硫化镉(CdS)是一种研究广泛的光催化剂,禁带能为2.4 eV,可以吸收波长小于520 nm的紫外和可见光,吸收波长范围宽,作为光催化剂具有较大的优势.纯CdS的光催化效率较低,在水溶液中易发生光腐蚀,致使催化寿命缩短,限制了CdS的应用.利用载体比表面积大,易于离子交换且有利于电子传递等优点,将纳米CdS制备成负载型催化剂,可以有效地提高CdS的光催化效率与稳定性,成为CdS改性的一种有效手段.本文综述了以SiO2、Al2O3、MgO、分子筛、高分子材料、层状化合物及钙钛矿型复合氧化物等为载体,制备负载型纳米CdS光催化剂的方法及其在光催化分解水制氢中的应用.
参考文献
| [1] | Fujishima A;Honda K .Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238(5358):37-38. |
| [2] | Serpone N;Borgarello E;Gratzel M.Visible light induced generation of hydrogen from H2S in mixed semiconductor dispersion:improved efficiency through inter-particle electron transfer[J].Journal of the Chemical Society,Chemical Communications,1984(06):342-344. |
| [3] | Borgarello E;Serpone N;Gratzel M et al.Hydrogen production through microhetero geneous photocatalysis of hydrogen sulfide cleavage:the thiosulfate cycle[J].International Journal of Hydrogen Energy,1985,10(11):737-741. |
| [4] | Rufus I B;Viswanthan B;Ramakrishnan V et al.Cadmium sulfide with iridium sulfide and platinum sulfide deposits as a photocatalyst for the decomposition of aqueous sulfide[J].Journal of Photochemistry and Photobiology A:chemistry,1995,91(01):63-66. |
| [5] | Rufus I B;Viswanthan B;Ramakrishnan V et al.Rhodium and rhodium sulfide coated cadmium sulfide as a photocatalyst for photochemical decomposition of aqueous sulfide[J].Langmuir,1990,6(03):565-567. |
| [6] | Chanjuan Xing;Yaojun Zhang;Wei Yan;Liejin Guo .Band structure-controlled solid solution of Cd_(1-x)Zn_xS photocatalyst for hydrogen production by water splitting[J].International journal of hydrogen energy,2006(14):2018-2024. |
| [7] | De G C;Roy A M;Bhattacharya S S .Effect of n-Si on the photocatalytic production of hydrogen by Pt-loaded CdS and CdS/ZnS catalyst[J].International Journal of Hydrogen Energy,1996,21(01):19-23. |
| [8] | Jang JS;Li W;Oh SH;Lee JS .Fabrication of CdS/TiO2 nano-bulk composite photocatalysts for hydrogen production from aqueous H2S solution under visible light[J].Chemical Physics Letters,2006(4-6):278-282. |
| [9] | 王学华,曹宏,吕飞,马懿超.La3+掺杂CdS/TiO2复合膜的制备及性能表征[J].化学与生物工程,2005(06):40-42. |
| [10] | 邱炜,陈爱平,刘威,刘伟.二氧化钛光催化剂的光敏化研究进展[J].现代化工,2004(z1):43-46. |
| [11] | Sobczynski A .Preparation and photocatalytic properties of silica-supported fine CdS powders[J].Monatshefte Fur Chemie,1992,123(03):211-216. |
| [12] | Kakuka N;Park K H;Finlayson M F et al.Photoassisted hydrogen production using visible light and copreclpitated ZnS-CdS without a noble metal[J].Journal of Physical Chemistry,1985,89(05):732-734. |
| [13] | 王芳,张鸟飞,金梅,菅盘铭.Al2O3负载TiO2光催化氧化剂的制备与性能试验[J].工业用水与废水,2007(04):88-90,94. |
| [14] | Manjit K. Arora;Namita Sahu;S. N. Upadhyay;A. S. K. Sinha .Activity of Cadmium Sulfide Photocatalysts for Hydrogen Production from Water: Role of Support[J].Industrial & Engineering Chemistry Research,1999(7):2659-2665. |
| [15] | Manjit K. Arora;Namita Sahu;S. N. Upadhyay;A. S. K. Sinha .Alumina-Supported Cadmium Sulfide Photocatalysts for Hydrogen Production from Water: Role of Dissolved Ammonia in the Impregnating Solution[J].Industrial & Engineering Chemistry Research,1999(12):4694-4699. |
| [16] | Manjit K. Arora;A. S. K. Sinha;S. N. Upadhyay .Effect of Dispersion and Distribution on Activity of Alumina-Supported Cadmium Sulfide Photocatalysts for Hydrogen Production from Water[J].Industrial & Engineering Chemistry Research,1998(4):1310-1316. |
| [17] | Subrahmanyam M;Supriya V T;Reddy P R .Photocatalytic H2 production with CdS-based catalysts from a sulphide/sulphite substrate:an effort to develop MgO-supported catalysts[J].International Journal of Hydrogen Energy,1996,21(02):99-106. |
| [18] | M.Sathish R.P.Viswanath .Photocatalytic generation of hydrogen over mesoporous CdS nanoparticle:Effect of particle size,noble metal and support[J].Catalysis Today,2007(3/4):421-427. |
