热塑性树脂改性热固性树脂,可以在不降低热固性树脂耐热温度的同时,大幅度提高改性材料的韧性.热塑性树脂改性热固性树脂体系初始是均相的,随着固化反应的进行,体系中两相的相容性下降,发生反应诱导相分离.介绍了固化反应诱导相分离的基本理论和研究进展,重点是近年来热塑性树脂改性热固性树脂体系固化反应诱导相分离的研究.
参考文献
| [1] | Zheng SX.;Guo QP.;Wei J.;Li JA.;Wang JA. .MISCIBILITY, MORPHOLOGY AND FRACTURE TOUGHNESS OF EPOXY RESIN POLY(STYRENE-CO-ACRYLONITRILE) BLENDS[J].Polymer: The International Journal for the Science and Technology of Polymers,1996(21):4667-4673. |
| [2] | Keizo Yamanaka;Takashi Inoue .Phase-separation mechanism of rubber-modified epoxy[J].Journal of Materials Science,1990,25:241. |
| [3] | Flory P J.Principles of polymer chemistry[M].New York:University Press,1953 |
| [4] | 江明.高分子合金的物理化学[M].成都:四川教育出版社,1988 |
| [5] | Inoue T .Reaction-induced phase-decomposition in polymer blends[J].Progress in Polymer Science,1995,20(01):119. |
| [6] | Cahn J W .Phase separation by spinodal decomposition in isotropic systems[J].Journal of Chemical Physics,1965,42(01):93. |
| [7] | Binder K;Stauffer D .Theory for the slowing down of the relaxation and spinodal decomposition of binary mixtures[J].Physical Review Letters,1974,33:1006. |
| [8] | Keizo Yamanaka;Yasushi Takagi;Inoue et al.Reactioninduced phase separation in rubber-modified epoxy resins[J].Polymer,1989,30(10):1839. |
| [9] | Rong Minzhi;Zeng Hanmin .Polycarbonate-epoxy semi-interpenetrating polymer network:2.Phase separation and morphology[J].Polymer,1997,38(02):269. |
| [10] | Kim SC.;Jo WH.;Ko MB. .THE EFFECT OF THE VISCOSITY OF EPOXY PREPOLYMER ON THE GENERATED MORPHOLOGY IN RUBBER-TOUGHENED EPOXY RESIN[J].Polymer: The International Journal for the Science and Technology of Polymers,1995(11):2189-2195. |
| [11] | Cheng Chung Chen;James L White .Compatibilizing agents in polymer blends:Interfacial tension,phase morphology,and mechanical properties[J].Polymer Engineering & Science,1993,33(14):923. |
| [12] | Hansj(o)rg Gramespacher;Joachim Meissner .Melt elongation and recovery of polymer blends,morphology,and influence of interfacial tension[J].Journal of Rheology,1997,41(01):27. |
| [13] | Xie XM.;Zhang ZM.;Tanioka A.;Xiao TJ. .Effect of interfacial tension on the formation of the gradient morphology in polymer blends[J].Journal of Colloid and Interface Science,1998(1):189-194. |
| [14] | Liang H.;Yu Y.S.;Eisenberg A.;Favis B.D. .Correlation between the interfacial tension and dispersed phase morphology in interfacially modified blends of LLDPE and PVC[J].Macromolecules,1999(5):1637-1642. |
| [15] | Li Zhaohui;Xiaomin Zhang;Shigeru Tasaka .The interfacial tension and morphology of reactive polymer blends[J].Materials Letters,2001(2):81-88. |
| [16] | Ruseckaite R A;Hu L J;Riccardi C C et al.Castor-oilmodified epoxy-resins as model systems of rubber-modified thermosets,2.Influence of cure conditions on morphologies generated[J].Polymer International,1993,30:287. |
| [17] | Girardreydet E.;Pascault JP.;Sautereau H.;Vicard V. .POLYETHERIMIDE-MODIFIED EPOXY NETWORKS - INFLUENCE OF CURE CONDITIONS ON MORPHOLOGY AND MECHANICAL PROPERTIES[J].Journal of Applied Polymer Science,1997(12):2433-2445. |
| [18] | Martinez I.;Martin M.D. .Phase separation in polysulfone-modified epoxy mixtures. Relationships between curing conditions, morphology and ultimate behavior[J].Polymer: The International Journal for the Science and Technology of Polymers,2000(3):1027-1035. |
