简单介绍辉光放电发射光谱技术的基础知识及相关书籍情况,重点评述其在国内钢铁行业的应用.国内钢铁行业基体分析涉及中低合金钢、不锈钢、生铁、铸铁、高温合金等;阳极直径4 mm为主,分析元素已达24种,激发功率12～90 W,数据精密度多小于5％;而深度轮廓分析主要涉及镀锌板、镀锡板、彩涂板,氟元素测定和制备电镜样品是其应用的一大亮点.概述辉光放电发射光谱国际标准和国家标准的进展,并对辉光放电发射光谱法、X射线荧光光谱法、电感耦合等离子体原子发射光谱法、火花源原子发射光谱法在低合金钢中多元素测定的重复性和再现性进行比较,数据表明辉光放电原子发射光谱法的重复性值较低,而再现性值偏高.最后对制约辉光放电光谱技术发展的因素进行了探讨.
参考文献
| [1] | 王海舟.冶金分析前沿书[M].北京:科学出版社,2004:121-131. |
| [2] | 郑国经;计子华;余兴.原子发射光谱分析技术及应用[M].北京:化学工业出版社,2009:338. |
| [3] | 宋卫良.冶金仪器分析[M].北京:冶金工业出版社,2008:113. |
| [4] | Michael R.Winchester;Richard Payling .Radio-frequency glow discharge spectrometry:A critical review[J].Spectrochimica Acta, Part B. Atomic Spectroscopy,2004(5):607-666. |
| [5] | Dempster Melissa A.D .Optimization of hollow cathode diameter for particle beam/hollow cathode glow discharge atomic emission spectrometry[J].Spectrochimica Acta, Part B. Atomic Spectroscopy,2000(6):599-910. |
| [6] | Yang C;Ingeneri K;Mohill M et al.Influence of discharge parameters on the resolution of depth profiling by pulsed glow discharge atomic emission spectrometry[J].Journal of Analytical Atomic Spectrometry,2000,15(01):73-78. |
| [7] | Yan XM.;Hang W.;Harrison WW.;Ingeneri K. .Factors influencing signal profiles in microsecond pulsed glow discharge atomic emission spectrometry[J].Journal of Analytical Atomic Spectrometry,2001(8):819-824. |
| [8] | Bengtson A;Eklund A;Lundholm M et al.Further improvements in calibration techniques for depth profiling with glow discharge optical emission spectrometry[J].Journal of Analytical Atomic Spectrometry,1990,5(06):563-567. |
| [9] | Parker M;Hartenstein ML;Marcus RK .INFLUENCE OF DISCHARGE PARAMETERS ON THE RESULTANT SPUTTERED CRATER SHAPES FOR A RADIO FREQUENCY GLOW DISCHARGE ATOMIC EMISSION SOURCE[J].Analytical chemistry,1996(23):4213-4220. |
| [10] | Prassler F.;Schumann J.;Wetzig K.;Hoffmann V. .COMPARISON OF DEPTH RESOLUTION FOR DIRECT CURRENT AND RADIOFREQUENCY MODES IN GLOW DISCHARGE OPTICAL EMISSION SPECTROMETRY[J].Journal of Analytical Atomic Spectrometry,1995(9):677-680. |
| [11] | Cho W B;Woo Y A;Kim H J et al.Comparison between direct-current and radio-frequency gas-jet-boosted glow discharge atomic emission spectrometry for the analysis of steel[J].Applied Spectroscopy,1997,51(07):1060-1066. |
| [12] | Hartenstein M L;Christopher S J;áKenneth Marcus R .Evaluation of helium-argon mixed gas plasmas for bulk and depth-resolved analysis by radiofrequency glow discharge atomic emission spectroscopy[J].Journal of Analytical Atomic Spectrometry,1999,14(07):1039-1045. |
| [13] | Payling R.;Michler J.;Aeberhard M. .Quantitative analysis of conductive coatings by radiofrequency-powered glow discharge optical emission spectrometry: hydrogen, d.c. bias voltage and density corrections[J].Surface and Interface Analysis: SIA: An International Journal Devoted to the Development and Application of Techniques for the Analysis of Surfaces, Interfaces and Thin Films,2002(6):472-477. |
