欢迎登录材料期刊网

材料期刊网

高级检索

染料敏化太阳电池(DSC电池)近年来已经引起国内外众多学者的重视,越来越多的研究者对此表现出极大的兴趣。染料敏化剂是染料敏化太阳电池的光电转化效率(IPCE)和寿命最关键的因素。简要介绍了DSC电池结构及工作原理,主要是针对近年来很有前景的香豆素类、半菁类、多烯类、吲哚类及其他很有发展潜力的有机染料敏化剂研究所取得的进展进行了综述。为新染料的设计与合成,为提高电池的光电转化效率和稳定性提出了值得进一步深入研究的问题。

The dye-sensitized solar cell (DSC) is a device of converting the solar energy into the electric power with the nanoparticle semiconductor, which has low-cost and high-efficiency advantages. The sensitizers constitutes the heart of the incident photo to current conversion efficiency (IPCE) and life of the DSC. The fundamental structure and operation principle of the DSC are presented in this paper. The study on the conditions and the progress of the organic dye-sensitizer including some prospective dyes such as comnain dyes, hemicyanine dyes, polyene dyes, indoline dyes, and so on for DCS are reviewed. Here some future development of the study are put out for new dyes synthesis and . the improvement of the IPCE.

参考文献

[1] O' Regan B;Gratzel M .A Low-Cost,High-Efficiency Solar Cell Based on Dye-Sensitized Colloidal TiO2[J].Nature,1991,353:737-739.
[2] Nazeeruddin M K;Kay A;Rodicio I et al.Conversion of Light to Electricity by Cis-X2 Bis( 2,2 '-Bipyridy1-4,4 '-Dicarboxylate )Ruthenium(II)Charge-Transfer Sensitizers( X = C1- ,Br- ,I- ,CN- and SCN- )on Nanocrystailine TiO2 Electrodes[J].Journal of the American Chemical Society,1993,115:6382-6390.
[3] Nazeeruddin M K;Angelis F D;Fantacci S et al.Combined Experimental and DFT-TDDFT Computational Study of Photoelec- troehemical Cell Ruthenium Sensitizers[J].Journal of the American Chemical Society,2005,127:16835-16847.
[4] Graitzel M .Recent Advances in Sensitized Mesoscopic Solar Ceils[J].AccountsChemRe,2009,42:1788-1798.
[5] Olea Alfredo;Sebastian P.J.;Ponce Georgina .Electron transfer via organic dyes for solar conversion[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1999(1):137-143.
[6] Balzani V.;Denti G.;Juris A.;Serroni S.;Venturi M.;Campagna S. .HARVESTING SUNLIGHT BY ARTIFICIAL SUPRAMOLECULAR ANTENNAE[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1995(1/4):159-173.
[7] Bignozzi CA.;Schoonover JR.;Meyer GJ.;Scandola F.;Argazzi R. .PHOTOSENSITIZATION OF WIDE BANDGAP SEMICONDUCTORS WITH ANTENNA MOLECULES[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1995(1/4):187-198.
[8] JING Bingwen;ZHANG Manhua;SHEN Tao .Advances in dye-sensitized solar cell[J].Chinese science bulletin,1997(23):1937-1947.
[9] Hara K;Sayama K;Suga S.A Coumarin-Derivative Dye Sensitized Nanocrystalline TiO2 Solar Cell Having a High Solar- Energy Conversion Efficiency up to 5.6%[J].Chemical Communications,2001(06):569-570.
[10] Kohjiro Hara;Tadatake Sato;Ryuzi Katoh;Akihiro Furube;Yasuyo Ohga;Akira Shinpo;Sadaharu Suga;Kazuhiro Sayama;Hideki Sugihara;Hironori Arakawa .Molecular Design of Coumarin Dyes for Efficient Dye-Sensitized Solar Cells[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2003(2):597-606.
[11] Kohjiro Hara;Mitsuhiko Kurashige;Kazuhiro Sayama;Hironori Arakawa;Yasufumi Dan-oh;Chiaki Kasada;Akira Shinpo;Sadaharu Suga .Design of new coumarin dyes having thiophene moieties for highly efficient organic-dye-sensitized solar cells[J].New Journal of Chemistry,2003(5):783-785.
