以十六烷基三甲基溴化铵((CTAB)为模板剂,采用溶胶-凝胶法配合水热晶化合成了具有短程有序介孔结构的层状化合物Zr(HPO4) 2.通过XRD、N2吸附、HRTEM等技术对样品的物相、孔结构和形貌进行了表征,结果表明,按n(CTAB):n(Zr)=O.8引入CTAB作为模板剂所合成的前驱体在120℃水热晶化48h.可以得到比表面积为66.9m2/g、孔容为0.11cm3/g、平均孔径为8.1nm的单相Zr(HPO4) 2结晶化合物.
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