| [14] | G Cicala;E De Tommaso;A C Rainò;Yu A Lebedev;V A Shakhatov .Study of positive column of glow discharge in nitrogen by optical emission spectroscopy and numerical simulation[J].Plasma Sources Science & Technology,2009(2):025032-15. |
| [15] | Galindo RE;Fornies E;Albella JM .Interfacial effects during the analysis of multilayer metal coatings by radio-frequency glow discharge optical emission spectroscopy - Part 1. Crater shape and sputtering rate effects[J].Journal of Analytical Atomic Spectrometry,2005(10):1108-1115. |
| [16] | Kim Hyo J. .Development of open-air type electrolyte-as-cathode glow discharge-atomic emission spectrometry for determination of trace metals in water[J].Spectrochimica Acta, Part B. Atomic Spectroscopy,2000(7):823-831. |
| [17] | Cserfalvi T;Mezei P .Direct solution analysis by glow discharge:electrolyte-cathode discharge spectrometry[J].Journal of Analytical Atomic Spectrometry,1994,9(03):345-349. |
| [18] | Rodriguez J.;Sanz-Medel A.;Pereiro R. .Glow discharge atomic emission spectrometry for the determination of chlorides and total organochlorine in water samples via on-line continuous generation of chlorine[J].Journal of Analytical Atomic Spectrometry,1998(9):911-915. |
| [19] | Weihong Huang;Bin Hu;Hongchun Xiong;Zucheng Jiang .Separation and preconcentration combined with glow discharge atomic emission spectrometry for the determination of rare earth elements (La,Nd,Eu,Dy,Y)in geological samples[J].Fresenius' Journal of Analytical Chemistry,2000(3):254-258. |
| [20] | Baude S.;Delfosse D.;Jakubowski N.;Fuechtjohann L. Orellana-Velado NG.;Pereiro R.;Sanz-Medel A.;Broekaert JAC. .Glow discharge atomic spectrometry for the analysis of environmental samples - a review [Review][J].Journal of Analytical Atomic Spectrometry,2000(11):1516-1525. |
| [21] | Matsumoto K;Ishiwatari T;Fuwa K .Hydride gen eration and atomic emission spectrometry with helium glow discharge detection for analysis of biological samples[J].Analytical Chemistry,1984,56(08):1545-1548. |
| [22] | Kennethá Marcus R .Analysis of amino acids and or ganometallic compounds by particle beam-hollow cathode glow discharge atomic emission spectrometry[J].Journal of Analytical Atomic Spectrometry,2000,15(01):43-48. |
| [23] | Beatriz Fernandez;Nerea Bordel;Rosario Pereiro;Alfredo Sanz-Medel .Radio Frequency Glow Discharge-Optical Emission Spectrometry For Direct Quantitative Analysis of Glass[J].Analytical Chemistry,2004(4):1039-1044. |
| [24] | Xiaohan Pan;R. Kenneth Marcus .Direct Analysis of Glass Powder Samples by Radio Frequency Glow Discharge Atomic Emission Spectrometry (rf-GD-AES)[J].Mikrochimica Acta: An International Journal for Physical and Chemical Methods of Analysis,1998(3/4):239-250. |
