针对地热能源利用过程中钢管材料出现的腐蚀结垢问题,模拟中部平原地热水的环境条件,探讨了地热水的结垢趋势以及20#钢、镀锌钢在80℃、65℃、50℃下的腐蚀和结垢规律.结果表明,在模拟地热水中,65℃、50℃试验条件下,20#钢表面形成的腐蚀结垢产物疏松,导致其腐蚀速率较快;而镀锌钢表面的锈垢混合物致密,有效减缓了镀锌钢的腐蚀速率.在80℃试验条件下,镀锌钢在模拟地热水中的表面电位较正,镀锌层失去阴极保护作用,从而加速了钢铁的腐蚀.
Corrosion and scaling are common troubles in geothermal application. The geothermal water of a central plain region was simulated to examine its scaling trends as well as the corrosion and scaling behavior of 20# carbon steel and galvanized steel pipe at 50℃, 65℃ and 80℃. The results showed that the corrosion products and scale formed on 20# carbon steel pipe surface were loose, leading to a fast corrosion rate, while the rust and scale formed on galvanized steel pipe surface were condensed, which could effectively reduce the corrosion rate in geothermal water at 50℃ and 65℃. Under the test condition at 80℃, the surface potential of galvanized steel pipes was more positive, the zinc film lost its cathodic protection role, thus accelerated the corrosion.
参考文献
[1] | 王宏伟,屠宝峰,林豹,王晓华.地热供热系统腐蚀问题初探[J].辽宁化工,2003(07):300-301. |
[2] | Predrag Milanovic;Branislav Jacimovic;Srbislav Genie .Experimental measurement of fouling resistance in the heat exchanger of a geothermal heating system[J].Geothermics,2006(1):79-86. |
[3] | Patzay G.;Karman FH.;Kalman E.;Stahl G. .Modeling of scale formation and corrosion from geothermal water[J].Electrochimica Acta,1998(1/2):137-147. |
[4] | 朱立群,山丹丹,赵波.动态热海水中碳钢材料缓蚀剂的研究[J].材料科学与工艺,2007(05):631-635. |
[5] | 赵金平,王心义,韩鹏飞,焦述强.河南省东部平原地热水结垢与腐蚀评价及防护技术的研究[J].福州大学学报(自然科学版),2004(01):118-122. |
[6] | 曹宗仑,陈进富,刘亚,罗平凯,张颖,卢春喜.油田采出水中成垢物质CaSO4·2H2O、CaCO3的溶解度[J].石油与天然气化工,2006(06):473-476. |
[7] | J. Banas;U. Lelek-Borkowska;B. Mazurkiewicz;W. Solarski .Effect of CO{sub}2 and H{sub}2S on the composition and stability of passive film on iron alloys in geothermal water[J].Electrochimica Acta,2007(18):5704-5714. |
[8] | 肖珩.地热输水镀锌管的耐蚀性研究[J].材料保护,1984(04):29. |
[9] | 周韬,施周,方伟,徐洪福,尤作亮.输配水镀锌钢管内壁腐蚀瘤物化特性研究[J].南华大学学报(自然科学版),2006(03):8-11. |
[10] | 张蓉台.温泉水输送管材的选择[J].给水排水,2005(12):87-90. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%