综述了近年来国内外聚合物空心纳米球的研究现状,重点阐述了聚合物空心纳米球的制备方法,包括自组装法、微乳液聚合法和模板法等,比较了各种制备方法的制备原理和优缺点,介绍了聚合物空心纳米球的表征手段,最后展望了聚合物空心纳米球的发展前景.
Due to its inner hollow structure, polymeric hollow nanosphere has many special properties and extensive potential applications. Recent research about polymeric hollow nanospheres at home and abroad is reviewed in this paper. The preparation methods, such as self-assembly method, microemulsion polymerization method and template method are elaborated. The preparation mechanisms and the advantages and disadvantages of preparation methods are also introduced. In addition, the characterization and testing methods for polymeric hollow nanospheres are involved. At last, the developments of polymeric hollow nanospheres are prospected.
参考文献
| [1] | 张萍,冯年平,武培怡.聚合物空心纳米球及其在药学领域的应用[J].药学进展,2006(08):350-353. |
| [2] | 张幼维,赵炯心,江明,汪佳烨.制备核-壳结构聚合物纳米微球和空心球的原位聚合方法的普适性研究[J].高等学校化学学报,2006(09):1762-1766. |
| [3] | 刘鹏,田军,刘维民,薛群基.空心聚合物纳米球研究进展[J].化学进展,2004(01):15-20. |
| [4] | 梁志武,郝广杰,申小义,郭天瑛,宋谋道,张邦华.中空结构聚合物微粒的制备方法[J].高分子通报,2003(05):36-41. |
| [5] | Ding J F;Liu G J .Water-soluble hollow nanospheres as potential drug carriers[J].Journal of Physical Chemistry B,1998,102:6107. |
| [6] | Liu SY.;Weaver JVM.;Save M.;Armes SP. .Synthesis of pH-responsive shell cross-linked micelles and their use as nanoreactors for the preparation of gold nanoparticles[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(22):8350-8357. |
| [7] | Xiaofeng Yuan;Ming Jiang;Hanying Zhao .Noncovalently Connected Polymeric Micelles in Aqueous Medium[J].Langmuir: The ACS Journal of Surfaces and Colloids,2001(20):6122-6126. |
| [8] | Min Wang;Guangzhao Zhang;Daoyong Chen;Ming Jiang;Shiyong Liu .Noncovalently Connected Polymeric Micelles Based on a Homopolymer Pair in Solutions[J].Macromolecules,2001(20):7172-7178. |
| [9] | Kuang M;Duan HW;Wang J;Jiang M .Structural factors of rigid-coil polymer pairs influencing their self-assembly in common solvent[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2004(41):16023-16029. |
| [10] | Wang M.;Jiang M.;Ning FL.;Chen DY.;Liu SY.;Duan HW. .Block-copolymer-free strategy for preparing micelles and hollow spheres: Self-assembly of poly(4-vinylpyridine) and modified polystyrene[J].Macromolecules,2002(15):5980-5989. |
| [11] | Ding JF.;Liu GJ. .Polystyrene block poly(2-cinnamoylethyl methacrylate) nanospheres with cross-linked shells[J].Macromolecules,1998(19):6554-6558. |
| [12] | Ding J F;Liu G J .Structures of polystyrene-block-poly(2-cinnamoylethyl methacrylate)films deposited on Mica surfaces from block-selective solvents[J].Langmuir,1999,15:1738. |
| [13] | Nardin C.;Leukel J.;Meier W.;Hirt T. .Polymerized ABA triblock copolymer vesicles[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(3):1035-1041. |
| [14] | Yang Z B .Synthesis and performance of nano-sized hollow opaque polymer particles[D].杭州:浙江大学,2007. |
| [15] | Bai F Y;Fang S J .Progress in research on hollow polymer particles by vesiclos templating[J].Colloid and Polymer Science,2004,23(04):26. |
| [16] | Decher G;Hong J D .Buildup of ultrathin muhilayer films by a self-assembly process consecutive adsorption anionic and cationic bipolar amphiphiles on charged surfaces[J].Makromolekulare Chemie-Macromolecular Symposia,1991,46:321. |
