用双氧水氧化法将钛箔表面氧化为三维多孔结构,以其为基板,用液相沉积法在氧化后的钛箔表面生长一定厚度的氧化钛膜,并用于柔性染料敏化太阳能电池(DSSCs)光阳极.60℃沉积、烧结、敏化、组装电池后,AM1.5模拟太阳光照下柔性DSSCs的光电转换效率达2.56%.沉积工艺对电池有明显影响,先在80℃沉积再于60℃沉积制备的具有梯度结构的光阳极,其DSSCs光电转换效率达3.09%.
参考文献
[1] | 南辉,林红,张璟,李鑫,王刚,李建保.染料敏化太阳能电池丝网印刷浆料中有机造孔剂对电池性能的影响[J].硅酸盐通报,2009(03):440-443. |
[2] | 庄东填,林红,李鑫,李建保.染料敏化太阳能电池中TiO2光阳极的包覆效果[J].硅酸盐学报,2010(09):1848-1851. |
[3] | 赵晓冲,杨盼,林红,李鑫,许晨阳,李建保.柔性染料敏化太阳能电池材料制备工艺参数的优化[J].硅酸盐学报,2010(01):25-28. |
[4] | Ito S;Ha NLC;Rothenberger G;Liska P;Comte P;Zakeeruddin SM;Pechy P;Nazeeruddin MK;Gratzel M .High-efficiency (7.2%) flexible dye-sensitized solar cells with Ti-metal substrate for nanocrystalline-TiO2 photoanode[J].Chemical communications,2006(38):4004-4006. |
[5] | O'Regan BC;Durrant JR;Sommeling PM;Bakker NJ .Influence of the TiCl4 treatment on nanocrystalline TiO2 films in dye-sensitized solar cells. 2. Charge density, band edge shifts, and quantification of recombination losses at short circuit[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(37):14001-14010. |
[6] | 郝艳明,石国英,钱迪峰,张青红.基于锐钛矿相二氧化钛溶胶的高效染料敏化太阳能电池[J].硅酸盐学报,2011(07):1090-1096. |
[7] | 张青红.二氧化钛基纳米材料及其在清洁能源技术中的研究进展[J].无机材料学报,2012(01):1-10. |
[8] | Shuang Li;Yaogang Li;Hongzhi Wang;Wugang Fan;Qinghong Zhang .Peptization–Hydrothermal Method as a Surfactant-Free Process towardNanorod-Like Anatase TiO_2 Nanocrystals[J].European journal of inorganic chemistry,2009(27):4078-4084. |
[9] | Hsu, C.-Y.;Cherng, S.-J.;Lin, Y.-J.;Chen, C.-M. .A Compact Nano-${rm TiO}_{2}$ Underlayer for Efficient Dye-Sensitized Solar Cell[J].IEEE Electron Device Letters,2013(11):1415-1417. |
[10] | Ito, S;Murakami, TN;Comte, P;Liska, P;Gratzel, C;Nazeeruddin, MK;Gratzel, M .Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10%[J].Thin Solid Films,2008(14):4613-4619. |
[11] | Pizem H.;Sukenik CN. .Effects of substrate surface functionality on solution-deposited titania films[J].Chemistry of Materials,2002(6):2476-2485. |
[12] | Wang Q;Moser JE;Gratzel M .Electrochemical impedance spectroscopic analysis of dye-sensitized solar cells[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2005(31):14945-14953. |
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