| [25] | Yoshiyasu Saito;Md. Khalilur Rahman .Investigation of positive electrodes after cycle testing of high-power Li-ion battery cells IV An approach to the power fading mechanism by depth profile analysis of electrodes using glow discharge optical emission spectroscopy[J].Journal of Power Sources,2007(2):877-882. |
| [26] | Wandee Luesaiwong;R.Kenneth Marcus .Depth-resolved analysis of Ni-P plated aluminium hard disks by radiofrequency glow discharge optical emission spectroscopy(rf-GD-OES)[J].Journal of Analytical Atomic Spectrometry,2004(3):345-353. |
| [27] | Takagi Y;Suzuki K .Quantitative surface analysis of Al-Mg-(Si) alloys by glow discharge optical emission spectroscopy[J].Applied Surface Science,1999,141(01):177-185. |
| [28] | Senofonte O.;Caroli S. .Determination of gold in precious alloys by glow discharge atomic emission spectrometry[J].Journal of Analytical Atomic Spectrometry,2000(7):869-872. |
| [29] | Harville TR;Marcus RK .ANALYSIS OF PRECIOUS METAL ALLOYS BY RADIO FREQUENCY GLOW DISCHARGE ATOMIC EMISSION SPECTROMETRY[J].Analytical chemistry,1995(7):1271-1277. |
| [30] | Wagatsuma K;Hirokawa K .Analysis of binary alloy surfaces by low wattage glow discharge emission spectrometry[J].Analytical Chemistry,1984,56(03):412-416. |
| [31] | Molchan I S;Marimuthu S;Mhich A et al.Effect of surface morphology changes of Ti-6Al-4V alloy modi fied by laser treatment on GDOES elemental depth profiles[J].Journal of Analytical Atomic Spectrometry,2013,28(01):150-155. |
| [32] | S.G. Gopalakrishnan;P. Huczkowski;J. Pernpeintner .Composition modifications and heat treatment procedures for increasing the emissivity of alumina surface scales on FeCrAI alloys[J].Materials at High Temperatures,2012(3):249-256. |
| [33] | Das Bakshi S;Dutta M;Bandyopadhyay N;Rajesh N .Improvement in galvannealed coating of IF-HS steel strips by combined GDOES and colour-etching method[J].Surface & Coatings Technology,2007(26):4547-4552. |
| [34] | Tapan Kumar Rout .Nanolayered oxide on a steel surface reduces surface reactivity: Evaluation by glow discharge optical emission spectroscopy (GDOES)[J].Scripta materialia,2007(7):573-576. |
| [35] | X.An;J.Cawley;W.M.Rainforth;L.Chen .A study of internal oxidation in carburized steels by glow discharge optical emission spectroscopy and scanning electron microscopy[J].Spectrochimica Acta, Part B. Atomic Spectroscopy,2003(4):689-698. |
| [36] | A. Martinavicius;G. Abrasonis;A.C. Scheinost .Nitrogen interstitial diffusion induced decomposition in AISI 304L austenitic stainless steel[J].Acta materialia,2012(10):4065-4076. |
| [37] | Angeli J;Kaltenbrunner T;Androsch F M .Quantitative depth-profiling with GDOS:application to ZnNi-electrogalvanized steel sheets[J].Fresenius'Journal of Analytical Chemistry,1991,341(1-2):140-144. |
| [38] | Shimizu K.;Skeldon P.;Thompson GE.;Wood GC.;Habazaki H. .GDOES depth profiling analysis of the air-formed oxide film on a sputter-deposited Type 304 stainless steel[J].Surface and Interface Analysis: SIA: An International Journal Devoted to the Development and Application of Techniques for the Analysis of Surfaces, Interfaces and Thin Films,2000(11):743-746. |
