通过电子显微分析,发现在热等静压的TiAl-V-Si合金中有大量的硅化物沿层状结构的相界面析出,这些硅化物为Ti_5Si_3相,通常为近六角形的薄片.Ti_5Si_3相与层状结构基体相(α_2和γ相)间具有如下的固定取向关系[0001]_(Ti_5Si_3)//[0001]_(Ti_3Al),(3120)_(Ti_5Si_3),//(1010)_(Ti_3Al)[0001]_(Ti_5Si_3)//[111]_(TiAl),(4150)_(Ti_5Si_3)//(110)_(TiAl)
Alloying element Si can improve the high-temperature creep resistance of the Ti-rich TiAl intermetallic compound. Numerous Ti_(5)Si_3 phase, precipitated as hexagonal foils along the γ-γ and γ-α_2 interfaces in the lamellar structure, was observed by TEM on the hot isostatic pressing TiAl-V-Si alloy compact. The orientation relationships between this precipitating phase and the TiAl and Ti_(3)Al phase are as follows:[0001]_(Ti_(5)Si_3)Correspondenl: HE Lianlong,research assistant , Institute of Metal Research, Chinese Academy of Sciences,Shenyang 110015
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[6] | LipsittHA,ShechtmanD,SchafrikRE.MetallTrans,1975 |
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