聚有机倍半硅氧烷微球(PSQ)具有无机/有机杂化材料的优异性能和微米级粒子的独特效应,因而备受人们关注.文中根据取代基的不同,将聚有机倍半硅氧烷微球分为聚巯丙基硅氧烷微球(MPPSQ)、聚氨丙基硅氧烷微球(APPSQ)、聚甲基硅氧烷微球(MPSQ)、聚苯基硅氧烷微球(PPSQ)、聚乙烯基硅氧烷微球(VPSQ)及含其他基团的硅氧烷微球,并对每一类聚有机倍半硅氧烷微球的合成方法和应用进行了详细的论述,总结了不同制备方法的研究成果及优缺点.
参考文献
| [1] | A. S. Maria Chong;X. S. Zhao;Angeline T. Kustedjo;S. Z. Qiao .Functionalization of large-pore mesoporous silicas with organosilanes by direct synthesis[J].Microporous and Mesoporous Materials,2004(1/3):33-42. |
| [2] | Song SW;Hidajat K;Kawi S .Functionalized SBA-15 materials as carriers for controlled drug delivery: Influence of surface properties on matrix-drug interactions[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(21):9568-9575. |
| [3] | Vinu A;Hossain KZ;Ariga K .Recent advances in functionalization of mesoporous silica[J].Journal of nanoscience and nanotechnology,2005(3):347-371. |
| [4] | K.J.Shea;D.A.Loy .Bridged Polysilsesquioxanes. Molecular-Engineered Hybrid Organic-Inorganic Materials[J].Chemistry of Materials,2001(10):3306-3319. |
| [5] | Hui Xu;Ping Xie;Rongben Zhang .Synthesis and characterization of oligomeric silsesquioxane with pendent carboxylic acid groups[J].European Polymer Journal,2001(12):2397-2405. |
| [6] | Y.-J.Lee;S.-W.Kuo;Y.-C.Su;J.-K.Chen;C.-W.Tu;F.-C.Chang .Syntheses,thermal properties,and phase morphologies of novel benzoxazines functionalized with polyhedral oligomeric silsesquioxane(POSS)nanocomposites[J].Polymer: The International Journal for the Science and Technology of Polymers,2004(18):6321-6332. |
| [7] | 马文石,张冬桥,段宇,万兆荣,王洪,徐迎宾.不同有机官能团聚硅氧烷微球的制备与表征[J].功能材料,2012(18):2568-2572. |
| [8] | Sankaraiah S;Lee JM;Kim JH;Choi SW .Preparation and characterization of surface-functionalized polysilsesquioxane hard spheres in aqueous medium[J].Macromolecules,2008(16):6195-6204. |
| [9] | Hu, H.;Zhou, H.;Liang, J.;An, L.;Dai, A.;Li, X.;Yang, H.;Yang, S.;Wu, H. .Facile synthesis of amino-functionalized hollow silica microspheres and their potential application for ultrasound imaging[J].Journal of Colloid and Interface Science,2011(2):392-398. |
| [10] | Jin-Gui Wang;Feng Li;Hui-Jing Zhou .Silica Hollow Spheres with Ordered and Radially Oriented Amino-Functionalized Mesochannels[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(4):612-620. |
| [11] | Matsumoto T.;Takayama Y.;Wada N.;Onoda H.;Kojima K.;Yamada H. Wakabayashi H. .Acid-free synthesis of poly-organo-siloxane spherical particles using a W/O emulsion[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(7):1764-1770. |
| [12] | Xin Lu;Zhong Xin .Synthesis of poly(styrene-co-3-trimethoxysilyl propyl methacrylate) microspheres coated with polysiloxane layer[J].Colloid and polymer science,2007(5):599-604. |
| [13] | Ma, W.;Zhang, D.;Duan, Y.;Wang, H..Highly monodisperse polysilsesquioxane spheres: Synthesis and application in cotton fabrics[J].Journal of Colloid and Interface Science,2013:194-200. |
| [14] | Tian-Song Deng;Jun-Yan Zhang;Kong-Tao Zhu .Highly monodisperse vinyl functionalized silica spheres and their self-assembled three-dimensional colloidal photonic crystals[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2010(1/3):104-111. |
| [15] | Tian-Song Deng;Frank Marlow .Synthesis of Monodisperse Polystyrene@Vinyl-SiO2 Core-Shell Particles and Hollow SiO2 Spheres[J].Chemistry of Materials: A Publication of the American Chemistry Society,2012(3):536-542. |
| [16] | 马文石,张冬桥,段宇,万兆荣,王洪,徐迎宾.单分散聚硅氧烷微球的制备表征及作为光散射剂的应用[J].高分子材料科学与工程,2012(08):129-132. |
| [17] | Dong, F.;Guo, W.;Chu, S.-W.;Ha, C.-S. .Novel fluorinated polysilsesquioxane hollow spheres: Synthesis and application in drug release[J].Chemical communications,2010(40):7498-7500. |
| [18] | Lee YG;Park JH;Oh C;Oh SG;Kim YC .Preparation of highly monodispersed hybrid silica spheres using a one-step sol-gel reaction in aqueous solution[J].Langmuir: The ACS Journal of Surfaces and Colloids,2007(22):10875-10878. |
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