| [39] | Marcus RK.;Gibeau TE.;Reynolds EM.;Dempster MA. .Sampling and analysis of particulate matter by glow discharge atomic emission and mass spectrometries[J].Analytical chemistry,1999(15):3061-3069. |
| [40] | J. Michler;M. Aeberhard;D. Velten;S. Winter;R. Payling;J. Breme .Depth profiling by GDOES: application of hydrogen and d.c. bias voltage corrections to the analysis of thin oxide films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2004(1):278-283. |
| [41] | Habazaki H.;Matsuo T.;Konno H.;Shimizu K.;Matsumoto K.;Takayama K. Oda Y.;Skeldon P.;Thompson GE. .Analysis of anodic films on Nb and NbNx by glow discharge optical emission spectroscopy[J].Surface and Interface Analysis: SIA: An International Journal Devoted to the Development and Application of Techniques for the Analysis of Surfaces, Interfaces and Thin Films,2003(7):618-622. |
| [42] | Shimizu K.;Skeldon P.;Thompson G.E.;Wood G.C.;Habazaki H. .GDOES depth profiling analysis of a thin surface film on aluminum[J].Surface and Interface Analysis: SIA: An International Journal Devoted to the Development and Application of Techniques for the Analysis of Surfaces, Interfaces and Thin Films,1999(11):998-1002. |
| [43] | E. Toyoda;M. Watanabe;Y. Higashi .Depth Profiling Analysis of Tarnish Films on Copper Formed During Short-Term Outdoor Exposure by Glow Discharge Optical Emission Spectroscopy[J].Corrosion: The Journal of Science and Engineering,2004(8):729-735. |
| [44] | Schwaller P;Fischer A;Thapliyal R;Aeberhard M;Michler J;Hug HJ .Single-target DC-pulsed deposition of lead zirconate titanate thin films: Investigation of the chemical and mechanical properties by glow-discharge optical emission spectroscopy and nanoindentation[J].Surface & Coatings Technology,2005(5/6):1566-1571. |
| [45] | E. Rayon Encinas;R. Escobar Galindo;J.M. Albella Martin;E. Matveeva .Hydrogen And Oxygen In-depth Evolution During Electrochemicalhydrogenation/dehydrogenation Of Y-pd Thin Films Analyzed By Glow discharge Optical Emission Spectroscopy[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2008(18):6524-6530. |
| [46] | Uemura M;Yamamoto T;Fushimi K et al.Depth profile analysis of thin passive films on stainless steel by glow discharge optical emission spectroscopy[J].Corrosion Science,2009,51(07):1554-1559. |
| [47] | Yang CL.;Mohill M.;Harrison WW.;Ingeneri K. .Depth profiling of thin films with pulsed glow discharge atomic emission spectrometry[J].Analytical chemistry,1999(23):5328-5334. |
| [48] | Pisonero J;Fernandez B;Pereiro R;Bordel N;Sanz-Medel A .Glow-discharge spectrometry for direct analysis of thin and ultra-thin solid films[J].TrAC: Trends in Analytical Chemistry,2006(1):11-18. |
