通过两种不同的方法合成了一种新的锡-石墨层间化合物并进行了表征.此化合物是通过KC8在四氢呋喃溶液中还原SnCl4而得到的.这种材料在锂离子电池中具有高的可逆容量和稳定性,说明锡插入石墨既能提高可逆容量也能阻止锡与锂反复脱嵌导致的体积变化.
参考文献
| [1] | A skew J R;Fayers F J;Kem shell F B .A General Description of the Lattice Code W IM S[J].Journal of the Brit Nuclear Energy Soc,1966,5(04):564-578. |
| [2] | 赵险峰;胡永明 .WIMSD4-SN程序系统的校核计算[J].清华大学学报(自然科学版),1997,7(05):99-101. |
| [3] | Selig;Ebert.[J].Advances in Inorganic Chemistry and Radiochemistry,1980(23):281. |
| [4] | N I Washita;M I Nagaki.[J].Chemical Society of Japan,1992(12):1412. |
| [5] | [P].德国申请 WO9851735 |
| [6] | 沈万慈.柔性石墨--一个新产业的发展与展望[J].新型碳材料,1996(04):24-27. |
| [7] | 宋克敏 等.[J].应用化学,1995,12(01):94. |
| [8] | 宋克敏 等.[J].无机材料学报,1994,9(04):455. |
| [9] | [J].日本化学会志(日本),2000(03):217-220. |
| [10] | Sklovsky D;Nallmova V .[J].Carbon,1995,33(03):329-345. |
| [11] | J walter;H shioyama .[J].Carbon,1999,37:1151-1158. |
| [12] | J walter;H shioyama .[J].Journal of Physics and Chemistry of Solids,1999,60:737-741. |
| [13] | F Kang;Y Leng;Zhang T Y .[J].Carbon,34(07):889-894. |
| [14] | A. Dailly;P. Willmann;D. Billaud .Synthesis, characterization and electrochemical performance of new antimony-containing graphite compounds used as anodes for lithium-ion batteries[J].Electrochimica Acta,2002(3):271-278. |
| [15] | Yoshio Idota;Tadahiko Kubota;Akihiro Matsufuji .[J].Science,1997,276:30. |
| [16] | By Dario Braga;Alberto Ripamonti.[J].Journal of the Chemical Society,Chemical Communications,1978:927. |
| [17] | David E;Bergbreiter;James M.Killough[J].Journal of the American Chemical Society,1978 |
| [18] | B Rousseau;H Estrade-Szwarckopf .[J].Solid State Communications,2003,126:583-587. |
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