| [19] | Kim BS.;Inoue T.;Chiba T. .MORPHOLOGY DEVELOPMENT VIA REACTION-INDUCED PHASE SEPARATION IN EPOXY POLY(ETHER SULFONE) BLENDS - MORPHOLOGY CONTROL USING POLY(ETHER SULFONE) WITH FUNCTIONAL END-GROUPS[J].Polymer: The International Journal for the Science and Technology of Polymers,1995(1):43-47. |
| [20] | Chen D;Pascault J P;Sautereau H et al.Rubber-modified epoxies,2.A reaction-induced phase-separation observed in-situ and a posteriori with different methods[J].Polymer International,1993,32:369. |
| [21] | Furukawa H .Pattern formations in unstable network model for cross-linked polymer chains[J].Journal of The Physical Society of Japan,1994,63:3919. |
| [22] | Thein Kyu;Jae-Hyung Lee .Nucleation initiated spinodal decomposition in a polymerizing system[J].Physical Review Letters,1996,76:3746. |
| [23] | Bong Sup Kim;Tsuneo Chiba;Takashi Inoue .Phase separation and apparent phase dissolution during cure process of thermoset/thermoplastic blend[J].Polymer,1995,36:67. |
| [24] | Verchere D;Sautereau H;Pascault J P et al.Rubbermodified epoxies.Ⅰ.Influence of carboxyl-terminated butadiene-acrylonitrile random copolymers (CTBN)on the polymerization and phase separation processes[J].Journal of Applied Polymer Science,1990,41(3-4):467. |
| [25] | Verchere D;Pascault J P;Sautereau H et al.Rubbermodified epoxies.Ⅱ.Influence of the cure schedule and rubber concentration on the generated morphology[J].Journal of Applied Polymer Science,1991,42(03):701. |
| [26] | Verchere D;Pascault J P;Sautereau H et al.Rubbermodified epoxies.Ⅳ.Influence of morphology on mechanical properties[J].Journal of Applied Polymer Science,1991,43(02):293. |
| [27] | Oyanguren PA.;Williams RJJ.;Girardreydet E.;Pascault JP.;Frontini PM. .REACTION-INDUCED PHASE SEPARATION IN POLY(BUTYLENE TEREPHTHALATE)-EPOXY SYSTEMS .1. CONVERSION-TEMPERATURE TRANSFORMATION DIAGRAMS[J].Polymer: The International Journal for the Science and Technology of Polymers,1996(14):3079-3085. |
| [28] | Oyanguren PA.;Williams RJJ.;Vigier G.;Pascault JP.;Frontini PM. .REACTION-INDUCED PHASE SEPARATION IN POLY(BUTYLENE TEREPHTHALATE)-EPOXY SYSTEMS .2. MORPHOLOGIES GENERATED AND RESULTING PROPERTIES[J].Polymer: The International Journal for the Science and Technology of Polymers,1996(14):3087-3092. |
| [29] | Girard-Reydet E;Sautereau H;Pascault J P .Use of block copolymers to control the morphologies and properties of thermoplastic/thermoset blends[J].Polymer,1999,40:1677. |
| [30] | Bonnet A.;Pascault J.P. .Epoxy-Diamine Thermoset/Thermoplastic Blends. 1. Rtes of Reactions before and after Phase Separation[J].Macromolecules,1999(25):8517-8523. |
| [31] | Bonnet A.;Pascault J.P. .Epoxy-Diamine Thermoset/Thermoplastic Blends. 2. Rheological Behavior before and after Phase Separation[J].Macromolecules,1999(25):8524-8530. |
| [32] | Cui Jun;Yu Y F;Chen W J et al.Studies on the phase separation of polyetherimide-modified epoxy resin,2.Effect of molecular weight of PEI on the structure formation[J].Macromolecular Chem Phys,1997,198:3267. |
| [33] | Peng Lingqing;Cui Jun;Li Shanjun .Studies on the phase separation of a polyetherimide-modified epoxy resin,4.Kinetic effect on the phase separation mechanism of a blend at different cure rates[J].Macromolecular Chem Phys,2000,201(06):699. |
| [34] | Jin Jianyong;Cui Jun;Tang Xiaolin et al.On polyetherimide modified bismaleimide resins,1.Effect of the chemical backbone of polyetherimide[J].Macromolecular Chem Phys,1999,200:1956. |
