室温条件下，通过配位调控方法合成了MOF家族中非常重要的成员Cu3（BTC）2（也称为HKUST-1，BTC为均苯三甲酸根）。通过调变反应体系的浓度，成功地获得了50～200nm的Cu2（BTC）2晶体。粉末XRD、TGA测试结果显示产物具有高的结晶度及良好的热稳定性，N2吸附测试结果表明产物具有高的比表面积及孔容积。这种具有高的气体吸附能力的小尺寸粒子在实际过程中将有重要的应用前景。
Cu3 (BTC)2 ( HKUST-1, BTC = 1,3,5-benzenetricarboxylate), one of the most well-known coordination polymers, has been synthesized at room temperature using coordination modulation method. By adjusting the concentrations of the reactants, Cu3 (BTC)2 crystals in the size range of 50-200nm were successfully obtained. The products were characterized by powder XRD,TGA and N2 sorption. The results show highly crystalline particles with good thermal stabilities. N2 sorption measurements reveal with large BET surface areas and total pore volumes. The significantly smaller particle sizes and high capacity of gas sorption are considered advantageous for envisaged applications in practical industrial process.
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