[12] Wang Z S;Hara K;Dan-oh Y et al.Photophysical and (Photo) Electrochemical Properties of a Coumarin Dye[J].Journal of Physical Chemistry B,2005,109(09):3907-3904.
[13] Z.-S. Wang;Y. Cui;K. Hara;Y. Dan-oh;C. Kasada;A. Shinpo .A High-Light-Harvesting-Efficiency Coumarin Dye for Stable Dye-Sensitized Solar Cells[J].Advanced Materials,2007(8):1138-1141.
[14] Hara K.;Tachibana Y.;Ohga Y.;Shinpo A.;Suga S.;Sayama K.;Sugihara H. Arakawa H. .Dye-sensitized nanocrystalline TiO2 solar cells based on novel coumarin dyes[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(1):89-103.
[15] 张莉,杨迈之,高恩勤,乔学斌,郝彦忠,王艳琴,蔡生民,孟凡顺,田禾.五甲川菁染料的敏化作用及其在Gratzel型太阳能电池中的应用[J].高等学校化学学报,2000(10):1543-1546.
[16] Frank G. Gao;Allen J. Bard;Lowell D. Kispert .Photocurrent generated on a carotenoid-sensitized TiO_2 nanocrystalline mesoporous electrode[J].Journal of Photochemistry and Photobiology, A. Chemistry,2000(1):49-56.
[17] Sayama K;Hara K;Ohga Y et al.Significant Effects of the Distance between the Cyanine Dye Skeleton and Semiconductor Surface on Photoelectrochemical Properties of Dye-Sensitized Porous Semiconductor Electrodes[J].New Journal of Chemistry,2001,25:200-202.
[18] Wang Z S;Li F Y;Huang C H et al.Photoelectric Conver- sion Properties of Nanocrystalline TiO2 Electrodes Sensitized with Hemicyanine Derivatives[J].Journal of Physical Chemistry B,2000,104:9676-9682.
[19] Wang Z S;Li F Y;Huang C H .Highly Efficient Sensitization of Nanocrystalline TiO2 Fihns with Styryl Benzothiazolium Propyl- sulfonate[J].Chemical Communications,2000,20:2063-2064.
[20] Wang Z S;Li F Y;Huang C H .Photocurrent Enhancement of Hemicyanine Dyes Containing RSO3 - Group through Treating TiO2 Filmswith Hydrochloric Acid[J].Journal of Physical Chemistry B,2001,105:9210-9217.
[21] Yao QH.;Shan L.;Li FY.;Yin DD.;Huang CH. .An expanded conjugation photosensitizer with two different adsorbing groups for solar cells[J].New Journal of Chemistry,2003(8):1277-1283.
[22] Yao QH.;Meng FS.;Li FY.;Tian H.;Huang CH. .Photoelectric conversion properties of four novel carboxylated hemicyanine dyes on TiO2 electrode[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(5):1048-1053.
[23] 姚巧红,单璐,李富友,尹东东,黄春辉.TiO2纳米晶电极上半菁衍生物分子设计中空间位阻效应的研究[J].化学学报,2003(05):647-652.
[24] Chen YS;Li C;Zeng ZH;Wang WB;Wang XS;Zhang BW .Efficient electron injection due to a special adsorbing group's combination of carboxyl and hydroxyl: dye-sensitized solar cells based on new hemicyanine dyes[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(16):1654-1661.
[25] Tennakone K;Kumara G;Kottegoda I R M et al.Sensitiza- tion of Nano-Porous Films of TiO2 with Santalin( Red Sandalwood Pigment)and Construction of Dye-Sensitized Solid-State Photo- voltaic Cells[J].Journal of Photochemistry and Photobiology A: Chemistry,1998,117:137-142.
[26] Kay A;Gratzel M .Photosensitization of Titania Solar Cells with Chlorophyll Derivatives and Related Natural Porphyrins[J].Journal of Physical Chemistry,1993,97:6272-6277.
[27] Hara K;Kurashige M;Ito S.Solar Energy Novel Polyene Dyes for Highly Efficient Dye-Sensitized Solar Cells[J].Chemical Communications,2003(02):252-253.
[28] Hara K.;Tachibana Y.;Ohga Y.;Shinpo A.;Suga S.;Sayama K.;Sugihara H. Arakawa H. .Dye-sensitized nanocrystalline TiO2 solar cells based on novel coumarin dyes[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(1):89-103.
