制备了基于Zn3[Co(CN)6]2的双金属氰化络合物催化剂,考察了其催化氧化环己烯/CO2共聚反应的特点,以及制备过程中有机配体和卤化锌种类对催化剂催化性能和共聚产物组成的影响. 结果表明,该催化剂能高效催化共聚反应,在催化剂含量为1.8×10-4 时其催化效率可达6 000 g/g以上, FT-IR和 1H NMR表征证实聚合产物为接近交替的共聚物. 催化剂催化效率受有机配体和卤化锌种类影响,但共聚物组成只受卤化锌种类影响,而不受有机配体种类影响,其中叔丁醇和ZnCl2分别是较好的有机配体和锌盐. 动力学研究表明,该共聚反应对催化剂浓度是一级反应,反应的平均活化能为41.6 kJ/mol.
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