P. Buchkremer;A. Ringuede;M. Cassir;A. Laresgoiti;I. Villarreal .Mnco_(1.9)fe_(0.1)o_4 Spinel Protection Layer On Commercial Ferritic Steels For Interconnect Applications In Solid Oxide Fuel Cells[J].Journal of Power Sources,2008(1):172-179. |
| [35] | Wenhua Huang;Srikanth Gopalan;Uday B. Pal .Evaluation of Electrophoretically Deposited CuMn_(1.8)O_4 Spinel Coatings on Crofer 22 APU for Solid Oxide Fuel Cell Interconnects[J].Journal of the Electrochemical Society,2008(11):(B)1161-1167. |
| [36] | Bateni, MR;Wei, P;Deng, XH;Petric, A .Spinel coatings for UNS 430 stainless steel interconnects[J].Surface & Coatings Technology,2007(26):4677-4684. |
| [37] | Piccardo P;Gannon P;Chevalier S;Viviani M;Barbucci A;Caboche G;Amendola R;Fontana S .ASR evaluation of different kinds of coatings on a ferritic stainless steel as SOFC interconnects[J].Surface & Coatings Technology,2007(4/7):1221-1225. |
| [38] | Chen H;Lucas JA;Priyantha W;Kopczyk M;Smith RJ;Lund K;Key C;Finsterbusch M;Gannon PE;Deibert M .Thermal stability and oxidation resistance of TiCrAlYO coatings on SS430 for solid oxide fuel cell interconnect applications[J].Surface & Coatings Technology,2008(19):4820-4824. |
| [39] | Paul Gannon;Max Deibert;Preston White;Richard Smith;Hui Chen;Weerashinge Priyantha;Jake Lucas;Vladimir Gorokhovsky .Advanced PVD protective coatings for SOFC interconnects[J].International journal of hydrogen energy,2008(14):3991-4000. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%