| [49] | Johann Angeli;Arne Bengtson;Annemie Bogaerts;Volker Hoffmann;Vasile-Dan Hodoroaba;Edward Steer .Glow discharge optical emission spectrometry: moving towards reliable thin film analysis-a short review[J].Journal of Analytical Atomic Spectrometry,2003(6):670-679. |
| [50] | Galindo RE;Fornies E;Albella JM .Compositional depth profiling analysis of thin and ultrathin multilayer coatings by radio-frequency glow discharge optical emission spectroscopy[J].Surface & Coatings Technology,2006(22/23):6185-6189. |
| [51] | Payling R.;Delfosse D.;Aeberhard M. .Improved quantitative analysis of hard coatings by radiofrequency glow discharge optical emission spectrometry (rf-GD-OES)[J].Journal of Analytical Atomic Spectrometry,2001(1):50-55. |
| [52] | Galindo R E;Manninen N K;Palacio C et al.Advanced surface characterization of silver nanocluster segregation in Ag TiCN bioactive coatings hy RBS,GDOES and ARXPS[J].Analytical and Bioanalytical Chemistry,2013,405(19):6259-6269. |
| [53] | D. Ifezue .Certified reference materials for quantification of vanadate species in anodic alumina Rf-GDOES depth profiles[J].Journal of Analytical Atomic Spectrometry,2013(8):1311-1319. |
| [54] | Gerardo Gamez;Gaurav Mohanty;Johann Michler .Ultrafast elemental mapping of materials combinatorial libraries and high-throughput screening samples via pulsed glow discharge optical emission spectroscopy[J].Journal of Analytical Atomic Spectrometry,2013(7):1016-1023. |
| [55] | Igor S. Molchan;George E. Thompson;Peter Skeleton .Analysis of molecular monolayers adsorbed on metal surfaces by glow discharge optical emission spectrometry[J].Journal of Analytical Atomic Spectrometry,2013(1):121-126. |
| [56] | Jones D G;Payling R;Gower S A et al.Analysis of pigmented polymer coatings with radiofrequency glow discharge optical emission spectrometry[J].Journal of Analytical Atomic Spectrometry,1994,9(03):369-373. |
| [57] | Michael R.Webb;Volker Hoffinann;Gary M.Hieftje .Surface elemental mapping using glow discharge-optical emission spectrometry[J].Spectrochimica Acta, Part B. Atomic Spectroscopy,2006(12):1279-1284. |
| [58] | Hartenstein Matthew L.;Marcus R. Kenneth;Christopher Steven J. .Evaluation of helium-argon mixed gas plasmas for bulk and depth-resolved analyses by radiofrequency glow discharge atomic emission spectroscopy[J].Journal of Analytical Atomic Spectrometry,1999(7):1039-1048. |
| [59] | Dorka R.;Hoffmann V.;Kunze R. .Investigation of SiO2 layers by glow discharge optical emission spectroscopy including layer thickness determination by an optical interference effect[J].Journal of Analytical Atomic Spectrometry,2000(7):873-876. |
| [60] | Thobor A.;Rousselot C.;Mikhailov S. .Depth profiles study of n(TiN plus AlN) bilayers systems by GDOES and RBS techniques[J].Surface & Coatings Technology,2003(0):351-359. |