| [19] | Kim Y I;Mallouk T E .Dynamic electron-transfer quenching of the tris(2,2'-bipyridyl) ruthenium(II) MLCT excited state by intrazeolitic methylviologen ions[J].Journal of Physical Chemistry,1992,96(07):2879-2885. |
| [20] | Corma A;Garcia H .Photoinduced electron transfer within zeolite cavities:cis-stilbene isomerization photosensitized by 2,4,6-triphenylpyrylium cation imprisoned inside zeolite[J].Journal of the American Chemical Society,1994,116(06):2276-2280. |
| [21] | 张向华,李文钊,徐恒泳,刘鸿.分子筛在光催化中的应用[J].化学进展,2004(05):728-737. |
| [22] | Ochoa-Landin R.;Flores-Acosta M.;Ramirez-Bon R.;Arizpe-Chavez H. Sotelo-Lerma M.;Castillon-Barraza FF. .Characterization of Cds clusters in zeolite-A grown in alkaline solution[J].The journal of physics and chemistry of solids,2003(11):2245-2251. |
| [23] | H.Peng;S.M.Liu;L.Ma .Growing process of CdS nanoclusters in zeolite Y studied by positron annihilation[J].Journal of Crystal Growth,2001(3/4):274-279. |
| [24] | Su Young Ryu;William Balcerski;T. K. Lee .Photocatalytic Production of Hydrogen from Water with Visible Light Using Hybrid Catalysts of CdS Attached to Microporous and Mesoporous Silicas[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(49):18195-18203. |
| [25] | Hirai Takayuki;Komasawa Isao;Okubo Hironori .Size-selective incorporation of CdS nanoparticles into mesoporous silica[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,1999(21):4228-4230. |
| [26] | Hwang Y J;Kim S J;Park S et al.Photoactivity of CdS particles grown in Pt-loaded zeolite Y[J].Bulletin of the Korean Chemical Society,2000,21(02):187-192. |
| [27] | Guan GQ.;Kida T.;Kusakabe K.;Kimura K.;Fang XM.;Ma TL.;Abe E. Yoshida A. .Photocatalytic H-2 evolution under visible light irradiation on CdS/ETS-4 composite[J].Chemical Physics Letters,2004(3-4):319-322. |
| [28] | Guoqing Guan;Tetsuya Kida;Katsuki Kusakabe;Kunio Kimura;Eiichi Abe .Photocatalytic activity of CdS nanoparticles incorporated in titanium silicate molecular sieves of ETS-4 and ETS-10[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(1):71-78. |
| [29] | Shaohua Shen;Liejin Guo .Growth of quantum-confined CdS nanoparticles inside Ti-MCM-41 as a visible light photocatalyst[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2008(2):437-446. |
| [30] | Mau A W H;Huang C B;Kakuta N et al.H2 photoproduction by Nafion/CdS/Pt films in H2O/S2-solutions[J].Journal of the American Chemical Society,1984,106(22):6537-6542. |
| [31] | K.G. Kanade;Jin-OoK Baeg;U.P. Mulik;D.P. Amalnerkar;B.B. Kale .Nano-CdS by polymer-inorganic solid-state reaction: Visible light pristine photocatalyst for hydrogen generation[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2006(12):2219-2225. |
| [32] | 桑丽霞,刘宇,李群伟,胥利先,马重芳,戴洪兴,何洪.纳米钙钛矿型复合氧化物LaFeO3光催化分解水制氢[J].中国稀土学报,2006(z2):42-45. |
| [33] | 桑丽霞,李群伟,胥利先,刘宇,马重芳.掺杂Cu2+对钙钛矿型LaFeO3光催化分解水制氢性能的影响[J].西安交通大学学报,2008(05):626-629. |
| [34] | 张莉莉,陆路德.无机层状化合物及其应用述评[J].化工新型材料,2004(03):1-4. |
| [35] | 王文峰.太阳能光解水制氢的研究进展[J].无机化学学报,2001(05):618-626. |
| [36] | Shangguan W F .Photocatalytic hydrogen evolution from water on nanocomposites incorporating cadmium sulfide into the interlayer[J].Journal of Physical Chemistry B,2002,106(47):12227-12230. |
| [37] | Shangguan WF.;Yoshida A. .Synthesis and photocatalytic properties of CdS-intercalated metal oxides[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(2):189-194. |
| [38] | Kida T.;Guan GQ.;Yoshida A. .LaMnO3/CdS nanocomposite: a new photocatalyst for hydrogen production from water under visible light irradiation[J].Chemical Physics Letters,2003(5-6):563-567. |
| [39] | B. C. Gates .Supported Metal Clusters: Synthesis, Structure, and Catalysis[J].Chemical Reviews,1995(3):511-522. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%