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采用失重法、极化曲线法研究了咪唑啉与KI的复配缓蚀剂在4%(质量浓度,下同)柠檬酸溶液中对碳钢的缓蚀协同作用。结果表明,复配缓蚀剂可有效抑制45#碳钢在柠檬酸溶液中的腐蚀,当缓蚀剂总浓度为0.4%时,咪唑啉和KI浓度比为3:1时缓蚀效果最好。极化曲线表明该复配缓蚀剂为混合型缓蚀剂。

The mixture of imidazoline and potassium iodide as a corrosion inhibitor for carbon steel in 4% (wt) citric acid solution was investigated by weight loss test and polarization curve methods. Results show that the combined inhibitor strongly inhibits the corrosion of 45 g carbon steel in citric acid solution and the mixture with the mass ratio undecyl-N-carboxymethyl-hydroxyethy imidzoline (UHCI) :KI of 8:1 has the best corrosion inhibition at a total concentration of 0. 4%. The polarization curves indicate that the combined inhibitor behaves as a mixed type inhibitor.

参考文献

[1] 李波,刘彦博.DDN-001柠檬酸缓蚀剂的研制和应用[J].黑龙江电力,2001(01):49-51.
[2] 张军,胡松青,王勇,郭文跃,刘金祥,尤龙.1-(2-羟乙基)-2-烷基-咪唑啉缓蚀剂缓蚀机理的理论研究[J].化学学报,2008(22):2469-2475.
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