将废旧瓦楞纸板粉碎制取废纸板纤维,与玉米淀粉、聚乙烯醇共混辅以发泡剂偶氮二甲酰胺-氧化锌(AC-ZnO),利用注塑发泡法制备废纸板纤维/淀粉发泡复合材料.采用双料筒毛细管流变仪,研究了甘油-邻苯二甲酸二辛酯(G-DOP)混合塑化剂含量、废纸板纤维含量、相容剂聚丙烯酸(EAA)含量、AC-ZnO含量以及温度对废纸板纤维/淀粉发泡复合材料的流变行为的影响,采用SEM研究了不同熔体黏度对泡孔形态的影响.结果表明:废纸板纤维/淀粉发泡复合材料熔体流动特征表现为假塑性.随着混合塑化剂含量的增加,熔体黏度下降;随着废纸板纤维含量的增加,熔体黏度增加;随着EAA含量的增加,熔体黏度增加;随着AC-ZnO含量的增加,熔体黏度下降;随着温度的升高,熔体黏度先降低后升高.随着熔体黏度的降低,泡孔数量减小,孔径增大,当熔体黏度为900 Pa·s时,泡孔合并现象严重.
参考文献
[1] | 马骁飞,于九皋.甲酰胺塑化热塑性淀粉的性能研究[J].高分子学报,2004(2):240-244.Ma Xiaofei,Yu Jiuhao.Studies on the properties of formamide plasticized-thermoplastic starch[J].Acta Polymerica Sinica,2004(2):240-244. |
[2] | 姜闻博,乔秀颖,唐忠柱,孙康.乙酰化淀粉的塑化和性能研究[J].高分子学报,2006(1):97-100.Jiang Wenbo,Qiao Xiuying,Tang Zhongzhu,Sun Kang.Preparation and properties of thermoplastic acetylated starch[J].Acta Polymerica Sinica,2006(1):97-100. |
[3] | 于九皋,郑华武,张捷,高建平,林通.淀粉与多元醇共混物性能的研究[J].天津大学学报:自然科学与工程技术版,1999,32(2):141-144.Yu Jiugao,Zheng Huawu,Zhang Jie,Gao Jianping,Lin Tong.Study on the properties of the blends of starch and polylols[J].Journal of Tianjin University,1999,32(2):141-144. |
[4] | 马骁飞,于九皋.纤维增强尿素和甲酰胺混合塑化热塑性淀粉[J].精细化工,2004(5):366-369.Ma Xiaofei,Yu Jiuhao.Microfibrils as reinforcement for thermoplastic starch plasticized with the mixture of formamide and glycerol[J].Fine Chemicals,2004(5):366-369. |
[5] | 李海东,孙朋,程凤梅.热塑性乙酰化淀粉/聚乳酸的性能及形态[J].复合材料学报,201 2,29(6):55-59.Li Haidong,Sun Peng,Cheng Fengmei.Performance and morphology of thermoplastic acetylated starch/poly (lactic acid)[J].Acta Materiae Compositae Sinica,2012,29(6):55-59. |
[6] | 曾广胜,林瑞珍,郑良杰,等.废纸浆增强玉米淀粉基复合材料的制备及其力学性能研究[J].功能材料学报,2012,16(43):2218-2221.Zeng Guangsheng,Lin Ruizhen,Zheng Liangjie,et al.Preparation and performance of waste paper pulp reinforced cornstarch-based composites[J].Journal of Functional Materials,2012,16(43):2218-2221. |
[7] | 林路,古菊,谢东,等.改性淀粉/丁苯橡胶复合材料的制备及性能研究[J].复合材料学报,2010,27(2):16-23.Lin Lu,Gu Ju,Xie Dong,et al.Preparation and performance of modified starch/styrene butadiene rubber composite[J].Acta Materiae Compositae Sinica,2010,27(2):16-23. |
[8] | 陈金周,刘宏治,李新法,等.全淀粉塑料流变性能的研究[J].包装工程,2002(2):1-4.Chen Jinzhou,Liu Hougzhi,Li Xinfa,et al.A study of rheological properties of full starch thermoplastics[J].Packaging Engineering,2002(2):1-4. |
[9] | Soest Van J J G,Borger D B.Structure and properties of compreddion moulded thermoplastic starch materials from normal and high-amylose maize starches[J].J Appl Polym Sci,1997,64:631-644. |
[10] | Soest Van J J G,Kortleve P M.The influence of maltodextrins on the structure and properties of compressionmoulded starch plastic sheets[J].J Appl Polym Sci,1999,74:2207-2219. |
[11] | Willett J L,Jasberg B K,Swanson C L.Rheology of thermoplastic starch:Effects of temperature,moisture content,and additives on melt viscosity[J].Polym Eng Sci,1995,35(2):202-210. |
[12] | 刘现峰,王 苓,于 磊.工艺参数对淀粉挤出发泡的影响[J].现代塑料加工应用,2007,19(5):35-38.Liu Xianfeng,Wang Ling,Yu Lei.Influence of process parameters on extruded starch foams[J].Modern Plastics Prcessing and Application,2007,19(5):35-38. |
[13] | 曾广胜,林瑞珍,郑良杰,等.AC/ZnO发泡剂系对植物纤维增强淀粉复合发泡材料性能的影响[J].功能材料学报,2012,16(43):708-711.Zeng Guangsheng,Lin Ruizhen,Zheng Liangjie,et al.The effect of the mixed foming agent of azodicarbonamide and zincoxide on ithe properties of foamed starch-based composite strengthened by plant-fiber[J].Journal of Functional Materials,2012,16(43):708-711. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%