| [61] | Garcia JA;Rodriguez RJ;Martinez R;Fernandez C;Fernandez A;Payling R .Depth profiling of industrial surface treatments by rf and dc glow discharge spectrometry[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2004(1/2):97-102. |
| [62] | 万真真,李小佳,王永清,孙荣霞,施宁.用于实时溅射深度测量的新型Grimm辉光放电光源的设计[J].光谱学与光谱分析,2011(04):1142-1146. |
| [63] | 万真真,王永清,李小佳,王海舟,施宁.直流辉光放电等离子体激发光源自动调节控制系统[J].光谱学与光谱分析,2011(03):839-843. |
| [64] | R. Escobar Galindo;R. Gago;A. Lousa;J.M. Albella .Comparative depth-profiling analysis of nanometer-metal multilayers by ion-probing techniques[J].TrAC: Trends in Analytical Chemistry,2009(4):494-505. |
| [65] | 胡维铸,范连明.射频辉光放电发射光谱法测定中低合金钢中痕量钙[J].冶金分析,2011(07):31-34. |
| [66] | 滕璇,韩永平,李小佳,王海舟,何玉田,郑迅燕.中低合金钢中多元素的射频辉光放电发射光谱发射谱线性质的研究[J].冶金分析,2006(04):8-12. |
| [67] | 滕璇,李小佳,王海舟.中低合金钢的辉光放电发射光谱分析研究[J].冶金分析,2003(05):1-5. |
| [68] | 王震,马秀艳,宋兆华.辉光光谱法分析中低合金钢[J].南方金属,2008(02):41-43. |
| [69] | 邓军华,于媛君,戚淑芳,梁慧智,曹新全,李化.直流辉光原子发射光谱法测定合金钢中16种元素含量[J].理化检验-化学分册,2010(08):943-945. |
| [70] | 余兴,李小佳,王海舟.辉光光谱法同时测定高温合金中多种元素含量[J].钢铁研究学报,2006(05):55-59. |
| [71] | 韩永平,李小佳,王海舟.直流辉光放电光谱法测定不锈钢中11种元素[J].冶金分析,2006(03):11-14. |
| [72] | 韩永平,李小佳,王海舟.射频辉光放电发射光谱法测定不锈钢成分的研究[J].冶金分析,2007(07):8-12. |
| [73] | 邓军华,邴一宏.直流辉光放电发射光谱法同时测定硅钢中11种元素[J].冶金分析,2010(01):24-28. |
| [74] | 邓军华,曹新全,李化.直流辉光放电发射光谱法测定电工钢中多元素含量[J].化学分析计量,2010(06):39-41. |
| [75] | 钢中砷、铅、锑、锡的辉光放电原子发射光谱分析[J].冶金分析,2005(05):32-34. |
| [76] | 张毅,邬君飞,陈英颖.辉光放电原子发射光谱法快速分析生铸铁[J].理化检验-化学分册,2007(03):174-178. |
| [77] | 周桂海,吴小红.辉光放电原子发射光谱法测定钢中痕量硼[J].理化检验-化学分册,2010(06):669-670,673. |
| [78] | 邓军华,李化,曹新全,李宪林,王隽.直流辉光放电发射光谱共线法测定钢铁中硼含量[J].冶金分析,2011(01):14-18. |
| [79] | 黄卫红;胡斌;王雷 等.直流辉光放电光谱分析铜合金的基本特性研究[J].武汉大学学报(自然科学版),1999,45(04):399-342. |
| [80] | 梁峙,周桂海,吴小红,何晓丽.辉光放电原子发射光谱法测定钢中超低碳含量[J].现代仪器,2012(02):72-74. |
| [81] | 邓军华.辉光放电发射光谱法测定低合金钢中痕量钙[J].理化检验：化学分册,2012(03):355-356. |
| [82] | 余卫华,ZHANG Sui-zhong,于录军.钢铁材料表面成分及其深度分布的射频辉光放电光谱研究[J].冶金分析,2008(07):11-17. |
| [83] | 余卫华,陈士华,李江文,张穗忠.辉光放电离子溅射在扫描电镜样品制备中的应用[J].冶金分析,2011(03):6-10. |
| [84] | 张毅,陈英颖,张志颖.辉光放电光谱法分析镀锌钢板[J].理化检验-化学分册,2004(04):191-194,197. |
| [85] | 张毅,陈英颖,吴则嘉,刘晓晗,杨晟远,张林春.辉光放电光谱法分析掺杂纳米硅薄膜的研究[J].冶金分析,2004(z1):253-258. |
| [86] | 张毅,邬君飞,缪乐德,陈英颖.辉光放电原子发射光谱法测定钢铁表面纳米尺度薄膜厚度的重复性和再现性[J].宝钢技术,2010(04):41-46. |
| [87] | 雷彩虹,李春香,黄卫红,闫永胜.镀TiN和镀锌钢板的辉光放电原子发射光谱深度轮廓分析[J].冶金分析,2007(10):1-5. |
| [88] | 张殿英.彩涂钢板涂镀层的辉光放电发射光谱逐层分析方法研究[J].冶金分析,2007(08):23-27. |
| [89] | 史玉涛,李小佳,王海舟.镀锡钢板辉光放电发射光谱法定量深度分析研究[J].冶金分析,2007(02):1-7. |
| [90] | 何晓蕾,张毅,蓝闽波,陈英颖,邬君飞,王艳萍.辉光放电光谱法定量分析金属材料表面纳米级薄膜的研究[J].理化检验-化学分册,2006(09):693-698. |
| [91] | 曾林,李宁,黎德育.电镀锡薄钢板氧化膜和钝化膜的分析检测方法[J].电镀与涂饰,2010(11):41-45. |
| [92] | 王振林.锌铬膜的成分与力学性能的深度剖面分析[J].热加工工艺,2007(18):18-20. |
| [93] | 范爱兰,刘小平,秦林,常大庆,唐宾.辉光放电光谱仪逐层分析Cr12钢表面渗硼层[J].冶金分析,2007(09):12-16. |
| [94] | 徐永林,张东生,倪建.辉光电光谱法测定合金化镀锌板镀层中铁含量[J].冶金分析,2012(01):23-28. |
| [95] | Arne Bengtson .直流辉光放电发射光谱对锌基镀层深度剖面定量分析标准的研究进展[J].钢铁译文集,2003,2:5-14. |
| [96] | 汤浩波;邹诚;王平.辉光光谱仪及其在宝钢的应用[J].冶金自动化,2007(z2):346-348. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%