综述了几种测定铜催化剂有效表面积的方法. N2O前沿反应色谱法(RFC)对设备要求简单,操作简便,测定结果重现性好,是测定铜催化剂中铜的表面积的有效方法. 给出了装置原理图和适当的实验条件.
参考文献
[1] | Dienes E K;Coleman R L;Hausberger A L .[P].US 4 279 781,1981. |
[2] | STILES A B .[P].US 4 111 847,1978. |
[3] | Velenyi L J;Krupa A S .[P].US 4 334 116,1982. |
[4] | Wall R G .[P].US 4 149 021,1979. |
[5] | Tsukada K;Hattori Y;Mimura T;Tabata O,Nishigaki F .[P].US 5 658 843,1997. |
[6] | Emmett P H;Skau N .[J].Journal of the American Chemical Society,1943,65(06):1029. |
[7] | Scholten J J F;Konvalinka J A .[J].Transactions of the Faraday Society,1969,65(09):2465. |
[8] | Dell R M;Stone F S;Tiley P F .[J].Transactions of the Faraday Society,1953,49(02):195. |
[9] | 张聚华 .[J].天然气化工,1998,23(04):15. |
[10] | Muhler M;Nielsen L P;Tornqvist E;Clausen B S,Topsoe H .[J].Catalysis Letters,1992,14(3-4):241. |
[11] | Ying D H S;Madix R J .[J].Journal of Catalysis,1980,61(01):48. |
[12] | Hinrichsen O;Genger T;Muhler M .[J].Chemical Engineering and Technology,2000,23(11):956. |
[13] | Genger T.;Hinrichsen,O. .The temperature-programmed desorption of hydrogen from copper surfaces[J].Catalysis Letters,1999(2/4):137-141. |
[14] | Russell W W;Ghering L G .[J].Journal of the American Chemical Society,1935,57(12):2544. |
[15] | Rhodin T N .[J].Journal of the American Chemical Society,1950,72(11):5102. |
[16] | Allen J A;Mitchell J W.[M].Discussions of the Faraday Society,1950:309. |
[17] | Giamello E;Fubini B;Lauro P;Bossi A .[J].Journal of Catalysis,1984,87(02):443. |
[18] | Osinga Th J;Linsen B G;van Beek W P .[J].Journal of Catalysis,1967,7(03):277. |
[19] | Dvoák B;Paek J .[J].Journal of Catalysis,1970,18(01):108. |
[20] | Chinchen G C;Hay C M;Vandervell H D;Waugh K C .[J].Journal of Catalysis,1987,103(01):79. |
[21] | Sundquist B E .[J].Acta Materialia,1964,12(01):67. |
[22] | Evans J W;Wainwright M S;Bridgewater A J;Young D J .[J].Applied Catalysis,1983,7(01):75. |
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