采用液相沉积技术成功制备了SrTiO3薄膜,并研究其光催化性能.采用偏光显微镜、扫描电镜和X射线衍射分析研究了不同制备条件对SrTiO3薄膜结构和形貌的影响,以罗丹明B(RhB)为目标降解物研究SrTiO3薄膜紫外光催化性能,结果表明:基板表面的Si-OH组群为SrTiO3薄膜制备提供了积极的贡献作用,并且垂直沉积的基板更有助于提高SrTiO3薄膜的表面均匀性.沉积制备的SrTiO3薄膜在基板表面以叶状和丛状交叉方式生长,且在空气中600℃煅烧2h转化为高纯结晶态.沉积温度为70℃的SrTiO3薄膜,紫外光照射120 min RhB降解率达到98%以上.
参考文献
[1] | Hwang DW;Kirn HG;Lee JS;Kim J;Li W;Oh SH.Photocatalytic hydrogen production from water over m-doped La2Ti2O7 (M = Cr, Fe) under visible light irradiation (lambda > 420 nm)[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,20056(6):2093-2102. |
[2] | Li Li;Paul A. Salvador;Gregory S. Rohrer.Photocatalysts with internal electric fields[J].Nanoscale,20141(1):24-42. |
[3] | Xiaoyun Fan;Ling Zang;Min Zhang.A Bulk Boron-Based Photocatalyst for Efficient Dechlorination: K3B6O_(10)Br[J].Chemistry of Materials: A Publication of the American Chemistry Society,201410(10):3169-3174. |
[4] | Matsumoto T.;Niino A.;Baba S.;Numata K.;Miyake S..Low temperature preparation of perovskite oxide films by ECR sputtering assisted with microwave treatment[J].Surface & Coatings Technology,20030(0):611-614. |
[5] | Ji Huiming;Li Cuixia;Meng Hui.Effects of Rare-Earth La_2O_3 Addition on Microstructures and Electrical Properties of SrTiO_3 Varistor-Capacitor Dual Functional Ceramics[J].Journal of Rare Earths,20051(1):55-58. |
[6] | Pontes FM.;Longo E.;Leite ER.;Lee EJH.;Varela JA.;Pizani PS.;Campos CEM.;Lanciotti F.;Mastellaro V.;Pinheiro CD..Photoluminescence at room temperature in amorphous SrTiO3 thin films obtained by chemical solution deposition[J].Materials Chemistry and Physics,20032(2):598-602. |
[7] | Sang Woon Lee;Oh Seong Kwon;Cheol Seong Hwang.Chemically conformal deposition of SrTiO_3 thin films by Atomic Layer Deposition using conventional metal organic precursors and remote-plasma activated H_2O[J].Microelectronic engineering,20051(1):158-161. |
[8] | Kajiyoshi K;Yanagisawa K.Growth of ATiO(3) (A = Ba, Sr) dielectric thin film by a hydrothermal-electrochemical method[J].Journal of Physics. Condensed Matter,200414(14):S1351-S1360. |
[9] | LIU Jian;MIAO Hongyan;TAN Guoqiang;HE Zhongliang;XIA Ao.Preparation and Characterization of SrTiO3 Thin Film on Functional Organic Self-Assembled Monolayers[J].武汉理工大学学报(材料科学版)(英文版),2010(3):365-369. |
[10] | Yoshifumi Aoi;Hisae Kambayashi;Tomoe Deguchi;Kohsuke Yato;Shigehito Deki.Synthesis of nanostructured metal oxide by liquid-phase deposition[J].Electrochimica Acta,20071(1):175-178. |
[11] | Amin Yourdkhani;Armando K. Perez;Cuikun Lin.Magnetoelectric Perovskite-Spinel Bilayered Nanocomposites Synthesized by Liquid-Phase Deposition[J].Chemistry of Materials: A Publication of the American Chemistry Society,201022(22):6075-6084. |
[12] | Wen, QY;Gu, DE;Zhang, HW;Yang, QH;Li, YX;Liu, YL;Xiao, JQ.Magnetic properties of V-doped TiO2 nanocrystalline film synthesized by liquid phase deposition technique[J].Journal of Physics. D, Applied Physics,20095(5):55012-1-55012-4-0. |
[13] | Selective Growth of the Silicon-Oxide Nanodot Array Using Nanosphere Lithography and Liquid-Phase Deposition[J].IEEE transactions on nanotechnology,20103(3):361. |
[14] | Hou Yan-chao;Huang Jian-feng;Zhou Xuan.Preparation of Sm_2S_3 thin films by liquid phase deposition method with self-assembled monolayers[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2012:119-123. |
[15] | Ezhilvalavan S.;Tseng TY..Progress in the developments of (Ba,Sr)TiO3 (BST) thin films for Gigabit era DRAMs [Review][J].Materials Chemistry and Physics,20003(3):227-248. |
[16] | Ming-Chi Hsu;Yu-Ming Sun;Ing-Chi Leu;Min-Hsiung Hon.Microstructural and compositional studies of liquid-phase deposition derived PbTiO_3 thin films on LaNiO_3 substrates[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,200718(18):7639-7644. |
[17] | Gu, J.;Yang, S.;Yang, W.;Qi, Y.;Zhao, G.;Sun, H..Effects of NiFe_2O_4 on magnetoelectric coupling effect of BiFeO_3 thin films[J].Journal of Magnetism and Magnetic Materials,2014:140-143. |
[18] | Y.Q, Dai;J.M. Dai;X.W. Tang.Thickness effect on the properties of BaTiO_3-CoFe_2O_4 multilayer thin films prepared by chemical solution deposition[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2014:681-687. |
[19] | 王竹梅;刘波;谢志翔;李月明;沈宗洋;左建林.B掺杂量对TiO2纳米粉体的结构与光催化性能影响研究[J].人工晶体学报,2016(1):229-235. |
[20] | 和娇娇;杜慧玲;杜娴;刘俊.镧掺杂混晶结构TiO2纳米粉体的制备及其光催化性能[J].人工晶体学报,2014(6):1529-1534. |
[21] | 张文杰;毕菲非;孙欣;孙鹏.煅烧温度对溶胶-凝胶法制备钛酸锶性能的影响[J].材料热处理学报,2013(z2):23-27. |
[22] | 王宏;都玲;孙欣;张文杰.PEG4000用量对溶胶-凝胶法制备多孔钛酸锶光催化剂的影响[J].材料工程,2014(12):39-43. |
[23] | 刘剑;董秀珍;郝斌;李悦.Piranha改性玻璃基板液相沉积制备SrTiO3功能陶瓷薄膜[J].无机化学学报,2012(5):1065-1069. |
[24] | 刘剑;谈国强;苗鸿雁;贺中亮;夏傲.OTS自组装单层膜诱导定向生长SrTiO3功能陶瓷薄膜[J].无机化学学报,2009(3):517-521. |
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