[29] Cherian S;Wamser C C .Adsorption and Photoactivity of Tetra( 4 - Carboxyphenyl )Porphyrin( TCPP )on Nanoparticulate TiO2[J].Journal of Physical Chemistry B,2000,104:3624-3629.
[30] Fungo F.;Sereno L.;Silber JJ.;Durantini EN.;Otero LA. .Synthesis of porphyrin dyads with potential use in solar energy conversion[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2000(3):645-650.
[31] Ito S;Zakeemddin S M;Humphry-Baker R .High-Efficiency Organic-Dye-Sensitized Solar Cells Controlled by Canocrystalline- TiO2 Electrode Thickness[J].Advanced Materials,2006,!8:12021205.
[32] Pastore, M.;De Angelis, F. .Aggregation of organic dyes on TiO_2 in dye-sensitized solar cells models: An Ab initio investigation[J].ACS nano,2010(1):556-562.
[33] Mariachiara Pastore;Edoardo Mosconi;Filippo De Angelis .A Computational Investigation of Organic Dyes for Dye-Sensitized Solar Cells: Benchmark, Strategies, and Open Issues[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(15):7205-7212.
[34] Pastore M;Fantacci S;De Angelis et al.Ground and Excited State Oxidation Potentials mophores for Dye-Sensitized Solar Cells[J].Determination of" of Organic Chro- J Phys Chem C,2010,114:22742-22750.
[35] Hagberg DP;Edvinsson T;Marinado T;Boschloo G;Hagfeldt A;Sun LC .A novel organic chromophore for dye-sensitized nanostructured solar cells[J].Chemical communications,2006(21):2245-2247.
[36] Hwang S;Lee JH;Park C;Lee H;Kim C;Park C;Lee MH;Lee W;Park J;Kim K .A highly efficient organic sensitizer for dye-sensitized solar cells[J].Chemical communications,2007(46):4887-4889.
[37] Hagberg, DP;Yum, JH;Lee, H;De Angelis, F;Marinado, T;Karlsson, KM;Humphry-Baker, R;Sun, LC;Hagfeldt, A;Gratzel, M .Molecular engineering of organic sensitizers for dye-sensitized solar cell applications[J].Journal of the American Chemical Society,2008(19):6259-6266.
[38] Tian H;Yang X;Sun L et al.Phen0thiazine Derivatives for Efficient Organic Dye Sensitized Solar Cells[J].Chemical Communications,2007,36:3741-3743.
[39] Bai Y;Cao Y M;Zhang J et al.High Performance Dye Sensi-tized Solar Cells Based on Solvent Free Electrolytes Produced from Eutectic Melts[J].Nature Materials,2008,7(08):626-630.
[40] Dong Shi;Nuttapol Pootrakulchote;Renzhi Li .New Efficiency Records for Stable Dye-Sensitized Solar Cells with Low-Volatility and Ionic Liquid Electrolytes[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(44):17046-17050.
[41] Qin H;Wenger S;Xu M;Gao F;Jing X;Wang P;Zakeeruddin SM;Gratzel M .An organic sensitizer with a fused dithienothiophene unit for efficient and stable dye-sensitized solar cells[J].Journal of the American Chemical Society,2008(29):9202-9203.
[42] Yiming Cao;Yu Bai;Qingjiang Yu .Dye-Sensitized Solar Cells with a High Absorptivity Ruthenium Sensitizer Featuring a 2-(Hexylthio)thiophene Conjugated Bipyridine[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(15):6290-6297.
[43] Zhang G;Bala H;Cheng Y et al.High Efficiency and Stable Dye-Sensitized Solar Cells with an Organic Chromophore Featu- ring a Binary -Conjugated Spacer[J].Chemical Communications,2009,16:2198-2200.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%