采用溶胶-凝胶法和表面改性结合的方法制备了疏水性透明γ-AlOOH/FAS复合薄膜,勃姆石(γ-AlOOH)薄膜经沸水处理表面形成网格状粗糙结构.氟硅烷(十三氟辛基三乙氧基硅烷,FAS)被用作疏水剂涂敷在勃姆石薄膜表面.研究采用XRD,SEM,接触角测定仪及UV-vis分光光度计对薄膜相结构、表面形貌、接触角及可见光透过率进行了一系列表征.研究结果表明:采用溶胶-凝胶法和表面改性结合的方法制备的γ-AlOOH/FAS复合薄膜具有高的透明性和疏水性,复合薄膜对可见光透过率达90%以上,对水的接触角为120.3°.
参考文献
[1] | Aurelie Lafuma;David Quere .Superhydrophobic states[J].Nature materials,2003(7):457-460. |
[2] | Quere D .Non-sticking drops[J].Reports on Progress in Physics,2005(11):2495-2532. |
[3] | Kako T.;Nakajima A.;Irie H.;Kato Z.;Uematsu K.;Watanabe T.;Hashimoto K. .Adhesion and sliding of wet snow on a super-hydrophobic surface with hydrophilic channels[J].Journal of Materials Science,2004(2):547-555. |
[4] | Zielecka M;Bujnowska E .Silicone-containing polymer matrices as protective coatings - Properties and applications[J].Progress in Organic Coatings: An International Review Journal,2006(2):160-167. |
[5] | Frederic Mange;David Fauchadour;Loic Barre;Laurent Normand;Loic Rouleau .A microstructural investigation of nanostructured boehmite films prepared by the sol-gel route[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,1999(2/3):199-210. |
[6] | Popa AF.;Rossignol S.;Kappenstein C. .Ordered structure and preferred orientation of boehmite films prepared by the sol-gel method[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2002(2):169-174. |
[7] | Kiyoharu Tadanaga;Noriko Katata;Tsutomu Minami .Super-water-repellent Al_2O_3 coating films with high transparency[J].Journal of the American Ceramic Society,1997(4):1040-1042. |
[8] | Tadanaga K.;Minami T.;Katata N. .FORMATION PROCESS OF SUPER-WATER-REPELLENT AL2O3 COATING FILMS WITH HIGH TRANSPARENCY BY THE SOL-GEL METHOD[J].Journal of the American Ceramic Society,1997(12):3213-3216. |
[9] | Nakajima A.;Hashimoto K.;Watanabe T.;Fujishima A. .Preparation of transparent superhydrophobic boehmite and silica films by sublimation of aluminum acetylacetonate[J].Advanced Materials,1999(16):1365-1368. |
[10] | Starov VM.;Velarde MG.;Kosvintsev SR. .Spreading of surfactant solutions over hydrophobic substrates[J].Journal of Colloid and Interface Science,2000(1):185-190. |
[11] | 石涛,郭兴忠,杨辉.勃姆石(γ-AlOOH)溶胶的制备及表征[J].稀有金属材料与工程,2008(z2):73-75. |
[12] | 石涛,郭兴忠,杨辉.溶胶凝胶法制备透明氧化铝薄膜及光学性能[J].武汉理工大学学报,2007(z1):193-197. |
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