| [35] | Li H;Gan W J;Zhao L et al.Studies on the phase separation of a polyetherimide modified epoxy resin.Ⅵ.Effect of surface energy on reaction-induced phase separation of epoxy resin modified with polyetherimide[J].J Macromolecular SciPure and Appl Chem,2003,A40:833. |
| [36] | Zhang Zhicheng;Cui Jun;Li Shanjun et al.Effect of hydroxyl-terminated polyethersulfone on the phase separation of polyetherimide-modified epoxy resin[J].Macromolecular Chem Phys,2001,202:126. |
| [37] | Hohenherg P C;Halperin B I .Theory of dynamic critical phenomena[J].Reviews of Modern Physics,1977,49:435. |
| [38] | Furukawa .A dynamic scaling assumption for phase separation[J].Advances in Physics,1985,34(48):703. |
| [39] | Doi M;Onuki A .Dynamic coupling between stress and composition in polymer solutions and blends[J].J De Physique Ⅱ,1992,2:1631. |
| [40] | Takashi Taniguchi;Akira Onuki .Network domain structure in viscoelastic phase separation[J].Physical Review Letters,1996,77:4910. |
| [41] | Hajime Tanaka .Appearance of a moving droplet phase and unusual networklike or spongelike patterns in a phase-separating polymer solution with a double-well-shaped phase diagram[J].Macromolecules,1992,25(23):6377. |
| [42] | Hajime Tanaka .Unusual phase separation in a polymer solution caused by asymmetric molecular dynamics[J].Physical Review Letters,1993,71:3158. |
| [43] | Hajime Tanaka;Takeaki Araki .Phase inversion during viscoelastic phase separation:Roles of bulk and shear relaxation moduli[J].Physical Review Letters,1997,78:4966. |
| [44] | Hajime Tanaka .Viscoelastic model of phase separation[J].Physical Review E,1997,56:4451. |
| [45] | Celeste Sagui;Luc Piché;Abdelhadi Sahnoune et al.Elastic effects in the foaming of thermoplastics[J].Physical Review E,1998,58:4654. |
| [46] | Gan WJ.;Yu YF.;Wang MH.;Tao QS.;Li SJ. .Viscoelastic effects on the phase separation in thermoplastics-modified epoxy resin[J].Macromolecules,2003(20):7746-7751. |
| [47] | Yu Y F;Wang M H;Gan W J et al.Polymerization-induced viscoelastic phase separation in polyethersulfone-modified epoxy systems[J].Journal of Physical Chemistry B,2004,108:6208. |
| [48] | Tao Qingsheng;Gan Wenjun;Yu Yingfeng et al.Viscoelastic effects on the phase separation in thermoplastics modified cyanate ester resin[J].Polymer,2004,45:3505. |
| [49] | Liu X;Yu YF;Li SJ .Viscoelastic phase separation in polyethersulfone modified bismaleimide resin[J].European Polymer Journal,2006(4):835-842. |
| [50] | Oyanguren P A;Galante M J;Andromaque K et al.Development of bicontinuous morphologies in polysulfone-epoxy blends[J].Polymer,1999,40:5249. |
| [51] | Galante M J;Borrajo J;Williams R J J et al.Double phase separation induced by polymerization in ternary blends of epoxies with polystyrene and poly(methyl methacrylate)[J].Macromolecules,2001,34:2686. |
| [52] | Huo Y L;Jiang X L;Zhang H D et al.Hydrodynamic effects on phase separation of binary mixtures with reversible chemical reaction[J].Journal of Chemical Physics,2003,118:9830. |
| [53] | Tang XL;Zhang LX;Wang T;Yu YF;Gan WJ;Li SJ .Hydrodynamic effect on secondary phase separation in an epoxy resin modified with polyethersulfone[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2004(15):1419-1424. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%