| [17] | Caruso F.;Mohwald H.;Renneberg R.;Trau D. .Enzyme encapsulation in layer-by-layer engineered polymer multilayer capsules[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(4):1485-1488. |
| [18] | Gittins D I;Caruso F .Tailoring the polyelectrolyte coating of metal nanoparticles[J].Journal of Physical Chemistry B,2001,105:6846. |
| [19] | Marinakos S M;Anderson S M;Ryan J A et al.Encapsulation,permeability and cellular uptake characteristics of hollow nnometer-sized conductive polymer capsules[J].Journal of Physical Chemistry B,2001,105:8872. |
| [20] | Mandal T K;Flemming M S;Walt D R et al.Production of hollow polymeric microspheres by surface-confined living radical polymerization on silica templates[J].Chemistry of Materials,2000,12:3481. |
| [21] | Jyongsik J;Hyunkyou H .Fabrication of hollow polystyrene nanospheres in microemulsion polymerization using triblock copolymers[J].Langmuir,2002,18:5613. |
| [22] | Sanji T.;Ohnishi S.;Sakurai H.;Nakatsuka Y. .Preparation of nanometer-sized hollow particles by photochemical degradation of polysilane shell cross-linked micelles and reversible encapsulation of guest molecules[J].Macromolecules,2000(23):8524-8526. |
| [23] | Mulvaney P .Surface plasmon spectroscopy of nanosized metal particles[J].Langmuir,1996,12(03):788. |
| [24] | HUANG JIE;WAN MEIXIANG .Polyaniline Doped with Different Sulfonic Acids by in Situ Doping Polymerization[J].Journal of Polymer Science, Part A. Polymer Chemistry,1999(19):1277-1284. |
| [25] | Lijuan Zhang;Meixiang Wan .Self-Assembly of Polyaniline-From Nanotubes to Hollow Microspheres[J].Advanced functional materials,2003(10):815-820. |
| [26] | Zhu Y;Hu D;Wan MX;Jiang L;Wei Y .Conducting and superhydrophobic rambutan-like hollow spheres of polyaniline[J].Advanced Materials,2007(16):2092-2096. |
| [27] | He H Y;Zhu Y;Li X et al.Synthesis and characterization of conductive ooly(m-toluidine)hollow microsoheres[J].Acta Polymerica Sinica,2008,12:1181. |
| [28] | Stoffer J O;Bone T et al.Polymerization in water-in-oil microemulsion systems EM dash 2.SEM inverstigation of structure[J].Science & Technology,1980,1(04):393. |
| [29] | McDonald CJ.;Chaput AB.;Stevens CJ.;Bouck KJ. .Emulsion polymerization of voided particles by encapsulation of a nonsolvent[J].Macromolecules,2000(5):1593-1605. |
| [30] | Park J H;Oh C;Shin S I et al.Preparation of hollow silica microspheres in W/O emulsions with polymers[J].Journal of Colloid and Interface Science,2003,266:107. |
| [31] | Wenjiang Li;Xiaoxiang Sha;Wenjun Dong;Zichen Wang .Synthesis of stable hollow silica microspheres with mesoporous shell in nonionic W/O emulsion[J].Chemical communications,2002(20):2434-2435. |
| [32] | Jyongsik Jang;Keonsuk Lee .Facile fabrication of hollow polystyrene nanocapsules by microemulsion polymerization[J].Chemical communications,2002(10):1098-1099. |
| [33] | Ma G H;Su Z G.Polymer microspheres[M].北京:化学工业出版社,2005:20. |
| [34] | Candau F;Pabon M;Anquetil J Y et al.Polymerizable microemulsions:Some criteria to achieve an optimal formulation[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1999,153:47. |
| [35] | 汪丽梅,窦立岩,陈大俊.中空球材料的研究进展[J].高分子通报,2005(03):55-61. |
| [36] | 乐园,陈建峰,汪文川.空心微球型纳米结构材料的制备及应用进展[J].化工进展,2004(06):595-599. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%